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Precisely-controlled synthesis of thermoelectric oxides via chemical solution process and enhancement of their performance by microstructural regulation

Research Project

Project/Area Number 20560670
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Material processing/treatments
Research InstitutionOsaka University

Principal Investigator

ITO Mikio  Osaka University, 工学研究科, 准教授 (00294033)

Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2010: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2009: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2008: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywords熱電変換材料 / 電気伝導性酸化物 / 錯体重合法 / 電気抵抗率 / 出力因子 / パルス通電焼結 / 粉末合成 / 緻密化温度 / 酸素欠損 / 低温迅速焼結 / ホットプレス / 常圧焼結 / 元素置換 / ゼーベック係数 / クエン酸錯体法 / 性能指数
Research Abstract

The thermoelectric oxides and their composites were synthesized and their microstructures were controlled by using the chemical solution process, resulting in enhancement of thermoelectric performance and establishment of synthesis process at lower temperature and for shorter period of operating time. Especially in the case of the n-type SrTiO_3, mixing with TiB_2 was found to be quite effective for enhancing thermoelectric performance due to reduction in electrical resistivity and decreasing temperature of sintering by about 200K. As a result, the total synthesis process from powder preparation to final sintering at lower temperature and for shorter period of operating time was established by using the chemical solution process.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (25 results)

All 2010 2009 2008

All Journal Article (10 results) (of which Peer Reviewed: 10 results) Presentation (15 results)

  • [Journal Article] Enhancement of thermoelectric performance of Na_xCo_2O_4 with Ag dispersion by precipitation from Ag^+ aqueous solution2010

    • Author(s)
      Mikio Ito, Junji Sumiyoshi
    • Journal Title

      Journal of Sol-Gel Science and Technology Vol.55

      Pages: 354-359

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Reduction in densification temperature by TiB_2 addition during sintering of oxides2010

    • Author(s)
      Mikio Ito, Naoki Hasegawa, Takayoshi Nakano
    • Journal Title

      Journal of Physics : Conference Series Vol.232

      Pages: 12006-12006

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Transport properties of thermoelectric SrTiO_3 synthesized by polymerized complex method and spark plasma sintering2010

    • Author(s)
      Mikio Ito, Naoto Ohira
    • Journal Title

      Journal of Physics : Conference Series Vol.232

      Pages: 12005-12005

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] 溶液プロセスを利用した熱電酸化物多結晶焼結体の微細構造制御と高性能化プロセスの開発2010

    • Author(s)
      井藤幹夫, 柳楽知也, 勝山茂
    • Journal Title

      粉体および粉末冶金 Vol.57, No.4

      Pages: 224-231

    • NAID

      10026346545

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Transport properties of thermoelectric SrTiO_3 synthesized by polymerized complex method and spark plasma sintering2010

    • Author(s)
      Mikio Ito, Naoto Ohira
    • Journal Title

      Journal of Physics : Conference Series

      Volume: 232 Pages: 12005-12005

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reduction in densification temperature by TiB_2 addition during sintering of oxides2010

    • Author(s)
      Mikio Ito, Naoki Hasegawa, Takayoshi Nakano
    • Journal Title

      Journal of Physics : Conference Series

      Volume: 232 Pages: 12006-12006

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhancement of thermoelectric performance of Na_xCo_2O_4 with Ag dispersion by precipitation from Ag^+ aqueous solution2010

    • Author(s)
      Mikio Ito, Junji Sumiyoshi
    • Journal Title

      Journal of Sol-Gel Science and Technology

      Volume: 55 Pages: 354-359

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 溶液プロセスを利用した熱電酸化物多結晶焼結体の微細構造制御と高性能化プロセスの開発2010

    • Author(s)
      井藤幹夫, 柳楽知也, 勝山茂
    • Journal Title

      粉体および粉末冶金 57(印刷中)

    • NAID

      10026346545

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 錯体重合法およびパルス通電焼結法を利用したSrTiO_3系熱電変換材料の合成2009

    • Author(s)
      井藤幹夫
    • Journal Title

      粉体および粉末冶金 Vol.56, No.6

      Pages: 371-376

    • NAID

      10025398750

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] 錯体重合法およびパルス通電焼結法を利用したSrTiO_3系熱電変換材料の合成2009

    • Author(s)
      井藤幹夫
    • Journal Title

      粉体および粉末冶金 56

      Pages: 371-376

    • NAID

      10025398750

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] TiB_2を添加したSrTiO_3粉末の焼結挙動2010

    • Author(s)
      井藤幹夫
    • Organizer
      第15回SPS研究会
    • Place of Presentation
      大阪市立工業研究所
    • Year and Date
      2010-12-02
    • Related Report
      2010 Final Research Report
  • [Presentation] TiB_2を添加したSrTiO_3粉末の焼結挙動2010

    • Author(s)
      井藤幹夫
    • Organizer
      SPS研究会
    • Place of Presentation
      兵庫県神戸市(招待講演)
    • Year and Date
      2010-12-02
    • Related Report
      2010 Annual Research Report
  • [Presentation] SrTiO_3焼結体の緻密化挙動に及ぼすTiB_2複合化効果2010

    • Author(s)
      長谷川直輝, 井藤幹夫
    • Organizer
      日本金属学会
    • Place of Presentation
      北海道大学
    • Year and Date
      2010-09-27
    • Related Report
      2010 Final Research Report
  • [Presentation] SrTiO_3焼結体の緻密化挙動に及ぼすTiB_2複合化効果2010

    • Author(s)
      長谷川直輝, 井藤幹夫
    • Organizer
      日本金属学会
    • Place of Presentation
      北海道札幌市
    • Year and Date
      2010-09-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] パルス通電焼結により合成したSrTiO_3+TiB_2複合体の緻密化挙動2010

    • Author(s)
      長谷川直輝, 井藤幹夫, 中野貴由
    • Organizer
      粉体粉末冶金協会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2010-05-26
    • Related Report
      2010 Final Research Report
  • [Presentation] パルス通電焼結により合成したSrTiO_3+TiB_2複合体の緻密化挙動2010

    • Author(s)
      長谷川直輝, 井藤幹夫, 中野貴由
    • Organizer
      粉体粉末冶金協会
    • Place of Presentation
      東京都新宿区
    • Year and Date
      2010-05-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] SPSを利用したSrTiO_3系熱電変換材料の低温迅速合成2009

    • Author(s)
      井藤幹夫
    • Organizer
      第14回SPS研究会
    • Place of Presentation
      東北大学
    • Year and Date
      2009-11-20
    • Related Report
      2010 Final Research Report
  • [Presentation] Reduction in densification temperature by TiB_2 addition during sintering of oxides2009

    • Author(s)
      長谷川直輝, 井藤幹夫, 中野貴由
    • Organizer
      The 4th International Symposium on Atomic Technology (ISAT-4)
    • Place of Presentation
      舞子ビラ神戸
    • Year and Date
      2009-11-19
    • Related Report
      2010 Final Research Report
  • [Presentation] Transport properties of thermoelectric SrTiO_3 synthesized by polymerized complex method and spark plasma sintering2009

    • Author(s)
      井藤幹夫, 大平直人
    • Organizer
      The 4th International Symposium on Atomic Technology (ISAT-4)
    • Place of Presentation
      舞子ビラ神戸
    • Year and Date
      2009-11-19
    • Related Report
      2010 Final Research Report
  • [Presentation] Transport properties of thermoelectric SrTiO_3 synthesized by polymerized complex method and spark plasma sintering2009

    • Author(s)
      井藤幹夫, 大平直人
    • Organizer
      The 4th International Symposium on Atomic Technology (ISAT-4)
    • Place of Presentation
      兵庫県神戸市
    • Year and Date
      2009-11-19
    • Related Report
      2009 Annual Research Report
  • [Presentation] Reduction in densification temperature by TiB_2 addition during sintering of oxides2009

    • Author(s)
      長谷川直輝, 井藤幹夫, 中野貴由
    • Organizer
      The 4th International Symposium on Atomic Technology (ISAT-4)
    • Place of Presentation
      兵庫県神戸市
    • Year and Date
      2009-11-19
    • Related Report
      2009 Annual Research Report
  • [Presentation] SrTiO_3粉末の焼結挙動に及ぼすTiB_2添加効果2009

    • Author(s)
      長谷川直輝, 井藤幹夫, 中野貴由
    • Organizer
      日本金属学会
    • Place of Presentation
      京都大学
    • Year and Date
      2009-09-15
    • Related Report
      2010 Final Research Report
  • [Presentation] SrTiO_3粉末の焼結挙動に及ぼすTiB_2添加効果2009

    • Author(s)
      長谷川直輝, 井藤幹夫, 中野貴由
    • Organizer
      日本金属学会
    • Place of Presentation
      京都府京都市
    • Year and Date
      2009-09-15
    • Related Report
      2009 Annual Research Report
  • [Presentation] SrTiO_3熱電材料の焼結挙動に及ぼすTiB_2添加の影響2009

    • Author(s)
      井藤幹夫, 川田健太郎, 長谷川直輝, 中野貴由
    • Organizer
      日本金属学会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2009-03-29
    • Related Report
      2010 Final Research Report 2008 Annual Research Report
  • [Presentation] 錯体重合法およびパルス通電焼結法を利用したSrTiO_3系熱電変換材料の合成2008

    • Author(s)
      井藤幹夫
    • Organizer
      粉体粉末冶金協会
    • Place of Presentation
      九州大学
    • Year and Date
      2008-11-05
    • Related Report
      2010 Final Research Report 2008 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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