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Mechanism and control of scorodite formation for arsenic stabilization

Research Project

Project/Area Number 20560694
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Metal making engineering
Research InstitutionKyushu Institute of Technology

Principal Investigator

HIDEYUKI Itou  Kyushu Institute of Technology, 大学院・工学研究院, 助教 (90213074)

Co-Investigator(Kenkyū-buntansha) TOMIO Takasu  九州工業大学, 大学院・工学研究院, 准教授 (20264129)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2010: ¥520,000 (Direct Cost: ¥400,000、Indirect Cost: ¥120,000)
Fiscal Year 2009: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2008: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Keywordsヒ素 / スコロダイト / 固定化 / 非晶質 / 結晶化
Research Abstract

Copper is one of important base metals. On the other hand, the concentrations of impurities in ores are increasing due to the decrease in the natural resources. In particular, arsenic becomes the problem. The technology to immobilize the arsenic after separation is required to store the arsenic safely and economically. The purpose of this study was to elucidate the formation mechanism of the scorodite which was an stable arsenic compound. It was made clear that, depending on conditions, amorphous ferric arsenate was once formed on a seed crystal in water solutions but crystallized with progress of the retention time. It was also found that crystallization of the amorphous into scorodite occurs even in gas atmospheres.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (5 results)

All 2011 2010 2009

All Journal Article (2 results) (of which Peer Reviewed: 1 results) Presentation (3 results)

  • [Journal Article] Crystallization of the Amorphous Ferric Arsenate in the Saturated Steam Atmosphere2011

    • Author(s)
      Hideyuki Itou, Tomio Takasu, Yasunori Ueno
    • Journal Title

      High Temperature Materials and Processes Vol.30, Nos.4

      Pages: 5-5

    • Related Report
      2010 Final Research Report
  • [Journal Article] Crystallization of the Amorphous Ferric Arsenate in the Saturated Steam Atmosphere2011

    • Author(s)
      Hideyuki Itou
    • Journal Title

      High Temperature Materials and Processes

      Volume: 30

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] 非晶質ヒ酸鉄の結晶化2010

    • Author(s)
      栗田幸之助
    • Organizer
      資源・素材学会平成22年度秋季大会ポスター発表
    • Place of Presentation
      福岡市
    • Year and Date
      2010-09-13
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] 非晶質ヒ酸鉄の結晶化2009

    • Author(s)
      伊藤秀行
    • Organizer
      資源・素材学会平成21年度秋季大会研究・業績発表講演会
    • Place of Presentation
      札幌市
    • Year and Date
      2009-09-09
    • Related Report
      2010 Final Research Report
  • [Presentation] 非晶質ヒ酸鉄の結晶化2009

    • Author(s)
      伊藤秀行
    • Organizer
      資源・素材学会平成21年度秋季大会 研究・業績発表講演会
    • Place of Presentation
      札幌市
    • Year and Date
      2009-09-09
    • Related Report
      2009 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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