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Development of low-cost, large scale synthesis of transition metal carbosulfide to improve the workability of metal solid lubricity

Research Project

Project/Area Number 20560695
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Metal making engineering
Research InstitutionSojo University

Principal Investigator

TOMOSHIGE Ryuichi  崇城大学, 工学部, 教授 (90258640)

Co-Investigator(Renkei-kenkyūsha) ISHIDA Kiyohito  東北大学, 大学院・工学研究科, 名誉教授 (20151368)
OIKAWA Katsunari  東北大学, 大学院・工学研究科, 准教授 (70356608)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2010: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2009: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2008: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords燃焼合成 / 炭硫化物 / トライボロジー / 微細組織 / 被削性 / 摩擦 / 固体潤滑剤 / 自己伝播高温合成 / 硬度 / 層状組織 / 快削鋼 / 動摩擦係数 / 層状化合物 / 摩耗
Research Abstract

We could obtain stably Cr sulfide, Ti and Zr-systems carbosulfides by using the combustion synthesis method. From the transmission electron microscopy, the layered structures were observed in the carbosulfides, as well as MoS2 of the typical solid lubricant. The high-temperature oxidation resistance tests showed that the carbosulfides were difficult to use as dispersants for improving machinability of steel under an oxidation atmosphere because their oxidation resistance degraded over 500℃. On the other hand, their dynamic friction coefficient,μ, indicated 0.11 to 0.12, which was equivalent to MoS2.Finally, it was concluded that the sulfide and carbosulfides could be expected sufficiently as one of the promising solid lubricants.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (13 results)

All 2011 2010 2009

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (12 results)

  • [Journal Article] Some Tribological Properties of SHS-Produced Chromium Sulfide2009

    • Author(s)
      R. Tomoshige, K. Niitsu, T. Sekiguchi, K. Oikawa, K. Ishida
    • Journal Title

      International Journal of Self-Propagating High-Temperature Synthesis

      Volume: 18 Pages: 287-292

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Presentation] 遷移金属炭硫化物の燃焼合成とその性質2011

    • Author(s)
      板谷俊哉、及川勝成、石田清仁、友重竜一
    • Organizer
      2011年日本化学会西日本大会
    • Place of Presentation
      熊本大学黒髪キャンパス
    • Year and Date
      2011-11-06
    • Related Report
      2010 Annual Research Report
  • [Presentation] Mo添加ジルコニウム炭硫化物の燃焼合成とその性質2011

    • Author(s)
      友重竜一、板谷俊哉、及川勝成、石田清仁
    • Organizer
      公益社団法人日本セラミックス
    • Place of Presentation
      静岡大学浜松キャンパス
    • Year and Date
      2011-09-18
    • Related Report
      2010 Final Research Report
  • [Presentation] Preparation of Mo-added zirconium carbosulfides by self-propagating high temperature synthesis2011

    • Author(s)
      R. Tomoshige, S. Itaya, K. Oikawa, K. Ishida
    • Organizer
      XI International symposium on self-propagating high temperature synthesis
    • Place of Presentation
      Eden beach hotel, Attica, Greece
    • Year and Date
      2011-09-09
    • Related Report
      2010 Final Research Report
  • [Presentation] Mo添加ジルコニウム炭硫化物の燃焼合成とその性質2011

    • Author(s)
      友重竜一、板谷俊哉、及川勝成、石田清仁
    • Organizer
      公益社団法人日本セラミックス協会2011年年会
    • Place of Presentation
      静岡大学浜松キャンパス
    • Year and Date
      2011-03-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] 遷移金属炭硫化物の燃焼合成とその性質2010

    • Author(s)
      板谷俊哉、及川勝成、石田清仁、友重竜一
    • Organizer
      2010年日本化学会西日本大会
    • Place of Presentation
      熊本大学黒髪キャンパス
    • Year and Date
      2010-11-06
    • Related Report
      2010 Final Research Report
  • [Presentation] ジルコニウム炭硫化物の燃焼合成とその性質2010

    • Author(s)
      板谷俊哉、及川勝成, 友重竜一、石田清仁
    • Organizer
      日本金属学会
    • Place of Presentation
      北海道大学
    • Year and Date
      2010-09-27
    • Related Report
      2010 Final Research Report
  • [Presentation] ジルコニウム炭硫化物の燃焼合成とその性質2010

    • Author(s)
      板谷俊哉、及川勝成, 友重竜一、石田清仁
    • Organizer
      日本金属学会2010年秋期(第147回)大会
    • Place of Presentation
      北海道大学
    • Year and Date
      2010-09-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] Preparation of carbosulfide of transition metal with high-energy chemical reaction 3rd International Symposium on explosion, shock wave and high energy reaction phenomena(ESHP-3)2010

    • Author(s)
      R. Tomoshige, Y. Yamagata, S. Itaya, K. Oikawa, K. Ishida
    • Organizer
      Seoul National University
    • Place of Presentation
      Seoul, Korea
    • Year and Date
      2010-09-01
    • Related Report
      2010 Final Research Report
  • [Presentation] Preparation of carbosulfide of transition metal with high-energy chemical Reaction2010

    • Author(s)
      R.Tomoshige, Y.Yamagata, S.Itaya, K.Oikawa, K.Ishida
    • Organizer
      3rd International Symposium on explosion, shick wave and high energy reaction phenomena (ESHP-3)
    • Place of Presentation
      Seoul National University, Seoul, Korea
    • Year and Date
      2010-09-01
    • Related Report
      2010 Annual Research Report
  • [Presentation] 自己伝播高温合成法による遷移金属硫化物のトライボロジー特性2009

    • Author(s)
      友重竜一、山形雄一、野津怜、新津甲大、及川勝成, 石田清仁
    • Organizer
      日本セラミックス協会第22回秋期シンポジウム
    • Place of Presentation
      愛媛大学
    • Year and Date
      2009-09-17
    • Related Report
      2010 Final Research Report
  • [Presentation] 自己伝播高温合成法による遷移金属硫化物のトライボロジー特性2009

    • Author(s)
      友重竜一
    • Organizer
      日本セラミックス協会第22回秋季シンポジウム
    • Place of Presentation
      愛媛大学(城北キャンパス)
    • Year and Date
      2009-09-17
    • Related Report
      2009 Annual Research Report
  • [Presentation] Some properties on tribology of transition metal sulfide produced by SHS2009

    • Author(s)
      R. Tomoshige, K. Niitsu, T. Sekiguchi, K. Oikawa, K. Ishida
    • Organizer
      X International symposium on self-propagating high temperature synthesis
    • Place of Presentation
      Multi Rest House Hotel, Tsakhadzor, Armenia
    • Year and Date
      2009-07-08
    • Related Report
      2010 Final Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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