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Investigation on zeolite membrane performance deterioration during separation processes

Research Project

Project/Area Number 20560709
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

INOUE Tomoya  National Institute of Advanced Industrial Science and Technology, 集積マイクロシステム研究センター, 主任研究員 (20392590)

Co-Investigator(Kenkyū-buntansha) KIYOZUMI Yoshimichi  独立行政法人産業技術総合研究所, コンパクト化学システム研究センター, 主任研究員 (60356904)
NAGASE Takako  独立行政法人産業技術総合研究所, コンパクト化学システム研究センター, 主任研究員 (30357628)
HASEGAWA Yasuhisa  独立行政法人産業技術総合研究所, コンパクト化学システム研究センター, 研究員 (90392646)
西出 利一  日本大学, 工学部, 教授 (30297783)
Co-Investigator(Renkei-kenkyūsha) NISHIDE Toshikazu  日本大学, 工学部, 教授 (30297783)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2010: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2009: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2008: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Keywords膜分離 / 劣化メカニズム / ゼオライト / ゼオライト膜 / 脱水 / 脱水プロセス / 劣化 / エステル化 / プロセス強化
Research Abstract

We prepared various kinds of zeolite membranes for hydrophobic nature as well as hydrophilic nature. Each membranes were evaluated mainly in pervaporation mode, using a real-time gas analyzer that we purchased by the grant. It revealed the performance decay profile for each membrane. The performance decay was due to hydrophilic transformation of zeolite crystalline composing the hydrophobic zeolite membrane by hydrolysis (for hydrophobic zeolite membrane) or hydrophilic transformation of zeolite crystalline composing the hydrophilic zeolite membrane by ion exchange (for hydrophilic zeolite membrane). For hydrophilic membrane we tested, such as philipsite, merlinoite, and chabazite, the zeolite framework was maintained during the contact by weak acid such as acetic acid, while close contact with strong protonic acid such as sulfonic acid deteriorated the framework. The membrane performance was recovered reversibly as long as the framework was maintained by ion exchange procedure. In this case, the membrane performance had been deteriorated due to protonated zeolite crystalline formation during the pervaporation operation in close contact with acidic solution.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (37 results)

All 2011 2010 2009 2008 Other

All Journal Article (14 results) (of which Peer Reviewed: 7 results) Presentation (22 results) Remarks (1 results)

  • [Journal Article] Preparation and Properties of a Hollow Fiber Consisting Mainly of Natural Mordenite2011

    • Author(s)
      長瀬多加子、阿部千枝、清住嘉道、長谷川泰久、花岡隆昌、水上富士夫
    • Journal Title

      Chemistry Letters 40

      Pages: 52-53

    • NAID

      10027655090

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and Properties of a Hollow Fiber Consisting Mainly of Natural Mordenite2011

    • Author(s)
      長瀬多加子、阿部千枝、清住嘉道、長谷川泰久、花岡隆昌、水上富士夫
    • Journal Title

      CHEMISTRY LETTERS

      Volume: 40 Pages: 52-53

    • NAID

      10027655090

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation, characterization, and dehydration performance of MER-type zeolite membranes2010

    • Author(s)
      長谷川泰久、長瀬多加子、清住嘉道、水上富士夫
    • Journal Title

      Separation and Purification Technology 73

      Pages: 25-31

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Influence of acid on the permeation properties of NaA-type zeolite membranes2010

    • Author(s)
      長谷川泰久、長瀬多加子、清住嘉道、花岡隆昌、水上富士夫
    • Journal Title

      Journal of Membrane Science 349

      Pages: 189-194

    • Related Report
      2010 Final Research Report 2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation, characterization, and dehydration performance of MER-type zeolite membranes2010

    • Author(s)
      長谷川泰久、長瀬多加子、清住嘉道、水上富士夫
    • Journal Title

      SEPARATION AND PURIFICATION TECHNOLOGY

      Volume: 73 Pages: 25-31

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Research and Development of Compact Chemical Processes based on Inorganic Membrane and Micro Reactor Technology2009

    • Author(s)
      井上朋也
    • Journal Title

      Journal of the Research Institute for Catalysis(総説) 30

      Pages: 17-25

    • NAID

      10024483896

    • Related Report
      2010 Final Research Report
  • [Journal Article] Process intensification of dehydration reaction by PV water removal via zeolite membrane - beyond the reactive distillation process2009

    • Author(s)
      井上朋也、長谷川泰久、長瀬多加子、清住嘉道、根本雄太、西出利一、水上富士夫
    • Journal Title

      Proc.CJCES-5 (CD配布)

    • Related Report
      2010 Final Research Report
  • [Journal Article] Permeation behavior in MER-type zeolite membranes2009

    • Author(s)
      長谷川泰久、長瀬多加子、清住嘉道、花岡隆昌、水上富士夫
    • Journal Title

      Proc.ZMPC2009(電子媒体)

    • Related Report
      2010 Final Research Report
  • [Journal Article] An effect of the seed species on the PV performance of the secondary synthesized MER zeolite membranes2009

    • Author(s)
      長瀬多加子、清住嘉道、根本雄太、長谷川泰久、池田拓史、井上朋也、水上富士夫、西出利一
    • Journal Title

      Microporous and Mesoporous Materials 126

      Pages: 107-114

    • Related Report
      2010 Final Research Report 2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Permeation behavior in MER-type zeolite membranes2009

    • Author(s)
      長谷川泰久、長瀬多加子、清住嘉道、花岡隆昌、水上富士夫
    • Journal Title

      Proc.ZMPC2009

    • Related Report
      2009 Annual Research Report
  • [Journal Article] Process intensification of dehydration reaction by PV water removal via zeolite membrane-beyond the reactive distillation process2009

    • Author(s)
      井上朋也、長谷川泰久、長瀬多加子、清住嘉道、根本雄太、西出利一、水上富士夫
    • Journal Title

      Proc.CJCES-5

    • Related Report
      2009 Annual Research Report
  • [Journal Article] The Research and Development of Compact Chemical Processes based on Inorganic Membrane and Micro Reactor Technology(総説)2009

    • Author(s)
      井上朋也
    • Journal Title

      Journal of the Research Institute for Catalysis 30

      Pages: 17-25

    • Related Report
      2009 Annual Research Report
  • [Journal Article] 無機膜・マイクロリアクターによるコンパクト化学プロセスの開発(総説)2008

    • Author(s)
      井上朋也
    • Journal Title

      触媒 50

      Pages: 675-678

    • Related Report
      2010 Final Research Report 2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ゼオライト膜の劣化機構について-エステル化反応に用いたPHI膜-2008

    • Author(s)
      清住嘉道
    • Journal Title

      触媒学会反応工学部会、触媒反応工学分科会2007年度報告書

      Pages: 29-36

    • Related Report
      2008 Annual Research Report
  • [Presentation] 天然モルデナイト中空糸多孔体の特性と応用2010

    • Author(s)
      長瀬多加子、阿部千枝、志村瑞己、長谷川泰久、清住嘉道、花岡隆昌
    • Organizer
      第26回ゼオライト研究発表会
    • Place of Presentation
      船堀
    • Year and Date
      2010-12-02
    • Related Report
      2010 Annual Research Report
  • [Presentation] 透過性、分離性、耐酸性の優れた脱水用ゼオライト膜の開発2010

    • Author(s)
      長谷川泰久、佐藤剛一、西岡将輝、長瀬多加子、清住嘉道、花岡隆昌
    • Organizer
      化学工学会
    • Place of Presentation
      宇都宮
    • Year and Date
      2010-08-19
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] Solvothermal synthesis of lithosite2010

    • Author(s)
      長瀬多加子、池田拓史、阿部千枝、清住嘉道、長谷川泰久
    • Organizer
      IZC16 & IMMS7
    • Place of Presentation
      Sorrento、Italy.
    • Year and Date
      2010-07-09
    • Related Report
      2010 Final Research Report
  • [Presentation] Preparation and properties of a natural mordenite hollow fiber2010

    • Author(s)
      長瀬多加子、阿部千枝、清住嘉道、長谷川泰久
    • Organizer
      IZC16 & IMMS7
    • Place of Presentation
      Sorrento、Italy.
    • Year and Date
      2010-07-09
    • Related Report
      2010 Final Research Report
  • [Presentation] Preparation and properties of a natural mordenite hollow fiber2010

    • Author(s)
      長瀬多加子、阿部千枝、清住嘉道、長谷川泰久
    • Organizer
      IZC16 & IMMS7
    • Place of Presentation
      Sorrento、Italy
    • Year and Date
      2010-07-09
    • Related Report
      2010 Annual Research Report
  • [Presentation] Solvothermal synthesis of lithosite2010

    • Author(s)
      長瀬多加子、池田拓史、阿部千枝、清住嘉道、長谷川泰久
    • Organizer
      IZC-IMMS2010
    • Place of Presentation
      Sorrento、Italy
    • Year and Date
      2010-07-09
    • Related Report
      2010 Annual Research Report
  • [Presentation] チャバサイト(CHA)膜の合成と浸透気化特性2009

    • Author(s)
      清住嘉道, ほか
    • Organizer
      ゼオライト学会
    • Place of Presentation
      福岡
    • Year and Date
      2009-11-25
    • Related Report
      2009 Annual Research Report
  • [Presentation] Permeation behavior in MER-type zeolite membranes2009

    • Author(s)
      長谷川泰久、長瀬多加子、清住嘉道、花岡隆昌、水上富士夫
    • Organizer
      ZMPC2009
    • Place of Presentation
      東京
    • Year and Date
      2009-08-05
    • Related Report
      2010 Final Research Report 2009 Annual Research Report
  • [Presentation] Process intensification of dehydration reaction by PV water removal via zeolite membrane-beyond the reactive distillation process (Key Note)2009

    • Author(s)
      井上朋也、長谷川泰久、長瀬多加子、清住嘉道、根本雄太、西出利一、水上富士夫
    • Organizer
      CJCES-5
    • Place of Presentation
      西安、中国
    • Year and Date
      2009-07-22
    • Related Report
      2010 Final Research Report
  • [Presentation] Process intensification of dehydration reaction by PV water removal via zeolite membrane-beyond the reactive distillation process(Key Note)2009

    • Author(s)
      井上朋也、長谷川泰久、長瀬多加子、清住嘉道、根本雄太、西出利一、水上富士夫
    • Organizer
      CJCES-5(第5回日中化工シンポジウム)
    • Place of Presentation
      西安(中国)
    • Year and Date
      2009-07-22
    • Related Report
      2009 Annual Research Report
  • [Presentation] ゼオライト膜-その現状と課題-(シンポジウム指名スピーカー)2009

    • Author(s)
      清住嘉道
    • Organizer
      日本膜学会第31年会
    • Place of Presentation
      東京
    • Year and Date
      2009-05-21
    • Related Report
      2010 Final Research Report
  • [Presentation] ゼオライト膜-その現状と課題-(シンポジウム 指名スピーカー)2009

    • Author(s)
      清住嘉道
    • Organizer
      日本膜学会第31年会
    • Place of Presentation
      東京
    • Year and Date
      2009-05-21
    • Related Report
      2009 Annual Research Report
  • [Presentation] エステル化反応に用いたPHI膜の劣化機構2008

    • Author(s)
      清住嘉道
    • Organizer
      第24回ゼオライト研究発表会
    • Place of Presentation
      船堀(東京)
    • Year and Date
      2008-11-27
    • Related Report
      2008 Annual Research Report
  • [Presentation] エステル化反応に用いたPHI膜の劣化機構2008

    • Author(s)
      清住嘉道
    • Organizer
      膜シンポジウム2008
    • Place of Presentation
      大阪大学基礎工
    • Year and Date
      2008-11-14
    • Related Report
      2008 Annual Research Report
  • [Presentation] Process Intensification of dehydration reaction by PV water removal via zeolite membrane-beyond the reactive distillation process2008

    • Author(s)
      井上朋也、長谷川泰久、長瀬多加子、清住嘉道、根本雄太、西出利一、水上富士夫
    • Organizer
      IWPI 2008
    • Place of Presentation
      東京
    • Year and Date
      2008-10-17
    • Related Report
      2010 Final Research Report
  • [Presentation] Process Intensification of dehydration reaction by PV water removal via zeolite membrane-beyond the reactive distillation process2008

    • Author(s)
      井上朋也
    • Organizer
      プロセス強化に関する国際会議(IWPI 2008)
    • Place of Presentation
      東京工業大学
    • Year and Date
      2008-10-17
    • Related Report
      2008 Annual Research Report
  • [Presentation] Zeolite Membrane for Process Intensification - From the Application Point of view (Keynote)2008

    • Author(s)
      井上朋也、清住嘉道
    • Organizer
      Post ICIM Symposium
    • Place of Presentation
      三島
    • Year and Date
      2008-08-23
    • Related Report
      2010 Final Research Report
  • [Presentation] Zeolite Membrane for Process Intensification-From the Application Point of view (Keynote)2008

    • Author(s)
      井上朋也
    • Organizer
      Post ICIM Symposium
    • Place of Presentation
      御殿場
    • Year and Date
      2008-08-23
    • Related Report
      2008 Annual Research Report
  • [Presentation] Dehydration of organic solutions using zeolite MER membranes and its separation mechanism2008

    • Author(s)
      長谷川泰久、長瀬多加子、清住嘉道、花岡隆昌、水上富士夫
    • Organizer
      ICIM-10
    • Place of Presentation
      東京
    • Year and Date
      2008-08-19
    • Related Report
      2010 Final Research Report
  • [Presentation] Dehydration of organic solutions using zeolite MER membranes and its separation mechanism2008

    • Author(s)
      長谷川泰久
    • Organizer
      第10回無機膜国際会議 (ICIM-10)
    • Place of Presentation
      早稲田大学
    • Year and Date
      2008-08-19
    • Related Report
      2008 Annual Research Report
  • [Presentation] Process Intensification Assisted by Zeolite Membrane2008

    • Author(s)
      井上朋也、長谷川泰久、長瀬多加子、清住嘉道、根本雄太、西出利一、水上富士夫
    • Organizer
      ISPC 08
    • Place of Presentation
      京都
    • Year and Date
      2008-07-30
    • Related Report
      2010 Final Research Report
  • [Presentation] Process Intensification Assisted by Zeolite Membrane2008

    • Author(s)
      井上朋也
    • Organizer
      プロセス化学国際会議 (ISPC 08)
    • Place of Presentation
      京都国際会館
    • Year and Date
      2008-07-30
    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://staff.aist.go.jp/inoue-tomoya/

    • Related Report
      2008 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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