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Studies on effect of materials containing in groundwater for catalytic purification of groundwater polluted with nitrate and countermeasure development

Research Project

Project/Area Number 20560717
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionHokkaido University

Principal Investigator

KAMIYA Yuichi  Hokkaido University, 大学院・地球環境科学研究院, 准教授 (10374638)

Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2008: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords地下水浄化 / 硝酸イオン / 水素化 / 水中共雑物 / パラジウム合金触媒 / フミン酸 / オゾン酸化 / 水中共存イオン / 水中共雑 / 光触媒反応 / 酸化チタン / 膜分離 / 固体触媒 / 地下水の浄化 / 水素化反応 / スズーパラジウム合金 / 共存イオン / 銅一パラジウム合金
Research Abstract

Pollution of groundwater with nitrate caused by overfertilization is increasing problem in the world. Active carbon-supported Cu-Pd catalyst decomposed almost all nitrate into nitrogen gas by the hydrogenation in water. However, the Active carbon-supported Cu-Pd catalyst was remarkably deactivated by chlorine contained in groundwater for remediation of actual groundwater. In contrast, active carbon-supported Sn-Pd catalyst showed high catalytic performance even in the reaction solution containing chlorine and remediated the actual groundwater polluted with nitrate. The reaction system consisted of platinum-modified titanium oxide and Sn-Pd/Al_2O_3 promoted effectively photocatalytic reduction of nitrate in the actual groundwater.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (17 results)

All 2010 2009 2008

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (14 results)

  • [Journal Article] Remediation of actual groundwater polluted with nitrate by the catalytic reduction over a copper-palladium supported on active carbon.2009

    • Author(s)
      Yi Wang, Yoshinori Sakamoto, Yuichi Kamiya
    • Journal Title

      Applied CatalysisA : General 361巻

      Pages: 123-129

    • NAID

      120001390981

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Remediation of actual groundwater polluted with nitrate by the catalytic reduction over copper-palladium supported on active carbon2009

    • Author(s)
      王毅(Yi Wang)
    • Journal Title

      Applied Catalysis A : General 361

      Pages: 123-129

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Remediation of actual groundwater polluted with nitrate by the catalytic reduction over copper-palladium suppo rted on active carbon2009

    • Author(s)
      Yi Wang(王毅)
    • Journal Title

      Applied Catalysis A : General (印刷中)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] Pt/TiO2とSn-Pd/Al2O3共存下での水中硝酸イオンの光還元反応2010

    • Author(s)
      近藤浩史、阿部竜、神谷裕一
    • Organizer
      第106回触媒討論会
    • Place of Presentation
      山梨大学(甲府)
    • Year and Date
      2010-09-17
    • Related Report
      2010 Final Research Report
  • [Presentation] Selective photocatalytic reduction of nitrate to nitrogen molecules in aqueous suspension of Pt/TiO_2 and Sn-Pd/Al_2O_3.2010

    • Author(s)
      Hirofumi Kondo, Ryu Abe, Yuichi Kamiya
    • Organizer
      The 6th Tokyo Conference on Advanced Catalytic Science and Technology & The 5th Asia Pacific Congress on Catalysis
    • Place of Presentation
      札幌コンベンションセンター(札幌)
    • Year and Date
      2010-07-19
    • Related Report
      2010 Final Research Report
  • [Presentation] Remediation of groundwater polluted with nitrate by using catalytic and photocatalytic systems2010

    • Author(s)
      Yuichi Kamiya
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学(東大阪)
    • Year and Date
      2010-04-28
    • Related Report
      2010 Final Research Report
  • [Presentation] Pt/TiO_2とSn-Pd/Al_2O_3を用いた紫外光照射下における水中硝酸イオン還元2010

    • Author(s)
      近藤浩史、阿部竜、神谷裕一
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学(東大阪)
    • Year and Date
      2010-04-27
    • Related Report
      2010 Final Research Report
  • [Presentation] Catalytic and photocatalytic reduction of nitrate to nitrogen molecules in groundwater2010

    • Author(s)
      Yuichi Kamiya
    • Organizer
      FHI-CRC Joint Symposium
    • Place of Presentation
      北海道大学触媒化学研究センター(札幌)
    • Year and Date
      2010-04-01
    • Related Report
      2010 Final Research Report
  • [Presentation] Remediation of groundwater polluted with nitrate by using catalytic and photocatalytic systems2010

    • Author(s)
      神谷裕一(Yuichi Kamiya)
    • Organizer
      日本化学会第90春季年会(2010)
    • Place of Presentation
      近畿大学
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] Pt/TiO_2とSn-Pd/Al_2O_3を用いた紫外光照射下における水中硝酸イオン還元2010

    • Author(s)
      神谷裕一
    • Organizer
      日本化学会第90春季年会(2010)
    • Place of Presentation
      近畿大学
    • Year and Date
      2010-03-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] Catalytic and Photocatalytic reduction of nitrate to nitrogen molecules in groundwater2010

    • Author(s)
      神谷裕一
    • Organizer
      FHI-CRC Joint Symposium-Surface Science and Catalysis for Sustainable Society-
    • Place of Presentation
      北海道大学触媒化学研究センター(札幌) 招待講演
    • Related Report
      2010 Annual Research Report
  • [Presentation] Selective photocatalytic reduction of nitrate to nitrogen molecules in aqueous suspension of Pt/TiO_2 and Sn-Pd/Al_2O_32010

    • Author(s)
      神谷裕一
    • Organizer
      The Sixth Tokyo Conference on Advanced Catalytic Science and Technology & The Fifth Asia Pacific Congress on Catalysis
    • Place of Presentation
      札幌コンベンションセンター(札幌)
    • Related Report
      2010 Annual Research Report
  • [Presentation] Pt/TiO_2とSn-Pd/Al_2O_3共存下での水中硝酸イオンの光還元反応2010

    • Author(s)
      神谷裕一
    • Organizer
      第106回触媒討論会
    • Place of Presentation
      山梨大学(甲府)
    • Related Report
      2010 Annual Research Report
  • [Presentation] 塩化物イオン耐性の高いPd-Sn/活性炭触媒による水中硝酸イオン還元2009

    • Author(s)
      倉持祥子、坂本啓典、神谷裕一
    • Organizer
      第104回触媒討論会
    • Place of Presentation
      宮崎大学(宮崎)
    • Year and Date
      2009-09-29
    • Related Report
      2010 Final Research Report
  • [Presentation] 塩化物イオン耐性の高いPd-Sn/活性炭触媒による水中硝酸イオン還元2009

    • Author(s)
      神谷裕一
    • Organizer
      第104回触媒討論会
    • Place of Presentation
      宮崎大学
    • Year and Date
      2009-09-29
    • Related Report
      2009 Annual Research Report
  • [Presentation] Cu-Pd bimetal cluster supported on active carbon as highly active and selective catalyst for hydrogenation of nitrate in water2008

    • Author(s)
      Yoshinori Sakamoto, Mitsuru Kanno, Yuichi Kamiya, Toshio Okuhara.
    • Organizer
      14th International Congress on Catalysis
    • Place of Presentation
      COEXコンベンションセンター(ソウル)
    • Year and Date
      2008-07-15
    • Related Report
      2010 Final Research Report
  • [Presentation] Cu-Pd bimetal cluster supported on active carbon as hig hly active and selective catalyst for hydrogenation of nitrate in water2008

    • Author(s)
      Yuichi, Kamiya(神谷裕一)
    • Organizer
      14th International Congress on Catalysis
    • Place of Presentation
      COEX Convention Center(ソウル)
    • Year and Date
      2008-07-14
    • Related Report
      2008 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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