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Hydrogen storage of Mg-nanocomposites obtained by mechanical grinding.

Research Project

Project/Area Number 20560782
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Energy engineering
Research InstitutionYamaguchi University

Principal Investigator

IMAMURA Hayao  Yamaguchi University, 大学院・理工学研究科, 教授 (60136166)

Co-Investigator(Kenkyū-buntansha) SAKATA Yoshihisa  山口大学, 大学院・理工学研究科, 准教授 (40211263)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2010: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2009: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2008: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywords水素貯蔵 / マグネシウム / 複合化 / ボールミリング / 金属水素化物 / 圧力-組成等温線
Research Abstract

Hydrogen storage in Sn/MgH_2 and SiC/MgH_2 nanocomposites which are formed by ball milling of MgH_2 with Sn and SiC compounds has been studied. Upon formation of nanocomposite between MgH_2 and Sn (or SiC), the desorption properties (desorption temperature and enthalpy of dehydriding) of MgH_2 were significantly improved. For Sn/MgH_2, ball milling of MgH_2 and 17 at% Sn resulted in a lowering of the desorption temperature to 473 K. TDS (thermal desorption spectrometry), TG (thermogravimetry) and DSC (differential scanning calorimeter) measurements exhibited the existence of at least two types of hydrogen species in the Sn/MgH_2 nanocomposite; the one was hydrogen in the newly formed Sn/MgH_2 nanocomposite and the other hydrogen derived from MgH_2 remaining in Sn/MgH_2.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (15 results)

All 2010 2009 2008 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (5 results) Remarks (2 results)

  • [Journal Article] Hydrogen storage in nitrides by the use of ammonia as a hydrogen carrier2010

    • Author(s)
      H.Imamura, N.Shimomura, K.Watanabe, K.Tanaka, F.Nakamura, Y.Sakata
    • Journal Title

      Materials Science Forum 654-656

      Pages: 2819-2822

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Magnesium-based nanocomposites synthesized by high-energy ball milling for hydrogen storage2010

    • Author(s)
      H.Imamura, S.Nakatomi, K.Tanaka, H.Hashimoto, Y.Sakata
    • Journal Title

      Proceedings WHEC2010

      Pages: 319-322

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and hydrogen storage properties of mechanically ball-milled SiC/MgH_2 nanocomposites2010

    • Author(s)
      H.Imamura, S.Nakatomi, Y.Hashimoto, I.Kitazawa, Y.Sakata, H.Mae, M.Fujimoto
    • Journal Title

      J.Alloys Compd. 488

      Pages: 265-269

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hydrogen storage in nitrides by the use of ammonia as a hydrogen carrier.2010

    • Author(s)
      H.Imamura
    • Journal Title

      Materials Science Forum

      Volume: 654-656 Pages: 2819-2822

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnesium-based nanocomposites synthesized by high-energy ball milling for hydrogen storage.2010

    • Author(s)
      H.Imamura
    • Journal Title

      Proceedings WHEC2010

      Pages: 319-322

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and hydrogen storage properties of mechanically ball-milled SiC/MgH2 nanocomposites2009

    • Author(s)
      H.Imamura
    • Journal Title

      J.Alloys Compd. 488

      Pages: 265-269

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrogen storage properties of nanocrystalline MgH2 and MgH2/Sn nanocomposite synthesized by ball milling2009

    • Author(s)
      H.Imamura
    • Journal Title

      J.Alloys Compd. 484

      Pages: 939-942

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mgナノ複合系水素貯蔵材料の開発2008

    • Author(s)
      今村速夫
    • Journal Title

      工業材料 56(3)

      Pages: 40-43

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] MgH2/Al複合系水素貯蔵材料の調製とその特性2010

    • Author(s)
      橋本佳之、酒多喜久、今村速夫
    • Organizer
      日本鉄鋼協会・日本金属・中四国支部大会
    • Place of Presentation
      山口大学・山口
    • Year and Date
      2010-08-10
    • Related Report
      2010 Final Research Report
  • [Presentation] MgH2/Al複合系水素貯蔵材料の調製とその特性2010

    • Author(s)
      橋本佳之
    • Organizer
      日本鉄鋼協会・日本金属・中四国支部大会
    • Place of Presentation
      山口大学工学部
    • Year and Date
      2010-08-10
    • Related Report
      2010 Annual Research Report
  • [Presentation] Magnesium-based nanocomposites synthesized by high-energy ball milling for hydrogen storage2010

    • Author(s)
      H.Imamura, S.Nakatomi, K.Tanaka, Y.Hashimoto, Y.Sakata
    • Organizer
      18th World Hydrogen Energy Conference
    • Place of Presentation
      Essen, Germany
    • Related Report
      2010 Final Research Report
  • [Presentation] ナノ複合化したSiC/MgH_2系の水素貯蔵特性2008

    • Author(s)
      中冨嗣朗
    • Organizer
      日本金属学会2008年秋期大会
    • Place of Presentation
      熊本大学
    • Year and Date
      2008-09-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] Hydrogen storage characteristics of SiC/MgH_2 nanocomposites formed upon ball milling2008

    • Author(s)
      Hayao Imamura
    • Organizer
      International Symposium of Metal-Hydrogen Systems
    • Place of Presentation
      Iceland University
    • Year and Date
      2008-06-28
    • Related Report
      2008 Annual Research Report
  • [Remarks] ホームページ等

    • URL

      http://suiso.amse.yamaguchi-u.ac.jp/

    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      http://suiso.amso.yamaguchi-u.ac.jp/

    • Related Report
      2010 Annual Research Report

URL: 

Published: 2008-04-01   Modified: 2016-04-21  

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