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Enantioseparation of DL-galactose in plants and foods

Research Project

Project/Area Number 20580148
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Food science
Research InstitutionToyama Institute of Health

Principal Investigator

KODAMA Shuji  Toyama Institute of Health, 化学部, 主幹研究員 (70360807)

Co-Investigator(Kenkyū-buntansha) KEMMEI Tomoko  富山県衛生研究所, 化学部, 副主幹研究員 (60416089)
YAMAMOTO Atsushi  中部大学, 応用生物学部, 教授 (60360806)
AIZAWA SenーIchi  富山大学, 理工学研究部, 教授 (60231099)
TAGA Atsushi  近畿大学, 薬学部, 講師 (20247951)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2010: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2009: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2008: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Keywordsキャピラリー電気泳動 / 光学分割 / 単糖 / L-糖 / 配位子交換
Research Abstract

D-Monosaccharides are distributed widely in nature, but it is not clarified that free L-monosaccharides, such as L-galactose, L-glucose and L-mannose, present. We tried to enantioseparate galactose in vegetables and processed foods by chiral ligand-exchange capillary electrophoresis. And also, epimerization of galactose was studied.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (38 results)

All 2010 2009 2008

All Journal Article (19 results) (of which Peer Reviewed: 19 results) Presentation (19 results)

  • [Journal Article] Enantioseparation of DL-isocitric acid by a chiral ligand exchange capillary electrophoresis with Ni(II)-D-quinic acid system.2010

    • Author(s)
      Kodama, S., Taga, A., Yamamoto, A., Ito, Y., Honda, Y., Suzuki, K., Yamashita, T., Kemmei, T., Aizawa, S
    • Journal Title

      Electrophoresis 31

      Pages: 3586-3591

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] In vitro assay of the interaction between Rnc1 protein and Pmp1 mRNA by affinity capillary electrophoresis with a carboxylated capillary2010

    • Author(s)
      Taga, A., Satoh, R., Ishiwata, S., Kodama, S., Sato, A., Suzuki, K., Sugiura R
    • Journal Title

      J. Pharm. Biomed.Anal. 53

      Pages: 1332-1337

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Analysis of phosphorus-containing amino acid-type herbicides by capillary electrophoresis/ mass spectrometry using a chemically modified capillary having amino groups2010

    • Author(s)
      Iwamuro, Y., Iio-Ishimaru, R., Chinaka, S., Takayama, N., Kodama, S., Hayakawa, K
    • Journal Title

      J. Heath Sci 56

      Pages: 606-612

    • NAID

      130000425097

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Metal(II)-Ligand molar ratio dependence of enantioseparation of tartaric acid by ligand exchange capillary electrophoresis with Cu(II) and Ni(II)-D-quinic acid systems.2010

    • Author(s)
      Kodama, S., Aizawa, S., Taga, A., Yamashita, T., Kemmei, T., Suzuki, K., Honda, Y., Yamamoto, A
    • Journal Title

      Electrophoresis 31

      Pages: 1051-1054

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Reproducible chiral capillary electrophoresis of methanephetamine and its related compounds using a chemically modified capillary having diol groups2010

    • Author(s)
      Iwamuro, Y., Iio-Ishimaru, R., Chinaka, S., Takayama, N., Kodama, S., Hayakawa, K.
    • Journal Title

      Forensic Toxicol 28

      Pages: 19-24

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enanti oseparation of DL-isocitric acid by a chiral ligand exchange capillary electrophoresis with Ni(II)-D-quinic acid system2010

    • Author(s)
      Kodama, et al.
    • Journal Title

      Electrophoresis

      Volume: 31 Pages: 3586-3591

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In vitro assay of the interaction between Rncl protein and Pmpl mRNA by affinity capillary electrophoresis with a carboxylated capillary2010

    • Author(s)
      Taga, et al.
    • Journal Title

      J.Pharm.BiomedAnal.

      Volume: 53 Pages: 1332-1337

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Metal(II)-ligand molar ratio dependence of enantioseparation of tartaric acid by ligand exchange capillary electrophoresis with Cu(II) and Ni(II) -D-quinic acid systems2010

    • Author(s)
      Shuji Kodama, et al.
    • Journal Title

      Electrophoresis 31

      Pages: 1051-1054

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Evaluation of sulfobetaine-type polymer resin as an SPE adsorbent in the analysis of trace tetracycline antibiotics in hone2009

    • Author(s)
      Tsukamoto, T., Yasuma, M., Yamamoto, A., Hirayama, K., Kihou, T., Kodama, S., Inoue, Y.
    • Journal Title

      J. Sep. Sci 32

      Pages: 3591-3595

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enan-tioseparation of nicotine alkaloids in cigarettes by capillary electrophoresis using sulfated β-cyclodextrin as a chiral selector and a capillary coated with amino groups2009

    • Author(s)
      Kodama, S., Morikawa, A., Nakagomi, K., Yamamoto, A., Sato, A., Suzuki, K., Yamashita, T., Kemmei, T., Taga A.
    • Journal Title

      Electrophoresis 30

      Pages: 349-356

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Study of solid-phase extraction for the determination of sequestering agents in river water by high-performance liquid chromatography2009

    • Author(s)
      Kemmei, T., Kodama, S., Muramoto, T., Fujishima, H., Yamamoto, A., Inoue, Y., Hayakawa, K
    • Journal Title

      J. Chromatogr. A 1216

      Pages: 1109-1114

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Evaluation of sulfobetaine-type polymer resin as an SPE adsorbent in the analysis of trace tetracycline antibiotics in honey2009

    • Author(s)
      Tomoyasu Tsukamoto, et al.
    • Journal Title

      Journal of Separation Science 32

      Pages: 3591-3595

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hayakawa K. A fast and simple analysis of glyphosate in tea beverages by capillary electrophoresis with on-line copper(II)-glyphosate complex formation2008

    • Author(s)
      Kodama, S., Ito, Y., Taga, A., Nomura, Y., Yamamoto, A., Chinaka, S., Suzuki, K.. Yamashita, T., Kemmei, T.
    • Journal Title

      J. Health Sci 54

      Pages: 602-606

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Determination of adulteration in apple juice by HPLC with novel optical rotation detector2008

    • Author(s)
      Yamamoto, A., Kawai, M., Miwa, T Tsukamoto, T., Kodama, S., Hayakawa, K.
    • Journal Title

      J Agric. Food Chem 56

      Pages: 7302-7304

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Analysis of an antibody pharmaceutical, tocilizumab by capillary electrophoresis using a carboxylated capillary.2008

    • Author(s)
      Taga, A., Kita, S., Nishiura, K., Hayashi, T.,Kinoshita, M., Sato, A., Suzuki, K., Kodama, S., Kakehi, K.
    • Journal Title

      J. Sep. Sci. 31

      Pages: 853-858

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] An optical rotatory detector for high-performance liquid chromatography using polarization modulation2008

    • Author(s)
      Yamamoto.A., Kawai, M., Sakamoto, Kodama, S., Hayakawa, K.
    • Journal Title

      Anal. Sci 24

      Pages: 361-364

    • NAID

      10021099026

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] A fast and simple analysis of glyphosate in tea beverages by capillary electrophoresis with on-line copper(II)-glyphosate complex formation2008

    • Author(s)
      Shuji Kodama, et al.
    • Journal Title

      Journal of Health Science 54

      Pages: 602-606

    • NAID

      110006935590

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Deermination of adulteration in apple juice by HPLC with novel optical rotation detector2008

    • Author(s)
      Atsushi Yamamoto, et al.
    • Journal Title

      Journal of Agricultural and Food Chemistry 56

      Pages: 7302-7304

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Analysis of an antibody pharmaceutical, tocilizumab, by capillary electrophoresis using a carboxylated capillary2008

    • Author(s)
      Atsushi Taga, et al.
    • Journal Title

      Journal of Separation Sciences 31

      Pages: 853-858

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] 還元糖光学異性体の加熱による異性化2010

    • Author(s)
      小玉修嗣, 他
    • Organizer
      日本分析化学会第59年会
    • Place of Presentation
      東北大学川内北キャンパス
    • Related Report
      2010 Final Research Report
  • [Presentation] キラル配位子交換キャピラリー電気泳動によるイソクエン酸の光学異性体分析2010

    • Author(s)
      小玉修嗣, 他
    • Organizer
      日本薬学会第130年会
    • Place of Presentation
      岡山県桃太郎アリーナ
    • Related Report
      2010 Final Research Report
  • [Presentation] アミノ基導入化学修飾キャピラリーを用いたキャピラリー電気泳動/質量分析(CE・MS)法による含リンアミノ酸系農薬の分析2010

    • Author(s)
      岩室嘉晃, 他
    • Organizer
      日本薬学会第130年会
    • Place of Presentation
      岡山県桃太郎アリーナ
    • Related Report
      2010 Final Research Report
  • [Presentation] 回折格子一次光の遅相測定-新規旋光度検出器の感度に及ぼす遅相の影響2010

    • Author(s)
      三輪俊夫, 他
    • Organizer
      日本薬学会第130年会
    • Place of Presentation
      岡山県桃太郎アリーナ
    • Related Report
      2010 Final Research Report
  • [Presentation] 還元糖光学異性体の加熱による異性化2010

    • Author(s)
      小玉修嗣
    • Organizer
      日本分析化学会第59年会
    • Place of Presentation
      東北大学川内 キャンパス(仙台市)
    • Related Report
      2010 Annual Research Report
  • [Presentation] キラル配位子交換キャピラリー電気泳動法によるイソクエン酸の光学異性体分析2010

    • Author(s)
      小玉修嗣
    • Organizer
      日本薬学会第130年会
    • Place of Presentation
      岡山大学津島キャンパス、桃太郎アリーナ他(岡山市)
    • Related Report
      2009 Annual Research Report
  • [Presentation] キャピラリー電気泳動/質量分析法の法科学分析への有効利用-化学修飾キャピラリーによる迅速性と再現性の向上-2009

    • Author(s)
      岩室嘉晃, 他
    • Organizer
      第29回キャピラリー電気泳動シンポジウム
    • Related Report
      2010 Final Research Report
  • [Presentation] 配位子交換キャピラリー電気泳動法での配位子濃度依存的エナンチオマー泳動順の逆転現象2009

    • Author(s)
      小玉修嗣, 他
    • Organizer
      日本分析化学会第58年会
    • Place of Presentation
      北海道大学高等教育機能開発総合センター
    • Related Report
      2010 Final Research Report
  • [Presentation] 新規旋光度検出器を用いた光学純度測定~マツタケオールにおける溶媒増感効果~2009

    • Author(s)
      三輪俊夫, 他
    • Organizer
      日本分析化学会第58年会
    • Place of Presentation
      北海道大学高等教育機能開発総合センター
    • Related Report
      2010 Final Research Report
  • [Presentation] 中心イオンにNi(II)イオンを用いたキラル配位子交換キャピラリー電気泳動法2009

    • Author(s)
      小玉修嗣, 他
    • Organizer
      日本薬学会第129年会
    • Place of Presentation
      国立京都国際会館
    • Related Report
      2010 Final Research Report
  • [Presentation] キャピラリー電気泳動法によるメープルシロップおよびメープルシュガー中の還元糖の分析2009

    • Author(s)
      多賀淳, 他
    • Organizer
      日本薬学会第129年会
    • Place of Presentation
      国立京都国際会館
    • Related Report
      2010 Final Research Report
  • [Presentation] キラル検出器による抗真菌薬イトラコナゾールの光学分割2009

    • Author(s)
      三輪俊夫, 他
    • Organizer
      日本薬学会第129年会
    • Place of Presentation
      国立京都国際会館
    • Related Report
      2010 Final Research Report
  • [Presentation] 河川水中のグリホサートおよびアミノメチルリン酸の簡易分析2009

    • Author(s)
      野村陽子, 他
    • Organizer
      日本薬学会第129年会
    • Place of Presentation
      国立京都国際会館
    • Related Report
      2010 Final Research Report
  • [Presentation] 配位子交換キャピラリー電気泳動法での配位子濃度依存的エナンチオマー泳動順の逆転現象2009

    • Author(s)
      小玉修嗣
    • Organizer
      日本分析化学会第58年会
    • Place of Presentation
      北海道大学高等教育機能開発総合センター(札幌市)
    • Related Report
      2009 Annual Research Report
  • [Presentation] キャピラリー電気泳動によるメープルシロップ及びメープルシュガー中の還元糖の分析2009

    • Author(s)
      多賀淳, 他2名
    • Organizer
      日本薬学会第129年会
    • Place of Presentation
      国立京都国際会館
    • Related Report
      2008 Annual Research Report
  • [Presentation] 中心イオンにNi(II)イオンを用いたキラル配位子交換キャピラリー電気泳動2009

    • Author(s)
      小玉修嗣, 他6名
    • Organizer
      日本薬学会第129年会
    • Place of Presentation
      国立京都国際会館
    • Related Report
      2008 Annual Research Report
  • [Presentation] オンライン銅錯体形成を利用した茶飲料混入グリホサートの迅速キャピラリー電気泳動分析2008

    • Author(s)
      小玉修嗣, 他
    • Organizer
      日本分析化学会第57年会
    • Place of Presentation
      福岡大学七隈キャンパス
    • Related Report
      2010 Final Research Report
  • [Presentation] 新規旋光度検出器の開発-CD検出器との比較-2008

    • Author(s)
      三輪俊夫, 他
    • Organizer
      日本分析化学会第57年会
    • Place of Presentation
      福岡大学七隈キャンパス
    • Related Report
      2010 Final Research Report
  • [Presentation] 食品分析におけるダイアリシス前処理信頼性の確認2008

    • Author(s)
      中島康夫, 他
    • Organizer
      日本分析化学会第57年会
    • Place of Presentation
      福岡大学七隈キャンパス
    • Related Report
      2010 Final Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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