A study on Ce (IV)-mediated radical generation from organosilicon compounds activated by fluoride ion

• Project/Area Number: 20590003
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Chemical pharmacy
• Research Institution: Kanazawa University
• Principal Investigator: UCHIYAMA Masahiko Kanazawa University, 学際科学実験センター, 准教授 (40277265)
• Project Period (FY): 2008 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000); Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2009: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2008: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
• Keywords: ラジカル / セリウム / 一電子酸化 / フッ素アニオン / 有機ケイ素化合物

Research Abstract

Ce(IV)-mediated radical generation from organosilicon compounds activated by fluoride ion was studied. Although the generation of radical by this method has not been obsereved to date, we observed the C-C bond formation reactions with catalytic amount of Ce(IV) or Ce(III) in aqueous media in the course of this study.