Synthesis of hypervalent organoantimony and bismuth compounds and their application for organic synthesis
| Project/Area Number |
20590019
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Chemical pharmacy
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| Research Institution | Hokuriku University |
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Principal Investigator |
KURITA Jyouji 北陸大学, 教育能力開発センター, 教授 (80100494)
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| Project Period (FY) |
2008 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2010: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2009: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2008: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
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| Keywords | アンチモン / ビスマス / 超原子価 / クロスカップリング / アリール化 / 窒素 / ホウ素 / リン / 高原子価アン / 高原子価ビスマス / 遷移金属触媒 / N-アリール化 / B-アリール化 / P-アリール化 / S-アリール化 / 高原子価アンチモン / C-アリール化 |
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| Research Abstract |
Carbon-carbon,-nitrogen, and-oxygen bonds formation by transition metal-catalyzed cross-coupling reaction is one of the most important reaction in organic synthesis and considerable attention has been paid for developing this methodology in the last two decades. In the course of our research program for advance of hypervalent organoantimony and bismuth compounds in organic synthesis, we disclosed that these hypervalent compounds played important roles as both transmetallating agents and pseudo-halides in a wide variety of transition metal-catalyzed cross-coupling reactions.
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Report
(4 results)
Research Products
(73 results)
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[Journal Article] Effect of periodic replacement of the heteroatom on the spectroscopic properties of indole and benzofuran derivatives2009
Author(s)
Atsuya Muranaka, Shuji Yasuike, Ching-Yuan Liu, Jyoji Kurita, Naoki Kakusawa, Takashi Tsuchiya, Masako Okuda, Nagao Kobayashi, Yotaro Matsumoto, Kengo Yoshida, Daisuke Hashizume, Masanobu Uchiyama, Atsuya Muranaka
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Journal Title
J. Phys. Chem
Volume: 113
Pages: 464-473
Related Report
Peer Reviewed
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