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Ion behavior in light-ion carrier type batteries analyzed by neutron-MEM

Research Project

Project/Area Number 20612015
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Quantum beam science
Research InstitutionJapan Atomic Energy Agency

Principal Investigator

IGAWA Naoki  独立行政法人日本原子力研究開発機構, 量子ビーム応用研究部門, 研究主幹 (60354833)

Co-Investigator(Kenkyū-buntansha) UTSUMI Wataru  独立行政法人日本原子力研究開発機構, 量子ビーム応用研究部門, 研究主幹 (60193918)
FUKAZAWA Hiroshi  独立行政法人日本原子力研究開発機構, 量子ビーム応用研究部門, 研究副主幹 (30370464)
YAMAUCHI Hiroki  独立行政法人日本原子力研究開発機構, 量子ビーム応用研究部門, 研究職 (50367827)
TAGUCHI Tomitsugu  独立行政法人日本原子力研究開発機構, 量子ビーム応用研究部門, 研究副主幹 (50354832)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2010: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2009: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2008: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords量子ビーム / 新エネルギー / 電池材料 / Rietveld解析 / MEM解析
Research Abstract

Proton and Li ions behaviors in the light-ion carrier type batteries have been analyzed by a method in combination with the neutron diffraction and Rietveld/MEM. We determined 3-dimensional Li-diffuse pathways in LiCo_<1/3> Ni_<1/3> Mn_<1/3> O_2 and LiMn_2O_4 ; Li ions diffuse through the 3a, 9e, and 3a sites on the(001),(003), and(00-3) planes in LiCo_<1/3> Ni_<1/3> Mn_<1/3> O_2, though those diffuse 3-dimensitonal network through the 8b, 16e, and 8b sites in LiMn_2O_4.We have also found that the proton distributed at 48n site in BaSn_<0.5> In_<0.5> O_<2.75> using a new method, a difference MEM analysis.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (42 results)

All 2012 2011 2010 2009 2008 Other

All Journal Article (22 results) (of which Peer Reviewed: 22 results) Presentation (19 results) Remarks (1 results)

  • [Journal Article] Electrochemical Characteristics of Layered Li_<1.95> Mn_<0.9> Co_<0.15> O_3(C2/m) as a Lithium-Battery Cathode2012

    • Author(s)
      K. Ozawa, Y. Nakao. T. Mochiku, Z. Cheng, L. Wang, H. Iwai, Y. Tsuchiya, H. Fujii, N. Igawa
    • Journal Title

      Journal of the Electrochemimcal Society

      Volume: 159 Issue: 3 Pages: A300-A304

    • DOI

      10.1149/2.079203jes

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Neutron Diffraction Study on the Xe behavior in Clathrate Hydrate Analyzed by Rietveld/Maximum Entropy Method2011

    • Author(s)
      N. Igawa, T. Taguchi, A. Hoshikawa, H. Yamauchi, A. Birumachi, Y. Ishii
    • Journal Title

      Materials Science and Engineering

      Volume: 18 Issue: 2 Pages: 22021-22021

    • DOI

      10.1088/1757-899x/18/2/022021

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of SiC Nanowires and Nanotubes Sheathed with BN2011

    • Author(s)
      T. Taguchi, N. Igawa, S. Shamoto
    • Journal Title

      Materials Science and Engineering

      Volume: 18 Issue: 6 Pages: 6202-6202

    • DOI

      10.1088/1757-899x/18/6/062020

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Neutron Diffraction Study on the Xe behavior in Clathrate Hydrate Analyzed by Rietveld/Maximum Entropy Method2011

    • Author(s)
      N.Igawa, T.Taguchi, A.Hoshikawa, H.Yamauchi, A.Birumachi, Y.Ishii
    • Journal Title

      Mater.Sci.Eng

      Volume: 18

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Diffuse Neutron Scattering Calculation of Spinel Structure of LiMn_2O_42010

    • Author(s)
      K. Basar, Xianglian, T. Sakuma, H. Takahashi, O. Abe, N. Igawa
    • Journal Title

      AIP Proceedings

      Volume: 1244 Pages: 129-135

    • URL

      http://dx.doi.org/10.1063/1.3462750.

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crystal Structure and Nuclear Density Distribution of LiCo_<1/3> Ni_<1/3> Mn_<1/3> O_2 Analyzed by Rietveld/Maximum Entropy Method2010

    • Author(s)
      N. Igawa, T. Taguchi, H. Fukazawa, H. Yamauchi, W. Utsumi
    • Journal Title

      Journal of the American Ceramic Society

      Volume: 93 Issue: 8 Pages: 2144-2146

    • DOI

      10.1111/j.1551-2916.2010.03688.x

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crystal and Magnetic Structures and Properties of BiMnO_<3+δ>2010

    • Author(s)
      A. A. Belik, K. Kodama, N. Igawa, S. Shamoto, K. Kosuda, E. Takayama-Muromachi
    • Journal Title

      Journal of the American Chemical Society

      Volume: 132 Issue: 23 Pages: 8137-8144

    • DOI

      10.1021/ja102014n

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] CO_2 motion in carbon dioxide deuterohydrate determined by applying maximum entropy method to neutron powder diffraction data2010

    • Author(s)
      Igawa N., Taguchi T., Hoshikawa A., Fukazawa H., Yamauchi H., Utsumi W. and Ishii Y
    • Journal Title

      Journal of Physics and Chemistry of Solids

      Volume: 71 Issue: 6 Pages: 899-905

    • DOI

      10.1016/j.jpcs.2010.03.039

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Study of Oxygen Ion Diffusion in(Ba_<0.5> Sr_<0.5>)(Co_<0.8> Fe_<0.2>) O_<233-δ> through In-situ Neutron Diffractions at 300 and 720 K2010

    • Author(s)
      T. Itoh, T. Hirai, J. Yamashita, S. Watanabe, E. Kawata, N. Kitamura, Y. Idemoto, N. Igawa
    • Journal Title

      Physica B

      Volume: 405 Issue: 8 Pages: 2091-2096

    • DOI

      10.1016/j.physb.2010.01.109

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crystal Structure and Nuclear Density Distribution of LiCo_<1/3>Ni_<1/3>/Mn_<1/3>/O_2 Analyzed by Rietveld/Maximum Entropy Method2010

    • Author(s)
      N.Igawa, T.Taguchi, H.Fukazawa, H.Yamauchi, W.Utsumi
    • Journal Title

      J.Am.Ceram.Soc

      Volume: 93 Pages: 2144-2146

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] CO_2 Motion in Carbon Dioxide Deuterohydrate Determined by Applying Maximum Entropy Method to Neutron Powder Diffraction Data2010

    • Author(s)
      N.Igawa, T.Taguchi, A.Hoshikawa, H.Fukazawa, H.Yamauchi, W.Utsumi, Y.Ishii
    • Journal Title

      J.Phys.Chem.Solids

      Volume: 71 Pages: 899-905

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Neutron Powder Diffraction and Difference Maximum Entropy Method Analysis of Protium-and Deuterium-dissolved BaSn_<0.5> In_<0.5> O_<2.75+ω>2009

    • Author(s)
      T. Nagasaki, S. Shiotani, N. Igawa, M. Yoshino, K. Iwasaki, H. Fukazawa, W. Utsumi
    • Journal Title

      Journal of Solid State Chemistry

      Volume: 182 Issue: 10 Pages: 2632-2639

    • DOI

      10.1016/j.jssc.2009.06.024

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crystal Structure and Lattice Vibration of Proton Dissolved BaZr_<0.8> Sc_<0.2> O_<2.9>2009

    • Author(s)
      T. Shimoyama, T. Tojo, H. Kawaji, T. Atake, H. Fukazawa, N. Igawa
    • Journal Title

      Solid State Ionics

      Volume: 180 Issue: 6-8 Pages: 560-562

    • DOI

      10.1016/j.ssi.2008.10.016

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Study of Mechanism of Mixed Conduction due to Electrons and Oxygen Ions in(La_<0.75> Sr_<0.25>) MnO_<3.00> and(Ba_<0.5> Sr_<0.5>)(Co_<0.8> Fe_<0.2>) O_<2.33> through Rietveld Refinement and MEM Analysis2009

    • Author(s)
      T. Itoh, S. Shirasaki, Y. Fujie, N. Kitamura, Y. Idemoto, K. Osaka, I. Hirosawa, N. Igawa
    • Journal Title

      Electrochemistry

      Volume: 77 Pages: 161-168

    • NAID

      10024731103

    • URL

      https://www.jstage.jst.go.jp/article/electrochemistry/77/2/77_2_161/_pdf.

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Determination of Crystal Structure and Charge Density of(Ba_<0.5> Sr_<0.5>)(Co_<0.8> Fe_<0.2>) O_<2.33> by Rietveld Refinement and Maximum Entropy Method Analysis2009

    • Author(s)
      T. Itoh, Y. Nishida, A. Tomita, Y. Fujie, N. Kitamura, Y. Idemoto, K. Osaka, I. Hirosawa, N. Igawa
    • Journal Title

      Solid State Communications

      Volume: 149 Issue: 1-2 Pages: 41-44

    • DOI

      10.1016/j.ssc.2008.10.020

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Neutron Powder Diffraction and Difference Maximum Entropy Method Analysis of Protium- and Deuterium-dissolved BaSn_<0.5>In_<0.5>O_<2.75+α>2009

    • Author(s)
      T.Nagasaki, S.Shiotani, N.Igawa, M.Yoshino, K.Iwasaki, H.Fukazawa, W.Utsumi
    • Journal Title

      Journal of Solid State Chemistry 182

      Pages: 2632-2639

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal Structure and Lattice Vibration of Proton Dissolved BaZr_<0.8>Sc_<0.2>O_<2.9>2009

    • Author(s)
      T.Shimoyama, T.Tojo, H.Kawaji, T.Atake, H.Fukazawa, N.Igawa
    • Journal Title

      Solid State Ionics 180

      Pages: 560-562

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Study of Mechanism of Mixed Conduction due to Electrons and Oxygen Ions in (La_<0.75>Sr_<0.25>)MnO_<3.00> and (Ba_<0.5>Sr_<0.5>)(Co_<0.8>Fe_<0.2>)O_<2.33> through Rietveld Refinement and MEM Analysis2009

    • Author(s)
      T.Itoh, S.Shirasaki, Y.Fujie, N.Kitamura, Y.Idemoto, K.Osaka, I.Hirosawa, N.Igawa
    • Journal Title

      Electrochemistry 77

      Pages: 161-168

    • NAID

      10024731103

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Determination of Crystal Structure and Charge Density of (Ba_<0.5>Sr_<0.5>)(Co_<0.8>Fe_<0.2>)O_<2.33> by Rietveld Refinement and Maximum Entropy Method Analysis2009

    • Author(s)
      T. Itoh, Y. Nishida, A. Tomita, Y. Fujie, N. Kitamura, Y. Idemoto, K. Osaka, I. Hirosawa, N. Igawa
    • Journal Title

      Solid State Communications 149

      Pages: 41-44

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Location of Deuterium Atoms in BaZr_<0.5> In_<0.5> O_<2.75+α> by Neutron Powder Diffraction2008

    • Author(s)
      T. Nagasaki, T. Ito, M. Yoshino, K. Iwasaki, S. Shiotani, H. Fukazawa, N. Igawa, Y. Ishii
    • Journal Title

      Journal of Nuclear Science and Technology

      Volume: 6 Pages: 122-127

    • URL

      http://www.aesj.or.jp/publication/ISE2007/45_122-127.pdf.

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Determination of Deuterium Location in Ba_3Ca_<1.18> Nb_<1.82> O_<8.73>2008

    • Author(s)
      T. Shimoyama, T. Tojo, H. Kawaji, T. Atake, N. Igawa, Y. Ishii
    • Journal Title

      Solid State Ionics

      Volume: 179 Issue: 7-8 Pages: 231-235

    • DOI

      10.1016/j.ssi.2008.01.064

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Location of Deuterium Atoms in BaZr_<0.5>In_<0.5>O_<2.75+α> by Neutron Powder Diffraction2008

    • Author(s)
      T. Nagasaki, T. Ito, M. Yoshino, K. Iwasaki, S. Shiotani, H. Fukazawa, N. Igawa, Y. Ishii
    • Journal Title

      Journal of Nuclear Science and Technology S5

      Pages: 122-127

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] 中性子回折法によるLiイオン二次電池正極材LiM_2O_4の結晶構造の温度依存性解析2011

    • Author(s)
      井川直樹, 樹神克明, 田口富嗣, 社本真一
    • Organizer
      日本セラミックス協会第24回秋季シンポジウム
    • Place of Presentation
      北海道大学
    • Year and Date
      2011-09-07
    • Related Report
      2010 Annual Research Report
  • [Presentation] FeSr_2Cu_2O_<6+δ>系における構造的な乱れと物性2011

    • Author(s)
      茂筑高士,畑慶明,星川晃範,岩瀬謙二, D. Sulistyanintyas,小黒英俊,石垣徹,井川直樹,土屋佳則,安岡宏,平田和人
    • Organizer
      日本物理学会第66回年次大会
    • Place of Presentation
      新潟大学
    • Year and Date
      2011-03-25
    • Related Report
      2010 Final Research Report
  • [Presentation] 中性子回折法によるLiイオン二次電池正極材LiMn_2O_4のLi伝導経路解析2011

    • Author(s)
      井川直樹,樹神克明,田口富嗣,社本真一
    • Organizer
      日本セラミックス協会2011年年会
    • Place of Presentation
      静岡大学
    • Year and Date
      2011-03-17
    • Related Report
      2010 Final Research Report
  • [Presentation] 層状ペロブスカイト型構造をもつLaSrGaO_4系酸化物イオン伝導体における高温結晶構造と酸化物イオン伝導経路の組成依存2011

    • Author(s)
      井手本康,北村尚斗,内野啓哲,浜尾尚樹,小菅智之,井川直樹
    • Organizer
      JRR-3改造20周年記念シンポジウム
    • Place of Presentation
      日本科学未来館
    • Year and Date
      2011-02-28
    • Related Report
      2010 Final Research Report
  • [Presentation] RietveldおよびMEM解析による(Ba, La)_4(Ti, Si, Mo)_3O_<12>強誘電体の結晶構造2011

    • Author(s)
      井手本康,北村尚斗,浜尾尚樹,室井諒,熊谷雄輔,井川直樹
    • Organizer
      JRR-3改造20周年記念シンポジウム
    • Place of Presentation
      日本科学未来館
    • Year and Date
      2011-02-28
    • Related Report
      2010 Final Research Report
  • [Presentation] 中性子回折を用いた固体酸化物型燃料電池空気極材料の長期アニールにおける安定性の考察2011

    • Author(s)
      伊藤孝憲,井川直樹
    • Organizer
      JRR-3改造20周年記念シンポジウム
    • Place of Presentation
      日本科学未来館
    • Year and Date
      2011-02-28
    • Related Report
      2010 Final Research Report
  • [Presentation] Li_xV_2O_5正極物質の結晶構造2011

    • Author(s)
      茂筑高士,土屋佳則,小澤清,江口美佳,井川直樹
    • Organizer
      JRR-3改造20周年記念シンポジウム
    • Place of Presentation
      日本科学未来館
    • Year and Date
      2011-02-28
    • Related Report
      2010 Final Research Report
  • [Presentation] リチウム過剰マンガン酸リチウム正極物質の結晶構造2011

    • Author(s)
      茂筑高士,土屋佳則,小澤清,井川直樹
    • Organizer
      JRR-3改造20周年記念シンポジウム
    • Place of Presentation
      日本科学未来館
    • Year and Date
      2011-02-28
    • Related Report
      2010 Final Research Report
  • [Presentation] Liイオン電池材料LiCoO_2の金属置換による結晶構造と伝導経路への影響2009

    • Author(s)
      井川直樹,田口富嗣,内海渉
    • Organizer
      日本中性子科学会第9回年会
    • Place of Presentation
      いばらき量子ビーム研究センター
    • Year and Date
      2009-12-10
    • Related Report
      2010 Final Research Report 2009 Annual Research Report
  • [Presentation] In-situ中性子回折によるSOFC電解質アニール効果の考察2009

    • Author(s)
      伊藤孝憲,平井岳根,王臻偉,森昌史,井川直樹
    • Organizer
      日本中性子科学会第9回年会
    • Place of Presentation
      いばらき量子ビーム研究センター
    • Year and Date
      2009-12-10
    • Related Report
      2010 Final Research Report
  • [Presentation] 中性子回折によるリチウムイオン伝導体Li_<1+x> Al_xGe_<2-x>(PO_4)_3の構造解析2009

    • Author(s)
      藤田泰裕,高橋東之,佐久間隆,井川直樹
    • Organizer
      日本中性子科学会第9回年会
    • Place of Presentation
      いばらき量子ビーム研究センター
    • Year and Date
      2009-12-10
    • Related Report
      2010 Final Research Report
  • [Presentation] Diffuse Neutron Scattering Calculation of Spinel Structure of LiMn_2O_42009

    • Author(s)
      K. Basar, Xianglian, T. Sakuma, H. Takahashi, O. Kamishima, and N. Igawa
    • Organizer
      The 2nd Inter. Conf. on Advances in Nucl. Sci. and Eng. 2009(ICANSE 2009)
    • Place of Presentation
      Bandung, Indonesia
    • Year and Date
      2009-11-04
    • Related Report
      2010 Final Research Report
  • [Presentation] In-situ中性子回折を用いた電解質アニール効果の考察2009

    • Author(s)
      伊藤孝憲,平井岳根,王臻偉,森昌史,井川直樹
    • Organizer
      2009年電気化学秋季大会
    • Place of Presentation
      東京農工大学
    • Year and Date
      2009-09-11
    • Related Report
      2010 Final Research Report
  • [Presentation] 中性子回折によるLiイオン伝導体Li(Co_<1/3>Ni_<1/3>Mn_<1/3>)O_2のLi伝導経路解析2009

    • Author(s)
      井川直樹, 田口富嗣, 深澤裕, 山内宏樹, 内海渉
    • Organizer
      日本セラミックス協会2009年年会
    • Place of Presentation
      東京理科大学
    • Year and Date
      2009-03-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] 中性子回折によるLiイオン伝導体Li(Co_<1/3> Ni_<1/3> Mn_<1/3>) O_2のLi伝導経路解析2009

    • Author(s)
      井川直樹,田口富嗣,深澤裕,山内宏樹,内海渉
    • Organizer
      日本セラミックス協会2009年年会
    • Place of Presentation
      東京理科大学
    • Year and Date
      2009-03-17
    • Related Report
      2010 Final Research Report
  • [Presentation] 重水・軽水を溶解したBa(Sn, In) O_3系プロトン伝導体の粉末中性子回折と差MEM解析(1)-差MEM解析の原理とその空間分解能2009

    • Author(s)
      長崎正雅,塩谷真也,井川直樹,岩崎航太,吉野正人,深澤裕,内海渉
    • Organizer
      第47回セラミックス基礎科学討論会
    • Place of Presentation
      大阪国際会議場
    • Year and Date
      2009-01-08
    • Related Report
      2010 Final Research Report
  • [Presentation] 重水・軽水を溶解したBa(Sn, In) O_3系プロトン伝導体の粉末中性子回折と差MEM解析(2)-実測データの差MEM解析とその評価2009

    • Author(s)
      塩谷真也,長崎正雅,井川直樹,岩崎航太,吉野正人,深澤裕,内海渉
    • Organizer
      第47回セラミックス基礎科学討論会
    • Place of Presentation
      大阪国際会議場
    • Year and Date
      2009-01-08
    • Related Report
      2010 Final Research Report
  • [Presentation] 中性子を用いたSOFC材料の構造解析2008

    • Author(s)
      伊藤孝憲,白崎紗央里,藤江良紀,山内宏樹,井川直樹,目時直人
    • Organizer
      第17回SOFC研究発表会
    • Place of Presentation
      科学技術館
    • Year and Date
      2008-12-18
    • Related Report
      2010 Final Research Report
  • [Presentation] Liイオン伝導体Li(Co, Ni, Mn) O_2の結晶構造と伝導経路解析2008

    • Author(s)
      井川直樹,田口富嗣,深澤裕,山内宏樹,内海渉
    • Organizer
      中性子科学会第8回年会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2008-12-01
    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      https://rrsys.tokai-sc.jaea.go.jp/sentan/

    • Related Report
      2010 Final Research Report

URL: 

Published: 2008-04-01   Modified: 2016-04-21  

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