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Principle Design of Chrome-Free Refractory with High Corrosion Resistance

Research Project

Project/Area Number 20613011
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Element strategy
Research InstitutionKyushu University

Principal Investigator

HOJO Junichi  Kyushu University, 大学院・工学研究院, 教授 (20038079)

Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2010: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2009: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2008: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords環境技術 / 無機工業化学 / 高温腐食 / 無機工学化学
Research Abstract

The corrosion behaviors of various oxide ceramics against a molten slag were investigated in order to find candidates of chrome-free refractory, and were classified into four categories : low wettability and low reactivity (Cr_2O_3) ; high wettability and high reactivity (MgO, Y_2O_3) ; low wettability but high reactivity (Al_2O_3) ; high wettability but low reactivity (ZrO_2, YAG). The reactivity was also supported by thermodynamic simulation. As a result, ZrO2 was proposed as candidate material because of the low solubility in molten slag.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (15 results)

All 2011 2010 2009 2008 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (12 results) Remarks (1 results)

  • [Journal Article] 廃棄物溶融炉スラグに対する耐火物成分の濡れ性及び反応性2011

    • Author(s)
      津田秀行, 猿渡康允, 村上角一, 榎本尚也, 北條純一
    • Journal Title

      耐火物 63巻

      Pages: 192-196

    • NAID

      10027975075

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] 廃棄物溶融炉スラグに対する耐火物成分の濡れ性及び反応性2011

    • Author(s)
      津田秀行, 猿渡康允, 村上角一, 榎本尚也, 北條純一
    • Journal Title

      耐火物

      Volume: 63 Pages: 192-196

    • NAID

      10027975075

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Systematic Evaluation of Ceramics Corrosion toward New Refractory2010

    • Author(s)
      J.Hojo, S.Sawano, N.Enomoto
    • Organizer
      3rd International Congress on Ceramics (ICC3)
    • Place of Presentation
      大阪国際会議場
    • Year and Date
      2010-11-17
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] クロムフリーキャスタブルの基礎研究2010

    • Author(s)
      津田秀行、榎本尚也、北條純一
    • Organizer
      日本材料学会 セラミック材料部門委員会
    • Place of Presentation
      京都工芸繊維大学
    • Year and Date
      2010-07-13
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] 廃棄物溶融炉スラグに対する耐火物成分の濡れ性及び反応性2010

    • Author(s)
      北條純一, 他4名
    • Organizer
      耐火物技術協会第26回セメント用耐火物研究会
    • Place of Presentation
      日本教育会館
    • Year and Date
      2010-05-15
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] 熱力学計算による溶鋼鍋用不定形耐火物のスラグ侵食シミュレーション2009

    • Author(s)
      北條純一, 他4名
    • Organizer
      日本MRS学術シンポジウム
    • Place of Presentation
      横浜市開港記念会館
    • Year and Date
      2009-12-07
    • Related Report
      2010 Final Research Report
  • [Presentation] 熱力学計算による溶鋼鍋用不定形耐火物のスラグ侵食シミュレーション2009

    • Author(s)
      貞富善喬・岩下和俊・加山恒夫・榎本尚也・北條純一
    • Organizer
      日本MRS学術シンポジウム
    • Place of Presentation
      横浜市開港記念会館、横浜情報文化センター、波止場会館
    • Year and Date
      2009-12-07
    • Related Report
      2009 Annual Research Report
  • [Presentation] 熱力学計算による溶鋼鍋用不定形耐火物のスラグ侵食特性の推定と最適化2009

    • Author(s)
      北條純一, 他4名
    • Organizer
      セラミックス協会&耐火物技術協会秋季合同研究発表会
    • Place of Presentation
      ウェルとばた
    • Year and Date
      2009-12-03
    • Related Report
      2010 Final Research Report
  • [Presentation] 熱力学計算による溶鋼鍋用不定形耐火物のスラグ侵食特性の推定と最適化2009

    • Author(s)
      貞富善喬・岩下和俊・加山恒夫・榎本尚也・北條純一
    • Organizer
      セラミックス協会&耐火物技術協会秋季合同研究発表会
    • Place of Presentation
      ウェルとばた 福岡県北九州市戸畑区
    • Year and Date
      2009-12-03
    • Related Report
      2009 Annual Research Report
  • [Presentation] 溶鋼鍋用キャスタブル中のスピネルとスラグの反応挙動2009

    • Author(s)
      北條純一, 他4名
    • Organizer
      耐火物技術協会 鋳造用耐火物専門委員会
    • Place of Presentation
      メルパルク岡山
    • Year and Date
      2009-11-24
    • Related Report
      2010 Final Research Report 2009 Annual Research Report
  • [Presentation] 不定形耐火物のスラグ侵食特性のシミュレーションとその実証2009

    • Author(s)
      北條純一, 他4名
    • Organizer
      セラミックス協会秋季シンポジウム
    • Place of Presentation
      愛媛大学(城北キャンパス)
    • Year and Date
      2009-09-16
    • Related Report
      2010 Final Research Report 2009 Annual Research Report
  • [Presentation] Investigation of Corrosion Resistance of Ceramics toward Chrome-free Refractory2009

    • Author(s)
      J.Hojo, Y.Nishimura, S.Sawano, N.Enomoto,
    • Organizer
      3rd International Conference on Science and Technology for Advanced Ceramics (STAC3)
    • Place of Presentation
      メルパルク横浜
    • Year and Date
      2009-06-16
    • Related Report
      2010 Final Research Report
  • [Presentation] Investigation of Corrosion Resistance of Ceramics toward Chrome-free Refractory2009

    • Author(s)
      Junichi HOJO, Yoshihiro NISHIMURA, Shoko SAWANO, Naoya ENOMOTO
    • Organizer
      3rd International Conference on Science and Technology for Advanced Ceramics(STAC3)
    • Place of Presentation
      メルパルク横浜
    • Year and Date
      2009-06-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] 溶鋼取鍋用キャスタブルの微構造調査及びスラグ浸潤特性2008

    • Author(s)
      北條純一, 他4名
    • Organizer
      日本セラミックス協会第21回秋季シンポジウム
    • Place of Presentation
      北九州国際会議場
    • Year and Date
      2008-09-18
    • Related Report
      2010 Final Research Report 2008 Annual Research Report
  • [Remarks] ホームページ等

    • URL

      http://www.cstf.kyushu-u.ac.jp/?hojolab/

    • Related Report
      2010 Final Research Report

URL: 

Published: 2008-04-01   Modified: 2016-04-21  

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