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Development of fast proton conductors and novel fuel cell system using interfacial transport phenomena

Research Project

Project/Area Number 20681007
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Environmental technology/Environmental materials
Research InstitutionThe University of Tokyo

Principal Investigator

OTOMO Junichiro  東京大学, 大学院・新領域創成科学研究科, 准教授 (90322065)

Project Period (FY) 2008 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥21,840,000 (Direct Cost: ¥16,800,000、Indirect Cost: ¥5,040,000)
Fiscal Year 2011: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2010: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2009: ¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
Fiscal Year 2008: ¥7,670,000 (Direct Cost: ¥5,900,000、Indirect Cost: ¥1,770,000)
Keywords省エネルギー技術 / 燃料電池 / プロトン伝導体 / 界面イオン伝導 / 電極反応 / 省エネルギー
Research Abstract

Proton conducting phosphoric glassy electrolyte was investigated. It is found that the interface between glassy phase and micro crystalline particle generated in the glass matrix enhances the proton conductivity. This result provides a principle of a material design for a fast proton conductor working at around 150-300℃. We also investigated electro-oxidation of alcohols such as ethanol, ethylene glycerol and glycerol, using an intermediate temperature fuel cell working at around 250℃. It is observed that the alcohols can be oxidized rapidly at the intermediate temperature. The reaction mechanisms were also calcified through the electrochemical measurements.

Report

(6 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report   Self-evaluation Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (31 results)

All 2012 2011 2010 2009 2008 Other

All Journal Article (14 results) (of which Peer Reviewed: 13 results) Presentation (15 results) Remarks (2 results)

  • [Journal Article] Electrochemical Performance for the Electro-oxidation of Ethylene Glycol on a Carbon-supported Platinum Catalyst at Intermediate Temperature2011

    • Author(s)
      Fumihiko Kosaka, Yoshito Oshima, Junichiro Otomo
    • Journal Title

      Electrochimica Acta

      Volume: 56(27) Pages: 10093-10100

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Acceleration of Ethanol Electro oxidation on a Carbon-supported Platinum Catalyst at Intermediate Temperatures2011

    • Author(s)
      Iori Shimada, Yoshito Oshima and Junichiro Otomo
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 158(4) Pages: 369-375

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Fast Proton Transport in Zinc Phosphorous Glass Composites2011

    • Author(s)
      Yuma Furuhashi, Iori Shimada, Junichiro Otomo
    • Journal Title

      Materials Chemistry and Physics

      Volume: 127(1-2) Pages: 322-328

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] 固体電解質形燃料電池の材料開発と構造制御による高性能化2011

    • Author(s)
      大友順一郎
    • Journal Title

      表面科学

      Volume: 32(2) Pages: 93-98

    • NAID

      10027904664

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical performance for the electro-oxidation of ethylene glycolon a carbon-supported platinum catalyst at intermediate temperature2011

    • Author(s)
      Fumihiko Kosaka, Yoshito Oshima, Junichiro Otomo
    • Journal Title

      Electrochimica Acta

      Volume: 56 Issue: 27 Pages: 10093-10100

    • DOI

      10.1016/j.electacta.2011.08.109

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Acceleration of Ethanol Electrooxidation on a Carbon-Supported Platinum Catalyst at Intermediate Temperatures2011

    • Author(s)
      Iori Shimada, Yoshito Oshima, Junichiro Otomo
    • Journal Title

      Journal of The Electrochemical Society 158(4)

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Fast Proton Transport in Zinc Phosphorous Glass Composites2011

    • Author(s)
      Yuma Furuhashi, Iori Shimada, Junichiro Otomo, Yoshito Oshima
    • Journal Title

      Materials Chemistry and Physics 127(1-2)

      Pages: 322-328

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] 固体電解質形燃料電池の材料開発と構造制御による高性能化(総説記事)2011

    • Author(s)
      大友順一郎
    • Journal Title

      表面科学 32(2)

      Pages: 93-98

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Acceleration of Ethanol Electrooxidation on a Carbon-Supported Platinum Catalyst at Intermediate Temperatures2011

    • Author(s)
      Iori Shimada, Yoshito Oshima, Junichiro Otomo
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 158

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fast Proton Transport in Zinc Phosphorous Glass Composites2011

    • Author(s)
      Yuma Furuhashi, Iori Shimada, Junichiro Otomo, Yoshito Oshima
    • Journal Title

      Materials Chemistry and Physics

      Volume: 127 Pages: 322-328

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 中温作動直接エタノール形燃料電池の電極反応特性評価2009

    • Author(s)
      嶋田五百里・大友順一郎・大島義人
    • Journal Title

      化学工学会エネルギー部会シンポジウム講演論文集 8(1)

      Pages: 37-40

    • NAID

      130004667681

    • Related Report
      2009 Annual Research Report
  • [Journal Article] Direct Alcohol Electro-oxidation in an Intermediate Temperature Fuel Cell2008

    • Author(s)
      Junichiro Otomo, Satoru Nishida, Hiroyuki Kato, Hidetoshi Nagamoto and Yoshito Oshima
    • Journal Title

      ECS Transactions

      Volume: 16(2) Pages: 1275-1284

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Direct Alcohol Electro-oxidation in an Intermediate Temperature Fuel Cell2008

    • Author(s)
      Junichiro Otomo, Satoru Nishida, Hiroyuki Kato, Hidetoshi Nagamoto, Yoshito Oshima
    • Journal Title

      ECS Transactions 16(2)

      Pages: 1275-1284

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Direct Alcohol Electro-oxidation in an Intermediate Temperature Fuel Cell2008

    • Author(s)
      J. Otomo, S. Nishida, H. Kato, H. Nagamoto, Y. Oshima
    • Journal Title

      ECS Transactions 16(2)

      Pages: 1275-1284

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] グリセリンを燃料に用いた中温作動形燃料電池の電極反応特性2012

    • Author(s)
      石山啓介・大友順一郎・大島義人
    • Organizer
      化学工学会第77年会
    • Place of Presentation
      工学院大学新宿キャンパス
    • Year and Date
      2012-03-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] 中温域における白金電極上の多価アルコールの反応特性2012

    • Author(s)
      大友順一郎、石山啓介、高坂文彦、大島義人
    • Organizer
      電気化学会第79回大会
    • Place of Presentation
      アクトシティ浜松
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 中温作動燃料電池におけるアルコール燃料の反応特性2011

    • Author(s)
      大友順一郎・嶋田五百里・高坂文彦・大島義人
    • Organizer
      INCHEM TOKYO 2011 産学官マッチングフォーラム
    • Place of Presentation
      東京ビックサイト
    • Year and Date
      2011-11-18
    • Related Report
      2011 Annual Research Report
  • [Presentation] Reaction Mechanism of Ethanol Electro-oxidation at Intermediate Temperatures2011

    • Author(s)
      Iori Shimada, Yoshito Oshima, Junichiro Otomo
    • Organizer
      62nd Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      朱鷺メッセ(新潟市万代島)
    • Year and Date
      2011-09-13
    • Related Report
      2011 Annual Research Report
  • [Presentation] 中温作動直接エタノール形燃料電池の電極反応特性評価2010

    • Author(s)
      嶋田五百里・大友順一郎・大島義人
    • Organizer
      第17回燃料電池シンポジウム(FCDIC)
    • Place of Presentation
      タワーホール船堀、東京
    • Year and Date
      2010-05-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] Electrooxidation of Alcohol Fuels at Intermediate Temperatures2010

    • Author(s)
      Junichiro Otomo, Iori Shimada, Fumihiko Kosaka and Yoshito Oshima
    • Organizer
      61st Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Nice, France
    • Related Report
      2011 Final Research Report 2010 Annual Research Report 2010 Self-evaluation Report
  • [Presentation] 種々のアルコール燃料を用いた中温作動直接アルコール形燃料電池のアノード反応特性2010

    • Author(s)
      大友順一郎、嶋田五百里、高坂文彦、大島義人
    • Organizer
      電気化学会第77回大会
    • Place of Presentation
      富山大学五福キャンパス
    • Related Report
      2011 Final Research Report 2010 Self-evaluation Report 2009 Annual Research Report
  • [Presentation] 中温作動直接エタノール形燃料電池の電極反応特性評価2009

    • Author(s)
      嶋田五百里・大友順一郎・大島義人
    • Organizer
      化学工学会第41回秋季大会
    • Place of Presentation
      広島大学東広島キャンパス
    • Year and Date
      2009-09-18
    • Related Report
      2009 Annual Research Report
  • [Presentation] 中低温作動燃料電池を指向したプロトン伝導性リン酸亜鉛系ガラス複合体の合成と添加物効果2009

    • Author(s)
      大友順一郎・古橋優磨・嶋田五百里・大島義人
    • Organizer
      電気化学会第76回大会
    • Place of Presentation
      京都市京都大学
    • Year and Date
      2009-03-31
    • Related Report
      2008 Annual Research Report
  • [Presentation] 中低温域におけるリン酸亜鉛系ガラス複合体のプロトン伝導特性と界面効果2009

    • Author(s)
      古橋優磨・嶋田五百里・大友順一郎・大島義人
    • Organizer
      化学工学会第74年会
    • Place of Presentation
      横浜市横浜国立大学
    • Year and Date
      2009-03-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] 中温域におけるアルコール類の電極酸化反応と反応生成物評価2009

    • Author(s)
      大友順一郎、嶋田五百里、大島義人
    • Organizer
      第50回電池討論会
    • Place of Presentation
      国立京都国際会館
    • Related Report
      2011 Final Research Report 2010 Self-evaluation Report 2009 Annual Research Report
  • [Presentation] 中低温作動燃料電池を指向したプロトン伝導性リン酸亜鉛系ガラス複合体の合成と添加物効果2009

    • Author(s)
      大友順一郎、古橋優磨、嶋田五百里、大島義人
    • Organizer
      電気化学会第76回大会
    • Place of Presentation
      京都大学吉田キャンパス
    • Related Report
      2011 Final Research Report 2010 Self-evaluation Report
  • [Presentation] Direct Alcohol Electro-oxidation in an Intermediate Temperature Fuel Cell2008

    • Author(s)
      J. Otomo, S. Nishida, H. Kato, H. Nagamoto, Y. Oshima
    • Organizer
      PRiME2008, 214^<th> Meeting of The Electrochemical Society
    • Place of Presentation
      米国ハワイ
    • Year and Date
      2008-10-15
    • Related Report
      2008 Annual Research Report
  • [Presentation] リン酸亜鉛系ガラス複合体の合成と中温域におけるプロトン伝導特性2008

    • Author(s)
      嶋田五百里・大友順一郎・大島義人
    • Organizer
      化学工学会第40回秋季大会
    • Place of Presentation
      仙台市東北大学
    • Year and Date
      2008-09-25
    • Related Report
      2008 Annual Research Report
  • [Presentation] Direct Alcohol Electro-oxidation in an Intermediate Temperature Fuel Cell2008

    • Author(s)
      Junichiro Otomo, Satoru Nishida, Hiroyuki Kato, Hidetoshi Nagamoto and Yoshito Oshima
    • Organizer
      PRiME2008(Pacific Rim Meeting on Electrochemical and Solid-State Science) 214th Meeting of The Electrochemical Society
    • Place of Presentation
      Honolulu, Hawaii, Hilton Hawaiian Village
    • Related Report
      2011 Final Research Report 2010 Self-evaluation Report
  • [Remarks]

    • URL

      http://www.oshimalab.k.u-tokyo.ac.jp/

    • Related Report
      2011 Final Research Report
  • [Remarks] ホームページ

    • URL

      http://www.oshimalab.k.u-tokyo.ac.jp/

    • Related Report
      2010 Self-evaluation Report

URL: 

Published: 2008-04-01   Modified: 2016-04-21  

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