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Elucidation of photophysico-chemical properties of single molecular nano-aggregates by using a low-temperature matrix isolation microscopy

Research Project

Project/Area Number 20685001
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Physical chemistry
Research InstitutionShizuoka University

Principal Investigator

MITSUI Masaaki  静岡大学, 理学部, 准教授 (90333038)

Project Period (FY) 2008 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥25,610,000 (Direct Cost: ¥19,700,000、Indirect Cost: ¥5,910,000)
Fiscal Year 2011: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2010: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2009: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2008: ¥11,440,000 (Direct Cost: ¥8,800,000、Indirect Cost: ¥2,640,000)
Keywords分子ナノ集合体 / ナノ粒子 / 顕微分光 / 単一分子分光 / シクロデキストリン / 包接錯体 / 励起三重項状態 / 水素原子移動 / 水素引き抜き / 分子クラスター / 単一分子蛍光分光 / 蛍光 / 光物性 / 励起状態ダイナミクス / クラスター / マトリクス単離 / レーザー走査顕微分光 / ナノ / 発光イメージ / 光子アンチバンチング / 点像分布関数
Research Abstract

We have developed a variable-temperature single-molecule spectroscopy(SMS) apparatus and revealed photo physical/photochemical properties of several organic dyes and their nano-aggregates as follows. 1) The triplet lifetimes, intersystem crossing yields, and photobleaching yields for single-molecules of 9, 10-bis(phenylethynyl) anthracene embedded in polymer films were quantitatively determined. 2) We examined the electronic energy transfer(EET) in tetracence-doped p-terphenyl nanoparticles and theoretically revealed the origin of the extremely efficient EET in this system. 3) SMS of perylene bisimide(PDI) in aγ-cyclodextrin(γCD) solid film was performed, and we found that the hydrogen atom transfer reaction would take place between PDI andγCD in the inclusion complex.

Report

(6 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report   Self-evaluation Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (41 results)

All 2012 2011 2010 2009 2008 Other

All Journal Article (25 results) (of which Peer Reviewed: 25 results) Presentation (9 results) Book (6 results) Remarks (1 results)

  • [Journal Article] 温度可変単一分子蛍光分光測定のための簡易試料基板ホルダーの開発2011

    • Author(s)
      三井正明, 河野祐也, 高橋良弥, 福井洋樹
    • Journal Title

      分光研究

      Volume: 60(4) Pages: 133-135

    • NAID

      10029340850

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Soft-landing experiments of Cr(benzene) 2 sandwich complexes onto a carboxyl-terminated self-assembled monolayer matrix2009

    • Author(s)
      K. Ikemoto, S. Nagaoka, T. Matsumoto, M. Mitsui, A. Nakajima
    • Journal Title

      J. Phys. Chem

      Volume: C113 Pages: 4476-4482

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] An atomic force microscope study of vanadium-benzene sandwich clusters soft-landed on self-assembled monolayers2009

    • Author(s)
      S. Nagaoka, K. Ikemoto, K. Fujio, K. Hiehata, A. Sasahara, M. Mitsui, H. Onishi, A. Nakajima
    • Journal Title

      Eur. Phy. J.

      Volume: D52 Pages: 103-106

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Characterization of alkyl monolayer covalently bonded to Si(111) and soft-landing of vanadium-benzene sandwich clusters onto the alkyl monolayer substrate2009

    • Author(s)
      T. Matsumoto, S. Nagaoka, K. Ikemoto, M. Mitsui, M. Ara, H. Tada, A. Nakajima
    • Journal Title

      Eur. Phy. J.

      Volume: D52 Pages: 99-102

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Soft-landing exper iments of Cr(benzene)2 sandwich complexes onto a carboxyl-terminated self-assembled monolayer matrix2009

    • Author(s)
      K.Ikemoto, S.Nagaoka, T.Matsumoto, M.Mitsui, A.Nakajima
    • Journal Title

      J.Phys.Chem.C 113

      Pages: 4476-4482

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] An atomic force microscope study of vanadium-benzene sandwich clust ers soft-landed on self-assembled mono layers2009

    • Author(s)
      S.Nagaoka, K.Ikemoto, K.Fujio, K.Hiehata, A.Sasahara, M.Mitsui, H.Onishi, A.Nakajima
    • Journal Title

      Eur.Phy.J.D 52

      Pages: 103-106

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Characterization of alkyl monolayer cova lently bonded to Si(111) and soft-landing of vanadium-benzene sandwich clusters onto the alkyl monolayer substrate2009

    • Author(s)
      T.Matsumoto, S.Nagaoka, K.Ikemoto, M.Mitsui, M.Ara, H.Tada, A.Nakajima
    • Journal Title

      Eur.Phy.J.D 52

      Pages: 99-102

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Characterization of alkyl monolayer covalently bonded to Si(111) and soft-landing of vanadium- benzene sandwich clusters onto the alkyl monolayer substrate2009

    • Author(s)
      T.Matsumoto, S.Nagaoka, K.Ikemoto, M.Mitsui, M.Ara, H.Tada, A.Nakajima
    • Journal Title

      European Physical Journal D 52

      Pages: 99-102

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] An atomic force microscope study of vanadium-benzene sandwich clusters soft-landed on self-assembled monolayers2009

    • Author(s)
      S.Nagaoka, K.Ikemoto, K.Fujio, K.Hiehata, A.Sasahara, M.Mitsui, H.Onishi, A.Nakajima
    • Journal Title

      European Physical Journal D 52

      Pages: 103-106

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Soft-landing experiments of Cr(benzene)_2 sandwich complexes onto a carboxyl-terminated self-assembled monolayer matrix2009

    • Author(s)
      K.Ikemoto, S.Nagaoka, T.Matsumoto, M.Mitsui, A.Nakajima
    • Journal Title

      Journal of Physical Chemistry C 113

      Pages: 4476-4482

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Infrared spectroscopy and thermal desorption study of vanadium-mesitylene 1 : 2 sandwich clusters soft landed onto a long-chain n-alkanethiolate self-assembled monolayer2008

    • Author(s)
      M. Mitsui, S. Doi, K. Ikemoto, S. Nagaoka, A. Nakajima
    • Journal Title

      Latest Advances in Atomic Cluster Collisions

      Pages: 199-204

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Soft-landing isolation of gas-phase synthesized transition metal-benzene complexes into a fluorinated self assembled monolayer matrix2008

    • Author(s)
      S. Nagaoka, K. Ikemoto, T. Matsumoto, M. Mitsui, A. Nakajima
    • Journal Title

      J. Phys. Chem

      Volume: C112 Pages: 15824-15831

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Mass PDI1 : 2 PDI-γCD inclusion complex≡pTP(D) 500 nm≡Tc(A) SEM image spectrometry and photoelectron spectroscopy of o-, m-, and p-terphenyl cluster anions : The effect of molecular shape on molecular assembly and ion core character2008

    • Author(s)
      M. Mitsui, N. Ando, A. Nakajima
    • Journal Title

      J. Phys. Chem

      Volume: A112 Pages: 5628-5635

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photoelectron spectroscopy of cluster anions of naphthalene and related aromatic hydrocarbons2008

    • Author(s)
      N. Ando, M. Mitsui, A. Nakajima
    • Journal Title

      J. Chem. Phys

      Volume: 128

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Thermal and hyper thermal collision-energy depositions of transition metal-benzene sandwich complexes onto a self-assembled n-octadecanethiol monolayer2008

    • Author(s)
      S. Nagaoka, K. Ikemoto, T. Matsumoto, M. Mitsui, A. Nakajima
    • Journal Title

      J. Phys. Chem

      Volume: C112 Pages: 6891-6899

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Infrared spectroscopy and thermal desorption study of vanadium -mesitylene 1 : 2 sandwich clusters soft- landed onto a long-chain n-alkanethiolate self-assembled monolayer2008

    • Author(s)
      M.Mitsui, S.Doi, K.Ikemoto, S.Nagaoka, A.Nakajima
    • Journal Title

      Latest Advances in Atomic Cluster Collisions

      Pages: 199-204

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Soft-landing isolation of gas-phase synthesized transition metal -benzene complexes into a fluorinated self- assembled monolayer matrix2008

    • Author(s)
      S.Nagaoka, K.Ikemoto, T.Matsumoto, M.Mitsui, A.Nakajima
    • Journal Title

      J.Phys.Chem.C 112

      Pages: 15824-15831

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Mass spectrometry and photoelectron spectroscopy of o-, m-, and p-terphenyl cluster anions: The effect of molecular shape on molecular assembly and ion core character2008

    • Author(s)
      M.Mitsui, N.Ando, A.Nakajima
    • Journal Title

      J.Phys.Chem.A 112

      Pages: 5628-5635

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Photoelectron spectroscopy of cluster anions of naphthalene and related aromatic hydrocarbons2008

    • Author(s)
      N.Ando, M.Mitsui, A.Nakajima
    • Journal Title

      J.Chem.Phys. 128

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Thermal and hyper thermal collision-energy depositions of trans ition metal-benzene sandwich complexes onto a self-assembled n-octadecanethiol mo nolayer2008

    • Author(s)
      S.Nagaoka, K.Ikemoto, T.Matsumoto, M.Mitsui, A.Nakajima
    • Journal Title

      J.Phys.Chem.C 112

      Pages: 6891-6899

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Thermal and hyperthermal collision-energy depositions of transition metal-benzene sandwich complexes onto a self-assembled n-octadecanethiol monolayer2008

    • Author(s)
      S. Nagaoka, K. Ikemoto, T. Matsumoto, M. Mitsui, A. Nakajima
    • Journal Title

      Journal of Physical Chemistry C 112

      Pages: 6891-6899

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photoelectron spectroscopy of cluster anions of naphthalene and related aromatic hydrocarbons2008

    • Author(s)
      N. Ando, M. Mitsui, A. Nakajima
    • Journal Title

      Journal of Chemical Physics 128

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mass spectrometry and photoelectron spectroscopy of o-, m-, and p-terphenyl cluster anions : The effect of molecular shape on molecular assembly and ion core character2008

    • Author(s)
      M. Mitsui, N. Ando, A. Nakajima
    • Journal Title

      Journal of Physical Chemistry A 112

      Pages: 5628-5635

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Soft-landing isolation of gas-phase synthesized transition metal-benzene complexes into a fluorinated self-assembled monolayer matrix2008

    • Author(s)
      S. Nagaoka, K. Ikemoto, T. Matsumoto, M. Mitsui, A. Nakajima
    • Journal Title

      Journal of Physical Chemistry C 112

      Pages: 15824-15831

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Infrared spectroscopy and thermal desorption study of Vanadium-Mesitylene 1:2 Sandwich Clusters Soft-Landed onto a Long-Chain n-Alkanethiolate Self-Assembled Monolayer2008

    • Author(s)
      M. Mitsui, S. Doi, K. Ikemoto, S. Nagaoka, A. Nakajima
    • Journal Title

      Latest Advances in Atomic Cluster Collisions

      Pages: 199-204

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] 温度可変マルチタスク単一分子蛍光分光装置の開発2011

    • Author(s)
      三井正明,福井洋樹,河野祐也,高橋良弥
    • Organizer
      第5回分子科学討論会
    • Place of Presentation
      札幌コンベンションセンター(北海道)
    • Related Report
      2011 Final Research Report
  • [Presentation] Super-efficient electronic energy transfer in composite organic nanoparticles2011

    • Author(s)
      Yuya Kawano, Masaaki Mitsui
    • Organizer
      第27回化学反応討論会
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都)
    • Related Report
      2011 Final Research Report
  • [Presentation] Single-molecule dynamics of perylene bisimide dyes in cyclodextrin thin films2011

    • Author(s)
      Ryoya Takahashi, Hiroki, Fukui, Masaaki Mitsui
    • Organizer
      第27回化学反応討論会
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都)
    • Related Report
      2011 Final Research Report
  • [Presentation] Super-efficient electronic energy transfer in composite organic nanoparticles2011

    • Author(s)
      Yuya Kawano, Masaaki Mitsui
    • Organizer
      第27回化学反応討論会
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都目黒区)
    • Related Report
      2011 Annual Research Report
  • [Presentation] Single-molecule dynamics of perylene bisimide dyes in cyclodextrin thin films2011

    • Author(s)
      Ryoya Takahashi, Hiroki, Fukui, Masaaki Mitsui
    • Organizer
      第27回化学反応討論会
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都目黒区)
    • Related Report
      2011 Annual Research Report
  • [Presentation] 温度可変マルチタスク単一分子蛍光分光装置の開発2011

    • Author(s)
      三井正明, 福井洋樹, 河野祐也, 高橋良弥
    • Organizer
      第5回分子科学討論会
    • Place of Presentation
      札幌コンベンションセンター(北海道札幌市)
    • Related Report
      2011 Annual Research Report
  • [Presentation] シクロデキストリンと色素の包接錯体の単一分子蛍光分光2010

    • Author(s)
      福井洋樹,三井正明
    • Organizer
      光化学討論会2010
    • Place of Presentation
      千葉大学西千葉キャンパス(千葉県)
    • Year and Date
      2010-09-10
    • Related Report
      2011 Final Research Report
  • [Presentation] シクロデキストリンと色素の包接錯体の単一分子蛍光分光2010

    • Author(s)
      福井洋樹, 三井正明
    • Organizer
      光化学討論会2010
    • Place of Presentation
      千葉大学 西千葉キャンパス(千葉県)
    • Year and Date
      2010-09-10
    • Related Report
      2010 Annual Research Report 2010 Self-evaluation Report
  • [Presentation] 光増感型複合有機ナノ結晶の光物理化学過程と光物性2010

    • Author(s)
      河野祐也,三井正明
    • Organizer
      ナノ学会第8回大会
    • Place of Presentation
      岡崎コンファレンスセンター(愛知県)
    • Year and Date
      2010-05-14
    • Related Report
      2011 Final Research Report 2010 Annual Research Report 2010 Self-evaluation Report
  • [Book] 光化学の事典2012

    • Author(s)
      三井正明, 他(分担執筆)
    • Publisher
      朝倉書店
    • Related Report
      2011 Final Research Report
  • [Book] 光化学の事典だれでもわかる光化学の初歩2012

    • Author(s)
      三井正明, 他(分担執筆)
    • Publisher
      朝倉書店(印刷中)
    • Related Report
      2011 Annual Research Report
  • [Book] Handbook of Nanophysics vol.2 "Clusters and Fullerens"2010

    • Author(s)
      M. Mitsui, A. Nakajima
    • Publisher
      CRC press
    • Related Report
      2011 Final Research Report
  • [Book] Clusters and Fullerens2010

    • Author(s)
      M.Mitsui, A.Nakajima
    • Publisher
      CRC press, Handbook of Nanophysics vol.2
    • Related Report
      2010 Self-evaluation Report
  • [Book] Handbook of Nanophysics vol.2 "Clusters and Fullerens"2010

    • Author(s)
      M.Mitsui, A.Nakajima
    • Publisher
      CRC press
    • Related Report
      2010 Annual Research Report
  • [Book] Handbook of Nanophysics2010

    • Author(s)
      M.Mitsui, A.Nakajima
    • Publisher
      Taylor & Francis
    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://www.sci.shizuoka.ac.jp/~chem/chem-j.html

    • Related Report
      2011 Final Research Report

URL: 

Published: 2008-04-01   Modified: 2016-04-21  

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