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Precise measurements of the PρTx and critical parameters forCO2/hydrocarbon mixtures in the super-critical region

Research Project

Project/Area Number 20686016
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Thermal engineering
Research InstitutionToyama Prefectural University

Principal Investigator

MIYAMOTO Hiroyuki  富山県立大学, 工学部, 准教授 (80348820)

Project Period (FY) 2008 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥25,480,000 (Direct Cost: ¥19,600,000、Indirect Cost: ¥5,880,000)
Fiscal Year 2011: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2010: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2009: ¥7,930,000 (Direct Cost: ¥6,100,000、Indirect Cost: ¥1,830,000)
Fiscal Year 2008: ¥9,490,000 (Direct Cost: ¥7,300,000、Indirect Cost: ¥2,190,000)
Keywords熱物性 / イソブタン / 混合冷媒 / 自然作動流体 / 炭化水素 / 熱力学性質 / ベローズ変容法 / PρTx性質 / CO2 / CO_2
Research Abstract

The precise measurements of PpTx property, saturation properties,and critical parameters have been performed in the liquid, super-critical, and saturationregions for the CO2/hydrocarbon mixtures, which are expected as long-term alternatives forrefrigeration and heat-pump systems. As the results, the reliable measurement data wereobtained in the wide ranges of temperatures, pressures, densities, and compositions. Theobtained data were systematically compared with the available thermodynamic propertymodels, from which the necessity of the improvements of the models could be confirmed.

Report

(6 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report   Self-evaluation Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (55 results)

All 2012 2011 2010 2009 2008 Other

All Journal Article (18 results) (of which Peer Reviewed: 15 results) Presentation (32 results) Remarks (5 results)

  • [Journal Article] (p, ρ, T, x) properties ofCO2/propane binary mixtures at 280 to 440K and 3 to 200 Mpa2012

    • Author(s)
      H. Miyamoto
    • Journal Title

      Int. J. Thermophys

      Volume: 掲載確定 Issue: 9-10 Pages: 1647-1660

    • DOI

      10.1007/s10765-012-1370-2

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Measurement of the (p, ρ, T) Properties for Pure Hydrocarbons at Temperatures up to600 K and Pressures up to 200 Mpa2012

    • Author(s)
      T. Ito, Y Nagata, H. Miyamoto
    • Journal Title

      Int. J.Thermophys

      Volume: 掲載確定 Issue: 9-10 Pages: 1636-1646

    • DOI

      10.1007/s10765-012-1383-x

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] (p,ρ,T,x) properties for CO2/n-butane binarymixtures at T= (280 to 440) K and (3 to200) Mpa2011

    • Author(s)
      T. Sugiyama, S. Orita, H. Miyamoto
    • Journal Title

      J. Chem. Thermodyn

      Volume: 43 Issue: 5 Pages: 645-650

    • DOI

      10.1016/j.jct.2010.11.012

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Theprecise measurement of the (vapour-liquid)equilibrium properties for (CO2 +isobutane) binary mixtures2011

    • Author(s)
      Y. Nagata, K. Mizutani, H. Miyamoto
    • Journal Title

      J. Chem.Thermodyn

      Volume: 43 Issue: 3 Pages: 244-247

    • DOI

      10.1016/j.jct.2010.09.004

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] (p, ρ, T,x) properties for CO2/isobutane binarymixtures at T= (280 to 440) K and (3 to200) Mpa2011

    • Author(s)
      T. Sugiyama, S. Orita, H. Miyamoto
    • Journal Title

      J. Chem. Thermodyn

      Volume: 43 Issue: 12 Pages: 1851-1856

    • DOI

      10.1016/j.jct.2011.06.012

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] The precise measurement of the (vapour-liquid) equilibrium properties for (CO2 + isobutane) binary mixtures2011

    • Author(s)
      Y.Nagata, K.Mizutani, H.Miyamoto
    • Journal Title

      J.Chem.Thermodyn. 43

      Pages: 244-247

    • Related Report
      2010 Self-evaluation Report
  • [Journal Article] (p, ρ , T, x) properties for CO2/n-butane binary mixtures at T=(280 to 440) K and (3 to 200) MPa2011

    • Author(s)
      T.Sugiyama, S.Orita, H.Miyamoto
    • Journal Title

      J.Chem.Thermodyn. 43

      Pages: 645-650

    • Related Report
      2010 Self-evaluation Report
  • [Journal Article] The precise measurement of the (vapour-liquid) equilibrium properties for (CO_2+isobutane) binary mixtures2011

    • Author(s)
      Y.Nagata, K.Mizutani, H.Miyamoto
    • Journal Title

      Journal of Chemical Thermodynamics

      Volume: 43 Pages: 244-247

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] (p,ρ,T,x) properties for CO_2/n-butane binary mixtures at T=(280 to 440) K and (3 to 200) MPa2011

    • Author(s)
      T.Sugiyama, S.Orita, H.Miyamoto
    • Journal Title

      Journal of Chemical Thermodynamics

      Volume: 43 Pages: 645-650

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Measurements of saturated-liquiddensities for isobutane at T = (280 to407)2008

    • Author(s)
      H. Miyamoto, T. Koshi,M. Uematsu
    • Journal Title

      K,J.Chem.Thermodyn

      Volume: 40 Issue: 8 Pages: 1222-1225

    • DOI

      10.1016/j.jct.2008.04.003

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] The(p,ρ,T,x) properties for (propane + n-butane+ isobutane) ternary mixtures over thetemperature range from (280 to 440) K atpressures from (1 to 200) Mpa2008

    • Author(s)
      H. Miyamoto, T. Koshi, M. Uematsu
    • Journal Title

      J. Chem.Thermodyn.

      Volume: 40 Issue: 4 Pages: 558-566

    • DOI

      10.1016/j.jct.2007.12.001

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] The(p,ρ,T,x) properties for (x1 n-butane +x2 isobutane) with x1 = (0.2625,0.4913,and 0.7508) in the temperature rangefrom (280 to 440) K at pressures from (1to 200) Mpa2008

    • Author(s)
      H. Miyamoto, T. Koshi, M. Uematsu
    • Journal Title

      J.Chem.Thermodyn

      Volume: 40 Issue: 4 Pages: 567-572

    • DOI

      10.1016/j.jct.2007.11.013

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] The (p, ρ, T, x) properties for (propane + n-butane + isobutane) ternary mixtures over the temperature range from (280 to 440) K at pressures from (1 to 200) MPa2008

    • Author(s)
      H.Miyamoto, T.Koshi, M.Uematsu
    • Journal Title

      J.Chem.Thermodyn. 40

      Pages: 558-566

    • Related Report
      2010 Self-evaluation Report
  • [Journal Article] The (p, ρ, 7, x) properties for (propane + n-butane + isobutane) ternary mixtures over the temperature range from (280 to 440) K at pressures from (1 to 200) Mpa2008

    • Author(s)
      H. Miyamoto, T. Koshi, M. Uematsu
    • Journal Title

      Journal of Chemical Thermodynamics 40

      Pages: 558-566

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The (p, ρ, 7, x) properties for (x_1 n-butane + x_2 isobutane) with x_1=(0.2625, 0.4913, and 0.7508) in the temperature range from (280 to 440) K at pressures from (1 to 200) Mpa2008

    • Author(s)
      H. Miyamoto, T. Koshi, M. Uematsu
    • Journal Title

      Journal of Chemical Thermodynamics 40

      Pages: 567-572

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Measurements of saturated-liquid densities for isobutane at T=(280 to 407) K2008

    • Author(s)
      H. Miyamoto, T. Koshi, M. Uematsu
    • Journal Title

      Journal of Chemical Thermodynamics 40

      Pages: 1222-1225

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Measurements of the critical parameters for {xNH_3+(1-x)H_2O} with x=(0.9098, 0.7757, 0.6808)2008

    • Author(s)
      A. Sakabe, D. Arai, H. Mivamoto. M. Uematsu
    • Journal Title

      Journal of Chemical Thermodynamics 40

      Pages: 1527-1530

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The (p, ρ, T, x) properties for {xNH_3+(1-x)H_2O} at T=(450, and 500) K over the pressure range from (10 to 200) Mpa2008

    • Author(s)
      S. Muromachi, H. Miyamoto, M. Uematsu
    • Journal Title

      Journal of Chemical Thermodynamics 40

      Pages: 1594-1599

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] Measurements of the ppTx properties for thehydrocarbons and their mixtures in thetemperature range to 600 K at pressures upto 200 Mpa2012

    • Author(s)
      T. Ito, Y. Nagata, H. Miyamoto
    • Organizer
      18th Symp. Thermophys. Prop
    • Place of Presentation
      Boulder, Co,USA
    • Related Report
      2011 Final Research Report
  • [Presentation] CO2/炭化水素二成分混合系の気液平衡性質および臨界軌跡に関する研究2012

    • Author(s)
      南岳悠・宮本泰行
    • Organizer
      第33回日本熱物性シンポジウム
    • Place of Presentation
      大阪
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] Measurements of the pρTx properties for the hydrocarbons and their mixtures in the temperature range to 600 K at pressures up to 200 MPa2012

    • Author(s)
      T. Ito, Y. Nagata, H. Miyamoto
    • Organizer
      18th Symposium on Thermophysical Properties
    • Place of Presentation
      Boulder, Co, USA
    • Related Report
      2011 Annual Research Report
  • [Presentation] Precise measurements of pρTx properties for CO2-propane systems in the temperature range from (280 to 440) K at pressures from (1 to 200) MPa2012

    • Author(s)
      H. Miyamoto
    • Organizer
      18th Symposium on Thermophysical Properties
    • Place of Presentation
      Boulder, Co, USA
    • Related Report
      2011 Annual Research Report
  • [Presentation] 自然冷媒系混合物の実用化に不可欠な熱物性データの精密測定2012

    • Author(s)
      宮本泰行
    • Organizer
      第49回日本伝熱シンポジウム
    • Place of Presentation
      富山
    • Related Report
      2011 Annual Research Report
  • [Presentation] セミクラスレート生成系(Carbon Dioxide + Tetrabutylammonium Bromide + Water)における炭酸ガスの溶解度測定2012

    • Author(s)
      室町実大・四十万淳・宮本泰行・大村亮
    • Organizer
      第33回日本熱物性シンポジウム
    • Place of Presentation
      大阪
    • Related Report
      2011 Annual Research Report
  • [Presentation] 自然作動流体n-butaneの臨界定数の精密測定2011

    • Author(s)
      伊藤崇善・山口昇悟・宮本泰行
    • Organizer
      可視化情報学会全国講演会(富山2011)
    • Place of Presentation
      富山
    • Related Report
      2011 Annual Research Report
  • [Presentation] 200 MPaまでの高圧域におけるCO2-炭化水素系のPVTx性質2011

    • Author(s)
      宮本泰行・丹羽良太朗
    • Organizer
      第52回高圧討論会
    • Place of Presentation
      沖縄
    • Related Report
      2011 Annual Research Report
  • [Presentation] ThePrecise Measurements of the Vapor-LiquidEquilibrium Properties for CO2/isobutaneBinary Mixtures2010

    • Author(s)
      Y. Nagata, K. Mizutani, H. Miyamoto
    • Organizer
      21th IUPAC Int. Conf.Chem. Thermodyn
    • Place of Presentation
      Tsukuba, Japan
    • Related Report
      2011 Final Research Report
  • [Presentation] The Precise Measurements of the Vapor-Liquid Equilibrium Properties for CO2/isobutane Binary Mixtures2010

    • Author(s)
      Y.Nagata, K.Mizutani, H.Miyamoto
    • Organizer
      21th IUPAC Int.Conf.Chem.Thermodyn.
    • Place of Presentation
      Tsukuba, Japan
    • Related Report
      2010 Self-evaluation Report
  • [Presentation] Measurement of the Critical Parameters for n-Butane2010

    • Author(s)
      Y.Nishira, Y.Sato, R.Kawasaka, H.Miyamoto
    • Organizer
      21th IUPAC International Conference on Chemical Thermodynamics
    • Place of Presentation
      Tsukuba, Japan
    • Related Report
      2010 Annual Research Report
  • [Presentation] (p.ρ,T,x) properties for CO_2/n-butane binary mixtures in the temperature range from (280 to 440) K at pressures from (1 to 200) MPa2010

    • Author(s)
      T.Sugiyama, S.Orita, H.Miyamoto
    • Organizer
      21th IUPAC International Conference on Chemical Thermodynamics
    • Place of Presentation
      Tsukuba, Japan
    • Related Report
      2010 Annual Research Report
  • [Presentation] The Precise Measurements of the Vapor-Liquid Equilibrium Properties for CO_2/isobutane Binary Mixtures2010

    • Author(s)
      Y.Nagata, K.Mizutani, H.Miyamoto
    • Organizer
      21th IUPAC International Conference on Chemical Thermodynamics
    • Place of Presentation
      Tsukuba, Japan
    • Related Report
      2010 Annual Research Report
  • [Presentation] PρT measurements of propane and n-butane in the temperature range to 600 K at pressures up to 200 MPa.2010

    • Author(s)
      T.Ito, Y.Nagata, H.Miyamoto
    • Organizer
      21th IUPAC International Conference on Chemical Thermodynamics
    • Place of Presentation
      Tsukuba, Japan
    • Related Report
      2010 Annual Research Report
  • [Presentation] 自然冷媒系混合流体の気液平衡性質の精密測定2010

    • Author(s)
      永田義和・水谷和紀・宮本泰行
    • Organizer
      可視化情報学会全国講演会(鹿児島2010)
    • Place of Presentation
      鹿児島
    • Related Report
      2010 Annual Research Report
  • [Presentation] 200 MPaまでの高圧域における炭化水素系混合物のPVTx性質および過剰モル体積の精密測定2010

    • Author(s)
      杉山貴紀・折田誠吾・宮本泰行
    • Organizer
      第31回日本熱物性シンポジウム
    • Place of Presentation
      福岡
    • Related Report
      2010 Annual Research Report
  • [Presentation] Precise measurements of ppTx properties for CO-hydrocarbon systems in thetemperature range from 280 to 440 K atpressures from 1 to 200 Mpa, 17th Symp.Thermophys. Prop2009

    • Author(s)
      T. Sugiyama, H. Miyamoto
    • Organizer
      17th Symp.Thermophys. Prop
    • Place of Presentation
      Boulder, Co, USA
    • Related Report
      2011 Final Research Report
  • [Presentation] Measurements of ppTx and criticalparameters for hydrocarbons and theirmixtures in temperatures to 600 K atpressures to 200 Mpa2009

    • Author(s)
      Y. Nishira, Y. Nagata, H. Miyamoto
    • Organizer
      17th Symp.Thermophys. Prop
    • Place of Presentation
      Boulder, Co, USA
    • Related Report
      2011 Final Research Report
  • [Presentation] Precise measurements of pρTx properties for CO2-hydrocarbon systems in the temperature range from 280 to 440 K at pressures from 1 to 200 MPa2009

    • Author(s)
      T.Sugiyama, H.Miyamoto
    • Organizer
      17th Symp.Thermophys.Prop.
    • Place of Presentation
      Boulder, Co, USA.
    • Related Report
      2010 Self-evaluation Report
  • [Presentation] Measurements of PρTx and critical parameters for hydrocarbons nad their mixtures in temperatures to 600K at pressures to 200Mpa2009

    • Author(s)
      Y.Nishira, Y.Nagata, H.Miyamoto
    • Organizer
      17th Symposium on Thermophysical Properties
    • Place of Presentation
      Boulder, Co, USA
    • Related Report
      2009 Annual Research Report
  • [Presentation] Precise measurements of PρTx properites for CO_2-hydrocarbon systems in the temperature range from 280 to 440K at pressures from 1 to 200Mpa2009

    • Author(s)
      T.Sugiyama, H.Miyamoto
    • Organizer
      17th Symposium on Thermophysical Properties
    • Place of Presentation
      Boulder, Co, USA
    • Related Report
      2009 Annual Research Report
  • [Presentation] 高温高圧流体のPρTx性質精密測定2009

    • Author(s)
      宮本泰行
    • Organizer
      化学工学会 第41回秋季大会
    • Place of Presentation
      広島
    • Related Report
      2009 Annual Research Report
  • [Presentation] Aspect of natural refrigerant and physical properties2009

    • Author(s)
      H.Miyamoto
    • Organizer
      Northeastern Asian Symposium of Environment Physical Property and Material in Ube-2009
    • Place of Presentation
      山口
    • Related Report
      2009 Annual Research Report
  • [Presentation] 高温高圧域におけるCO_2-炭化水素系冷媒のPρTx性質に関する精密測定2009

    • Author(s)
      杉山貴紀・宮本泰行
    • Organizer
      第30回日本熱物性シンポジウム
    • Place of Presentation
      山形
    • Related Report
      2009 Annual Research Report
  • [Presentation] 自然冷媒系混合流体の気液平衡性質の精密測定に関する研究2009

    • Author(s)
      永田義和・伊藤崇喜・宮本泰行
    • Organizer
      第30回日本熱物性シンポジウム
    • Place of Presentation
      山形
    • Related Report
      2009 Annual Research Report
  • [Presentation] 高温・高圧域におけるアンモニア/水混合系の臨界軌跡の精密測定2008

    • Author(s)
      坂部昭憲・宮本泰行・上松公彦
    • Organizer
      2008年度日本冷凍空調学会年次大会
    • Place of Presentation
      大阪
    • Year and Date
      2008-10-21
    • Related Report
      2008 Annual Research Report
  • [Presentation] 高温高圧の自然冷媒系混合流体の熱物性精密測定に関する研究2008

    • Author(s)
      坂部昭憲・宮本泰行・上松公彦
    • Organizer
      第29回日本熱物性シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2008-10-08
    • Related Report
      2008 Annual Research Report
  • [Presentation] Precise measurements of the ppTx andcritical properties for the ammonia-watersystems in the temperature range from (437to 503) K at pressures up to 200 Mpa2008

    • Author(s)
      A Sakabe, H. Miyamoto, M. Uematsu
    • Organizer
      15thInt. Conf. Prop. Water and Steam (15thICPWS)
    • Place of Presentation
      Berlin,Germany
    • Related Report
      2011 Final Research Report
  • [Presentation] Precise measurements of the prTx and critical properties for the ammonia-water systems in the temperature range from (437 to 503) K at pressures up to 200 MPa2008

    • Author(s)
      A Sakabe, H.Miyamoto, M.Uematsu
    • Organizer
      15th Int.Conf.Prop.Water and Steam (15th ICPWS)
    • Place of Presentation
      Berlin, Germany
    • Related Report
      2010 Self-evaluation Report
  • [Presentation] Precise measurements of the pρTx and critical properties for the ammoni a-water systems in the temperature range from (437 to 503) K at pressures up to 200 Mpa2008

    • Author(s)
      A Sakabe, H. Miyamoto, M. Uematsu
    • Organizer
      15th International Conference on the Properties of Water and Steam (15th ICPWS)
    • Place of Presentation
      Berlin, Germany
    • Related Report
      2008 Annual Research Report
  • [Presentation] Precise thermodynamic property measurements for the ammonia-water systems in higher ranges of temperatures and pressures2008

    • Author(s)
      A Sakabe, H. Miyamoto, M. Uematsu
    • Organizer
      2nd International Forum on Heat Transfer (IFHT)
    • Place of Presentation
      Tokyo, Japan
    • Related Report
      2008 Annual Research Report
  • [Presentation] 自然冷媒系混合物の実用化に不可欠な熱物性データの精密測定

    • Author(s)
      宮本泰行
    • Organizer
      富山県立大学―ASME日本支部共催 「もの作り講演会」
    • Place of Presentation
      富山
    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://www.pu-toyama.ac.jp/renkei/img/t-soran/miyamoto.pdf

    • Related Report
      2011 Final Research Report
  • [Remarks] 研究者紹介(富山県立大学)

    • URL

      http://www.pu-toyama.ac.jp/renkei/img/t-soran/miyamoto.pdf

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://www.pu-toyama.ac.jp/renkei/img/t-soran/miyamoto.pdf

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.pu-toyama.ac.jp/renkei/img/t-soran/miyamoto.pdf

    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://www.pu-toyama.ac.jp/renkei/img/H20soran/miyamoto.pdf

    • Related Report
      2008 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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