Facile synthesis of metal nano-wires aligned in atomic level using polymeric templates

• Project/Area Number: 20710081
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Nanomaterials/Nanobioscience
• Research Institution: Yamagata University
• Principal Investigator: OCHIAI Bungo Yamagata University, 大学院・理工学研究科, 准教授 (20361272)
• Project Period (FY): 2008 – 2009
• Project Status: Completed (Fiscal Year 2009)
• Budget Amount: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000); Fiscal Year 2009: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000); Fiscal Year 2008: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
• Keywords: ポリマー / 金属ナノワイヤー / イオウ / グラフトコポリマー

Research Abstract

A facile synthetic method for graft copolymers with controllable molecular weight was established via combination of polyaddition and conventional free radical polymerization. Nano-wires containing metal salts were successfully synthesized via the addition of metal salts to the C=S moieties in the stem chains of the graft copolymers. Reducing the metal salt yielded nano-wires containing 0-valent metals. In addition, highly refractive nano-particles were developed by applying this method to nano-particle synthesis.

Research Products

• [Journal Article] Synthesis of refractive star-shaped polysulfide by anionic polymerization of phenoxy propylene sulfide using an initiating system consisting of trifunctional thiol derived from five-membered cyclic dithiocarbonate and amine. (2010)
  • Author(s): Hirata, M.; Ochiai, B.; Endo, T.
  • Journal Title: J. Polym. Sci., Part A: Polym. Chem. 48 Pages: 525-531
  • Peer Reviewed
• [Journal Article] Synthesis of refractive star-shaped polysulfide by anionic polymerization of phenoxy propylene sulfide using an initiating system consisting of trifunctional thiol derived from five-membered cyclic dithiocarbonate and amine (2010)
  • Author(s): Hirata, M., Ochiai, B., Endo, T.
  • Journal Title: J.Polym.Sci., Part A : Polym.Chem. 48 Pages: 525-531
  • Peer Reviewed
• [Journal Article] One-pot synthesis of graft copolymer by combination of free radical polymerization and polyaddition. (2009)
  • Author(s): Ochiai, B.; Kato, Y.; Endo, T.
  • Journal Title: Macromolecules 42 Pages: 8001-8002
  • Peer Reviewed
• [Journal Article] Polyaddition of bifunctional cyclic carbonate with diamine in ionic liquids: in situ ion composite formation and simple separation of ionic liquid Ochiai (2009)
  • Author(s): B.; Satoh, Y.; Endo, T.
  • Journal Title: J. Polym. Sci., Part A: Polym. Chem. 47 Pages: 4629-4635
  • Peer Reviewed
• [Journal Article] Synthesis of rare-metal absorbing polymer by three-component polyaddition through combination of chemo-selective nucleophilic and radical additions Ochiai (2009)
  • Author(s): B.; Ogihara, T.; Mashiko, M.; Endo, T.
  • Journal Title: J. Am. Chem. Soc. 131 Pages: 1636-1637
  • Peer Reviewed
• [Journal Article] Polyaddition of bifunctional cyclic carbonate with diamine in ionic liquids : in situ ion composite formation and simple separation of ionic liquid (2009)
  • Author(s): Ochiai, B., Satoh, Y., Endo, T.
  • Journal Title: J.Polym.Sci., Part A : Polym.Chem. 47 Pages: 4629-4635
  • Peer Reviewed
• [Journal Article] One-pot synthesis of graft copolymer by combination of free radical polymerization and polyaddition (2009)
  • Author(s): Ochiai, B., Kato, Y., Endo, T.
  • Journal Title: Macromolecules 42 Pages: 8001-8002
  • Peer Reviewed
• [Journal Article] Synthesis of rare-metal absorbing polymer by three-component polyad dition through combination of chemo-selective nucleophilic and radical additions (2009)
  • Author(s): Ochiai, B. ; Ogihara, T. ; Mashik o, M. ; Endo, T.
  • Journal Title: J. Am. Chem. Soc. 131 Pages: 1636-1637
  • Peer Reviewed
• [Journal Article] Thermally latent reaction of hemiacetal ester with epoxide catalyzed by rcyclable polymeric catalyst consisting of Salen-zinc complex and polyurethane main chain Komatsu (2008)
  • Author(s): H.; Ochiai, B.; Endo, T.
  • Journal Title: J. Polym. Sci., Part A: Polym. Chem. 46 Pages: 3673-3681
  • Peer Reviewed
• [Journal Article] Solid-supported synthesis of well-defined amphiphilic block copolymer from methacrylates Nagai (2008)
  • Author(s): D.; Fujii, A.; Ochiai, B.; Sudo, A.; Endo, T.
  • Journal Title: J. Polym. Sci., Part A: Polym. Chem. 46 Pages: 1990-1997
  • Peer Reviewed
• [Journal Article] Solid-supported synthesis of well-defined amphiphilic block copolymer from methacrvlates (2008)
  • Author(s): Nagai, D. ; Fujii, A. ; Ochiai, B. ; Sudo, A. ; Endo, T.
  • Journal Title: J. Polym. Sci., Part A : Polym. Chem 46 Pages: 1990-1997
  • Peer Reviewed
• [Journal Article] Thermally latent reaction of hemiacetal ester with epoxide catalyzed b y rcyclable polymeric catalyst consisting of Salen-zinc complex and p olyurethane main chain (2008)
  • Author(s): Komatsu, H. ; Ochiai, B. ; Endo, T.
  • Journal Title: J. Polym. Sci., Part A : Polym. Chem 46 Pages: 3673-3681
  • Peer Reviewed
• [Presentation] 二酸化炭素および二硫化炭素を用いる高分子合成 (2010)
  • Author(s): 落合文吾
  • Organizer: 高分子学会関東支部第24回群馬・栃木地区講演会
  • Place of Presentation: 群馬大学工学部
  • Year and Date: 2010-03-09
• [Presentation] 二酸化炭素および二硫化炭素とエポキシドの反応を利用する高分子合成 (2010)
  • Author(s): 落合文吾
  • Organizer: 2009年度高分子学会中国四国支部高分子講演会
  • Place of Presentation: 岡山大学環境理工学部
  • Year and Date: 2010-01-20
• [Presentation] 二酸化炭素・二硫化炭素を利用した高分子合成 (2009)
  • Author(s): 落合文吾
  • Organizer: 第18回ポリマー材料フォーラム
  • Place of Presentation: タワーホール船堀
  • Year and Date: 2009-11-27
• [Presentation] 二酸化炭素・二硫化炭素を利用する高分子合成 (2009)
  • Author(s): 落合文吾
  • Organizer: 次世代ポリエステル材料設計研究会
  • Place of Presentation: 名古屋工業大学
  • Year and Date: 2009-06-19
• [Remarks] ホームページ等
  • URL: http://ochiai.yz.yamagata-u.ac.jp
• [Remarks]
  • URL: http://ochiai.yz.yamagata-u.ac.jp
• [Patent(Industrial Property Rights)] 多官能チオールと金属化合物との重縮合反応による金属錯体ならびに有機-無機ハイブリッド材料 (2010)
  • Inventor(s): 落合文吾、今田裕久
  • Industrial Property Rights Holder: 国立大学法人山形大学
  • Industrial Property Number: 2010-108776
  • Filing Date: 2010-05-10
  • Acquisition Date: 2010-05-10