In-situ spectroscopic observations of surface speciation of anions in water-oxides interfaces

• Project/Area Number: 20740315
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Geochemistry/Astrochemistry
• Research Institution: Kanazawa University
• Principal Investigator: FUKUSHI Keisuke Kanazawa University, 環日本海域環境研究センター, 助教 (90444207)
• Project Period (FY): 2008 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000); Fiscal Year 2010: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000); Fiscal Year 2009: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000); Fiscal Year 2008: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
• Keywords: 表面化学種 / その場全減衰反射赤外分光法 / 表面錯体モデリング / フェリハイドライト / 酸化物 / 硫酸 / ヨウ素酸 / ヨウ化物イオン / TR-FTIR / モノハイドロカルサイト / リン酸 / ATR-FTIR / ヨウ素酸イオン / ヒ酸

Research Abstract

Surface speciation of anionic species as function of environmental parameters were invesgitated by using surface complexation modeling and in-situ spectroscopic observations. This study showed that iodide adsorbs to oxide surfaces as outer-sphere complex. Iodate takes both inner- and outer-sphere complexes on oxide surfaces. Sulfate adsorbs to ferrihydrite as inner-sphere complex.

Research Products

• [Journal Article] Phosphate sorption on monohydrocalcite. (2011)
  • Author(s): Yagi, S., Fukushi, K
  • Journal Title: Journal of Mineralogical and Petrological Sciences 106 Pages: 109-113
  • NAID: 130005054342
  • Peer Reviewed
• [Journal Article] Quantification of the effects of organic and carbonate buffers on arsenate and phosphate adsorption on a goethite-based granular porous adsorbent. (2011)
  • Author(s): Kanematsu, M., Young T.M., Fukushi, K., Sverjensky, D., Green, P.G., Darby, J.L.
  • Journal Title: Environmental Science and Technology 45 Pages: 561-568
  • Peer Reviewed
• [Journal Article] Quantification of the effects of organic and carbonate buffers on arsenate and phosphate adsorption on a goethite-based granular porous adsorbent. (2011)
  • Author(s): Kanematsu, M.Young T.M., Fukushi, K.Sverjensky, D.Green, P.G., Darby, J.L.
  • Journal Title: Environmental Science and Technology Volume: 45 Pages: 561-568
  • Peer Reviewed
• [Journal Article] Synthesis of nano-sized boehmites for optimum phosphate sorption. (2011)
  • Author(s): Watanabe, Y.Kasama, T.Fukushi, K.Ikoma, T.Komatsu, Y.Tanaka, J.Moriyoshi, Y., Yamada, H.
  • Journal Title: Separation Science and Technology Volume: 46 Pages: 818-824
  • Peer Reviewed
• [Journal Article] Prediction of iodate adsorption and surface speciation on oxides by surface complexation modeling. (2010)
  • Author(s): Nagata T, Fukushi, K.
  • Journal Title: Geochimica etCosmochimica Acta 74 Pages: 6000-6013
  • Peer Reviewed
• [Journal Article] Iron-bentonite interactions in the Kawasaki bentonite deposit, Zao area, Japan. (2010)
  • Author(s): Fukushi, K., Sugiura, T., Morishita, T., Takahashi, Y., Hasebe, N., Ito, H.
  • Journal Title: Applied Geochemistry 25 Pages: 1120-1132
  • Peer Reviewed
• [Journal Article] Iron-bentonite interactions in the Kawasaki bentonite deposit, Zao area, Japan. (2010)
  • Author(s): Fukushi, K.Sugiura, T.Morishita, T.Takahashi, Y.Hasebe, N., Ito, H.
  • Journal Title: Applied Geochemistry Volume: 25 Pages: 1120-1132
  • Peer Reviewed
• [Journal Article] Prediction of iodate adsorption and surface speciation on oxides by surface complexation modeling. (2010)
  • Author(s): Nagata T, Fukushi, K.
  • Journal Title: Geochimica et Cosmochimica Acta Volume: 74 Pages: 6000-6013
  • Peer Reviewed
• [Journal Article] 鉱物による無機陰イオン種の吸着に関する研究 (2010)
  • Author(s): 福士圭介
  • Journal Title: 若石鉱物科学 Volume: 39 Pages: 19-25
  • NAID: 10025996582
  • Peer Reviewed
• [Journal Article] 鉱物による無機陰イオン種の吸着に関する研究 (2010)
  • Author(s): 福士圭介
  • Journal Title: 岩石鉱物科学 39 Pages: 19-25
  • NAID: 10025996582
• [Journal Article] Extended Triple Layer Modeling of Arsenate and Phosphate Adsorption on A Goethite-based Gracular Porous Adsorbent (2010)
  • Author(s): Kanematsu M, Young T, Fukushi K, Green P, Darby J
  • Journal Title: Environmental Science and Technology (In press)
  • Peer Reviewed
• [Journal Article] Prediction of iodide adsorption on oxides by surface complexation modeling with spectroscopic confirmation. (2009)
  • Author(s): Nagata, T., Fukushi, K., Takahashi Y.
  • Journal Title: Journal of Colloid and Interface Science 332 Pages: 309-316
  • Peer Reviewed
• [Journal Article] 水-鉱物相互作用の素過程としてみた吸着反応 (2009)
  • Author(s): 福士圭介
  • Journal Title: 粘土科学 48 Pages: 82-91
• [Journal Article] Prediction of iodide adsorption on oxides by surface complexation modeling with spectroscopic confirmation (2009)
  • Author(s): Nagata, T. Fukushi, K. and Takahashi Y.
  • Journal Title: Journal of Colloid and Interface Science 332 Pages: 309-316
  • Peer Reviewed
• [Journal Article] Transformation kinetics of monohydrocalcite to aragonite in aqueous solution. (2008)
  • Author(s): Munemoto, T., Fukushi, K.
  • Journal Title: Journal of Mineralogical and Petrological Sciences 103 Pages: 345-349
  • NAID: 10022079497
  • Peer Reviewed
• [Journal Article] Transformation kinetics of monohydrocalcite to aragonite in aqueous solution (2008)
  • Author(s): Munemoto, T. and Fukushi, K.
  • Journal Title: Journal of Mineralogical and Petrological Sciences 203 Pages: 345-349
  • NAID: 10022079497
  • Peer Reviewed
• [Journal Article] 粘土によるイオン吸着のモデリング (2008)
  • Author(s): 福士圭介
  • Journal Title: 粘土科学 47 Pages: 93-103
• [Journal Article] 酸化物による無機陰イオンの吸着-吸着実験による巨視的吸着挙動とその場分光分析による微視的表面錯体構造 (2008)
  • Author(s): 福士圭介
  • Journal Title: 粘土科学 47 Pages: 121-158
  • NAID: 110006990308
• [Presentation] Arsenate and phosphate removal by fixed-bed adsorbers packed with a goethite-based adsorbent : Effects of water quality and operating conditions (2011)
  • Author(s): Kanematsu M, Young TM, Fukushi K, Green PG, Darby JL
  • Organizer: 241st ACS National meeting
  • Place of Presentation: Anaheim, USA
• [Presentation] Extended triple layer modeling arsenate adsorption on a nanostructured goethite-based granular porous adsorbent in the presence of major co-existing ions (2011)
  • Author(s): Kanematsu M, Young TM, Fukushi K, Green PG, Darby JL
  • Organizer: 241st ACS National meeting
  • Place of Presentation: Anaheim, USA
• [Presentation] モノハイドロカルサイトによるリン酸の取り込み (2010)
  • Author(s): 八木新大朗・福士圭介
  • Organizer: 地球惑星科学連合2010年大会
  • Place of Presentation: 千葉幕張メッセ
  • Year and Date: 2010-05-23
• [Presentation] 水溶液中における酸化マグネシウムの相変化挙動 (2010)
  • Author(s): 矢部太章・福士圭介・伊藤弘志
  • Organizer: 地球惑星科学連合2010年大会
  • Place of Presentation: 千葉幕張メッセ
  • Year and Date: 2010-05-23
• [Presentation] 鉄を含む溶液によるベントナイト変質 (2010)
  • Author(s): 長谷川優介・杉浦朋典・福士圭介・森下知晃
  • Organizer: 地球惑星科学連合2010年大会
  • Place of Presentation: 千葉幕張メッセ
  • Year and Date: 2010-05-23
• [Presentation] 瑞浪超深地層研究所における地球化学的研究-地下施設建設が周辺環境へ与える影響の把握- (2010)
  • Author(s): 水野崇・福士圭介・Abdelgawad M.bdelrahaman・竹内真司・渡辺邦夫
  • Organizer: 地球惑星科学連合2010年大会
  • Place of Presentation: 千葉幕張メッセ
  • Year and Date: 2010-05-23
• [Presentation] 先進的表面錯体モデリングによる酸化物への陰イオン吸着挙動の予測 (2010)
  • Author(s): 福士圭介
  • Organizer: 日本地球化学会第57回年会
  • Place of Presentation: 立正大学(埼玉)(奨励賞受賞講演)
• [Presentation] Prediction of Iodine (I- and IO3-)Adsorption and Surface Speciation onOxides by Surface Complexation Modeling (2010)
  • Author(s): Fukushi K. Nagata T., Takahashi Y
  • Organizer: Goldschmidt2010
  • Place of Presentation: Knoxville, USA
• [Presentation] Mineralogy of long drill core from Darhad Basin in Northern Mongolia (2010)
  • Author(s): Fukushi K, Fuchizaki M, Hasebe N, Kashiwaya K
  • Organizer: The 8th international symposium on Environmental Processes of East Eurasia
  • Place of Presentation: Kunming, China
• [Presentation] In situ ATR-FTIR observation of sulfate on ferrihydrite (2010)
  • Author(s): Aoyama K, Fukushi K
  • Organizer: Present Earth Surface Processes and Histrical Environmental Changes in East Asia
  • Place of Presentation: Jeju, Korea
• [Presentation] Approaches to estimate alteration age and temperature of bentonite (2010)
  • Author(s): Yamada H, Hasebe N, Fukushi K, Hasebe A, Arai S
  • Organizer: Present Earth Surface Processes and Histrical Environmental Changes in East Asia
  • Place of Presentation: Jeju, Korea
• [Presentation] Arsenate removal by monohydrocalcite (2010)
  • Author(s): Fukushi K, Sakai M., Munenoto T
  • Organizer: Present Earth Surface Processes and Histrical Environmental Changes in East Asia
  • Place of Presentation: Jeju, Korea
• [Presentation] モノハイドロカルサイトによるリン酸の取り込み (2010)
  • Author(s): 八木新大朗・福士圭介
  • Organizer: 日本鉱物科学会2010年年会
  • Place of Presentation: 島根大学
• [Presentation] ATR-FTIRによるフェリハイドライト表面における硫酸吸着反応のその場観察 (2010)
  • Author(s): 青山和樹・福士圭介
  • Organizer: 日本鉱物科学会2010年年会
  • Place of Presentation: 島根大学
• [Presentation] 酸化物へのモリブデン酸吸着の表面錯体モデリング (2010)
  • Author(s): 福士圭介・Dimitri A.Sverjensky
  • Organizer: 日本鉱物科学会2010年年会
  • Place of Presentation: 島根大学
• [Presentation] Extended Triple Layer Modelによるフェリハイドライトへの硫酸吸着挙動の解析 (2010)
  • Author(s): 青山和樹・福士圭介
  • Organizer: 日本地球化学会第57回年会
  • Place of Presentation: 立正大学
• [Presentation] 先進的表面錯体モデリングによる酸化物への陰イオン吸着挙動の予測(奨励賞受賞講演) (2010)
  • Author(s): 福士圭介
  • Organizer: 日本地球化学会第57回年会
  • Place of Presentation: 立正大学(招待講演)
• [Presentation] 水溶液中における酸化マグネシウムの相変化挙動 (2010)
  • Author(s): 矢部太章・福士圭介・伊藤弘志
  • Organizer: 第54回粘土科学討論会
  • Place of Presentation: 名古屋大学
• [Presentation] 鉄を含む溶液によるベントナイト変質 (2010)
  • Author(s): 長谷川優介・杉浦朋典・福士圭介・森下知晃・大橋竜太郎
  • Organizer: 第54回粘土科学討論会
  • Place of Presentation: 名古屋大学
• [Presentation] ベントナイトの変質年代決定の試み (2010)
  • Author(s): 山田浩史・長谷部徳子・福士圭介・田村明弘
  • Organizer: 第54回粘土科学討論会
  • Place of Presentation: 名古屋大学
• [Presentation] シュベルトマナイトによるヒ素吸着に及ぼす腐植物質の影響 (2010)
  • Author(s): 岡道隆・木戸良介・高松裕美・福士圭介・汲田幹夫・川西琢也
  • Organizer: 化学工学会第42回秋季大会
  • Place of Presentation: 同志社大学
• [Presentation] Surface Speciation of Sulfate at Mineral-Water Interfaces (2010)
  • Author(s): Aoyama K., Fukushi K.
  • Organizer: Goldschmidt2010
  • Place of Presentation: Knoxville, USA
• [Presentation] Prediction of Iodine (I- and IO3-) Adsorption and Surface Speciation on Oxides by Surface Complexation Modeling (2010)
  • Author(s): Fukushi K.Nagata T., Takahashi Y
  • Organizer: Goldschmidt2010
  • Place of Presentation: Knoxville, USA
• [Presentation] Formation and Stability of Monohydrocalcite (2010)
  • Author(s): Munemoto T., Fukushi K.
  • Organizer: Goldschmidt2010
  • Place of Presentation: Knoxville, USA
• [Presentation] Prediction of arsenate and phosphate adsorption on goethite-based granular porous adsorbent using the extended triiple layer model (ETLM) (2010)
  • Author(s): Kanematsu M, Young TM, Fukushi K, Green PG, Darby JL
  • Organizer: 239th ACS National meeting
  • Place of Presentation: San Francisco
• [Presentation] Effects of carbonate on adsorption and mobility of arsenate near the maximum contaminated level (MCL) on a goethite-based porous adsorbent (2010)
  • Author(s): Kanematsu M, Young TM, Fukushi K, Green PG, Darby JL
  • Organizer: 239th ACS National meeting
  • Place of Presentation: San Francisco
• [Presentation] Arsenate uptake by monohydrocalcite (2010)
  • Author(s): Fukushi K.Sakai M., Munemoto T.(招待講演)
  • Organizer: Joint Conference of NIMS International Workshop on Photocatalysis and Environmental Remediation Materials 2010 & 3rd Japan-China Symposium on Advanced Potocatalytic Materials
  • Place of Presentation: 物質・材料研究機構(茨城県)
• [Presentation] 水-フェリハイドライト界面における硫酸の表面化学種分布 (2009)
  • Author(s): 青山和樹・福士圭介・永田貴洋
  • Organizer: 日本地球惑星科学連合2009年大会
  • Place of Presentation: 幕張メッセ (千葉県)
  • Year and Date: 2009-05-17
• [Presentation] モノハイドロカルサイトによるヒ酸の取り込み (2009)
  • Author(s): 酒井実・宗本隆志・福士圭介
  • Organizer: 日本地球惑星科学連合2009年大会
  • Place of Presentation: 幕張メッセ (千葉県)
  • Year and Date: 2009-05-17
• [Presentation] 地球表層での水-鉱物相互作用におよぼす吸着の重要性 (2009)
  • Author(s): 福士圭介
  • Organizer: 鉱物科学会2009年年会
  • Place of Presentation: 北海道大学(奨励賞受賞講演)
• [Presentation] 水-鉱物相互作用の素過程としてみた吸着反応 (2009)
  • Author(s): 福士圭介
  • Organizer: 第53回粘土科学討論会
  • Place of Presentation: 岩手大学(シンポジウム基調講演)
• [Presentation] Surface Speciation of Sulfate at a Mineral/Water Interface (2009)
  • Author(s): Aoyama K, Nagata T, Fukushi K
  • Organizer: Present Earth Surface Processes and Histrical Environmental Changes in East Asia
  • Place of Presentation: 台北・台湾
• [Presentation] モノハイドロカルサイトによるヒ酸の取り込み (2009)
  • Author(s): 福士圭介・酒井実・宗本隆志・横山由佳・高橋嘉夫
  • Organizer: 日本地球化学会第56回年会
  • Place of Presentation: 広島大学 (広島県)
• [Presentation] 表面錯体モデリングによる酸化物へのIO3-吸着の予測 (2009)
  • Author(s): 永田貴洋・福士圭介・高橋嘉夫
  • Organizer: 日本地球化学会第56回年会
  • Place of Presentation: 広島大学 (広島県)
• [Presentation] 水・フェリハイドライト界面における硫酸の表面スペシエーション (2009)
  • Author(s): 青山和樹・福士圭介・永田貴洋
  • Organizer: 日本地球化学会第56回年会
  • Place of Presentation: 広島大学 (広島県)
• [Presentation] 地球表層での水-鉱物相互作用におよぼす吸着の重要性 (2009)
  • Author(s): 福士圭介(受賞講演)
  • Organizer: 鉱物科学会2009年年会
  • Place of Presentation: 北海道大学 (北海道)
• [Presentation] 水-鉱物相互作用の素過程としてみた吸着反応 (2009)
  • Author(s): 福士圭介(招待講演)
  • Organizer: 第53回粘土科学討論会
  • Place of Presentation: 岩手大学 (岩手県)
• [Presentation] Surface Speciation of Sulfate at a Water-Ferrihydrite Interface (2009)
  • Author(s): Aoyama K.Nagata T.Fukushi K.
  • Organizer: Goldschmidt2009
  • Place of Presentation: Davos, Switzerland
• [Presentation] Prediction of Iodine Adsorption on Oxides by Surface Complexation Modeling with Spectroscopic Confirmation (2009)
  • Author(s): Nagata T.Fukushi K.Takahashi Y
  • Organizer: Goldschmidt2009
  • Place of Presentation: Davos, Switzerland
• [Presentation] Surface speciation of sulfate on ferrihydrite-aqueous solution interface (2008)
  • Author(s): Fukushi K. Aoyama K. and Naaata T.
  • Organizer: 5rd Japan-Korea-China International Work shop
  • Place of Presentation: 函館
  • Year and Date: 2008-10-07
• [Presentation] Alteration kinetics of monohydrocalcite to aragonite in aqueous solutions (2008)
  • Author(s): Munemoto T. and Fukushi K.
  • Organizer: 5rd Japan-Korea-China International Workshop
  • Place of Presentation: 函館
  • Year and Date: 2008-10-07
• [Presentation] Prediction of iodide adsorption on oxides by surface complexation modeling with spectroscopic confirmation (2008)
  • Author(s): Nagata T. Fukushi K. and Takahashi Y.
  • Organizer: 5rd Japan-Korea-China International Workshop
  • Place of Presentation: 函館
  • Year and Date: 2008-10-07
• [Presentation] 水-フェリハイドライト界面における吸着硫酸イオンの表面化学種分布 (2008)
  • Author(s): 福士圭介・青山和樹・永田貴洋
  • Organizer: 日本地球化学会第55回年会
  • Place of Presentation: 東京大学
  • Year and Date: 2008-09-19
• [Presentation] 表面錯体モテリングによる酸化物へのI-吸着の予測 (2008)
  • Author(s): 永田貴洋・福士圭介・高橋嘉夫
  • Organizer: 日本地球化学会第55回年会
  • Place of Presentation: 東京大学
  • Year and Date: 2008-09-19
• [Presentation] モノハイドロカルサイトの安定性 : モノハイドロカルサイトの相変化速度に及ぼすリン酸の影響 (2008)
  • Author(s): 宗本隆志・福士圭介
  • Organizer: 第52回粘土科学討論会
  • Place of Presentation: 琉球大学
  • Year and Date: 2008-09-04
• [Presentation] フェリハイドライトによるヨウ素吸着の表面錯体モデリング (2008)
  • Author(s): 永田貴洋・福士圭介・高橋嘉夫
  • Organizer: 日本地球惑星科学連合2008年大会
  • Place of Presentation: 幕張
  • Year and Date: 2008-05-29
• [Presentation] モノハイドロカルサイトの生成と安定性 (2008)
  • Author(s): 宗本隆志・福士圭介
  • Organizer: 日本地球惑星科学連合2008年大会
  • Place of Presentation: 幕張
  • Year and Date: 2008-05-29
• [Presentation] Formation, stability and interaction with anionic species of monohydrocalcite found in the sediments in lake Hovsgol (2008)
  • Author(s): Fukushi K. Munemoto T. Sakai M. Fukumoto H. and Kashiwaya K.
  • Organizer: The 7^<th> International Symposium on Terre strial Environmental Changes in East Eur asia and Adjacent Areas
  • Place of Presentation: Ulaanbaatar-Hatgal, Mongolia
  • Year and Date: 2008-05-23
• [Book] 粘土ハンドブック第三版 (2009)
  • Author(s): 日本粘土学会編(分担執筆)
  • Publisher: 技報堂出版
• [Patent(Industrial Property Rights)] リン回収剤及びそれを用いた排水の浄化方法 (2010)
  • Inventor(s): 福士圭介・八木新大朗
  • Industrial Property Rights Holder: 国立大学法人金沢大学
  • Industrial Property Number: 2010-174259
  • Filing Date: 2010-08-03
• [Patent(Industrial Property Rights)] ヒ素収着材 (2009)
  • Inventor(s): 福士圭介・酒井実・宗本隆志
  • Industrial Property Rights Holder: 国立大学法人金沢大学
  • Industrial Property Number: 2009-017367
  • Filing Date: 2009-01-28
• [Patent(Industrial Property Rights)] ヒ素収着材及びヒ素汚染物質の浄化方法 (2009)
  • Inventor(s): 福士圭介・酒井実・宗本隆志
  • Industrial Property Rights Holder: 金沢大学
  • Filing Date: 2009-01-25
  • Overseas