Investigation of cooling processes and vibrational-electronic states of carbon cluster anions

• Project/Area Number: 20750015
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Physical chemistry
• Research Institution: Tokyo Metropolitan University
• Principal Investigator: MATSUMOTO Jun Tokyo Metropolitan University, 理工学研究科, 助教 (10443029)
• Project Period (FY): 2008 – 2009
• Project Status: Completed (Fiscal Year 2009)
• Budget Amount: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000); Fiscal Year 2009: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000); Fiscal Year 2008: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
• Keywords: クラスター / 励起分子素過程 / イオン蓄積リング / 炭素クラスター / 負イオン

Research Abstract

The lifetimes for metastable states of the chain carbon and hydrocarbon anions from dimers to hexamers were measured by using an electrostatic storage ring equipped at TMU. All the kinds of the hydrocarbon anion have a few metastable states with a lifetime in the millisecond range from decay plot analysis. Vis/near-IR excitation spectra of the hydrocarbon tetramer anions were measured by detecting neutral species produced by photoabsorption. The yield dependence of the laser wave length and the storage time in the ring were observed.

Research Products

• [Journal Article] Absolute cooling rates of freely decaying fullerenes (2009)
  • Author(s): A.E.K. Sunden, M. Goto, J. Matsumoto, H. Shiromaru, H. Tanuma, T. Azuma, J.U. Andersen, S.E. Canton, K. Hansen
  • Journal Title: Phys. Rev. Lett. 103 Pages: 143001-143001
  • Peer Reviewed
• [Journal Article] Absolut cooling rates of freely decaying fullerenes (2009)
  • Author(s): A.E.K. Sunden, 他
  • Journal Title: Physical Review Letters 103 Pages: 1430011-4
  • Peer Reviewed
• [Journal Article] Absorption spectra of zinc phthalocyanine anions under radiative cooling (2008)
  • Author(s): M. Goto, M. Togawa, S. Jinno, T. Takao, J. Matsumoto, H. Shiromaru, Y. Achiba, H. Tanuma, T. Azuma
  • Journal Title: Chem. Phys. Lett. 460 Pages: 46-46
  • Peer Reviewed
• [Journal Article] Absorption spectra of zinc phthalocyanine anions under radiative cooling (2008)
  • Author(s): M. Goto, J. Matsumoto, 他
  • Journal Title: Chemical Physics Letters 460 Pages: 46-49
  • Peer Reviewed
• [Presentation] TMU E-ringを用いた炭素負イオンクラスターの準安定状態の寿命測定 (2009)
  • Author(s): 松本淳, 他
  • Organizer: 日本物理学会2008年秋季大会
  • Place of Presentation: 岩手大学
  • Year and Date: 2009-09-23
• [Presentation] TMU E-ringを用いた炭化水素負イオンの準安定状態の寿命測定 (2009)
  • Author(s): 松本淳, 後藤基, 間嶋拓也, 田沼肇, 東俊行, 城丸春夫, 阿知波洋次
  • Organizer: 原子衝突研究協会第34回年会
  • Place of Presentation: 八王子
  • Year and Date: 2009-08-28
• [Presentation] TMU E-ringを用いた炭化水素負イオンの準安定状態の寿命測定 (2009)
  • Author(s): 松本淳, 他
  • Organizer: 原子衝突研究協会第34回年会
  • Place of Presentation: 東京都八王子市
  • Year and Date: 2009-08-28
• [Presentation] Detection of the metastable chain hydrocarbon anions by an electrostatic ion storage ring (2009)
  • Author(s): J. Matsumoto, M. Goto, Y. Zama, T. Majima, H. Tanuma, T. Azuma, H. Shiromaru, Y. Achiba
  • Organizer: XXVI International Conference on Photonic, Electronic, and Atomic Collisions
  • Place of Presentation: Kalamazoo, US
  • Year and Date: 2009-07-22
• [Presentation] Detection of the metastable chain hydrocarbon anions by an electrostaticion storage ring (2009)
  • Author(s): J.Matsumoto, 他
  • Organizer: XXVI International Conference on Photonic, Electronic, and Atomic Collisions
  • Place of Presentation: Kalamazoo, US
  • Year and Date: 2009-07-22
• [Presentation] Lifetime of metastable chain-form hydrocarbon anions stored in the TMU E-rin (2009)
  • Author(s): J. Matsumoto, M. Goto, T. Majima, H. Tanuma, T. Azuma, H. Shiromaru
  • Organizer: 3rd International Workshop on Electrostatic Storage Devices
  • Place of Presentation: Aarhus, Denmark
  • Year and Date: 2009-06-24
• [Presentation] Lifetime of metastable chain-form hydrocarbon anions stored in the TMUE-ring (2009)
  • Author(s): J.Matsumoto, 他
  • Organizer: 3rd International Workshop on Electrostatic Storage Devices
  • Place of Presentation: Aarhus, Denmark
  • Year and Date: 2009-06-24
• [Presentation] 静電型イオン蓄積リングを用いた直鎖炭素分子および炭化水素負イオンの準安定状態の寿命測定 (2009)
  • Author(s): 松本淳, 後藤基, 座間優, 川口瑛司, 大月聡子, 間嶋拓也, 田沼肇, 東俊行, 城丸春夫, 阿知波洋次
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 船橋
  • Year and Date: 2009-03-28
• [Presentation] 静電型イオン蓄積リングを用いた直鎖炭素分子および炭化水素負イオンの準安定状態の寿命測定 (2009)
  • Author(s): 松本淳, 他
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 日本大学理工学部
  • Year and Date: 2009-03-28
• [Presentation] TMU E-ringを用いた炭素負イオンクラスターの準安定状態の寿命測定 (2008)
  • Author(s): 松本淳, 高雄智治, 後藤基, 神野智史, 間嶋拓也, 田沼肇, 東俊行, 城丸春夫
  • Organizer: 日本物理学会2008年秋季大会
  • Place of Presentation: 盛岡
  • Year and Date: 2008-09-23
• [Presentation] TMU E-ringで蓄積した炭素クラスター負イオンの準安定状態の寿命 (2008)
  • Author(s): 松本淳, 後藤基, 座間優, 大月聡子, 間嶋拓也, 田沼肇, 東俊行, 城丸春夫
  • Organizer: 原子衝突研究協会第33回研究会
  • Place of Presentation: 札幌
  • Year and Date: 2008-08-07
• [Presentation] TMU E-ringで蓄積した炭素クラスター負イオンの準安定状態の寿命 (2008)
  • Author(s): 松本淳, 他
  • Organizer: 原子衝突研究協会第33回研究会
  • Place of Presentation: 北海道大学
  • Year and Date: 2008-08-07
• [Presentation] TMU E-ringを用いた負イオン蓄積実験の現状 (2008)
  • Author(s): 松本淳, 後藤基, 高雄智治, 外川茉実, 間嶋拓也, 田沼肇, 東俊行, 城丸春夫
  • Organizer: 第5回原子・分子・光科学(AMO)討論会
  • Place of Presentation: 八王子市
  • Year and Date: 2008-06-14