High-resolution solid-state NMR under fluctuating field

• Project/Area Number: 20750019
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Physical chemistry
• Research Institution: Institute for Molecular Science
• Principal Investigator: LIJIMA Takahiro Institute for Molecular Science, 物質分子科学研究領域, 助教 (20402761)
• Project Period (FY): 2008 – 2009
• Project Status: Completed (Fiscal Year 2009)
• Budget Amount: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000); Fiscal Year 2009: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000); Fiscal Year 2008: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
• Keywords: 分子構造 / 高分解能NMR / 固体NMR

Research Abstract

A method of two-dimensional ultrafast NMR in solids measured under unstable magnetic fields has been studied. This method works in one dimensional NMR acquiring signals with high-sensitivity and measuring molecular motion, while in two-dimensional NMR ultrafast measurement can be performed under fluctuating field by incorporating compensation algorithm. The one dimensional NMR has been demonstrated for ^2H NMR of a paramagnetic compounds.

Research Products

• [Journal Article] Solid-state 95Mo NMR of mixed-valence polyoxomolybdates(V, VI) with localized or delocalized d1 electrons (2010)
  • Author(s): T. Iijima, T. Yamase, M. Tansho, T. Shimizu, K. Nishimura
  • Journal Title: Chem. Phys. Lett. 487 Pages: 232-236
  • Peer Reviewed
• [Journal Article] Solid-state ^<95>Mo NMR of mixed-valence polyoxomolybdates(V, VI)with localized or delocalized d^1 electrons (2010)
  • Author(s): T.Iijima, T.Yamase, M.Tansho, T.Shimizu, K.Nishimura
  • Journal Title: Chem.Phys.Lett 487 Pages: 232-236
  • Peer Reviewed
• [Presentation] モリブデンポリ酸のMo(V)の固体95Mo NMR (2010)
  • Author(s): 飯島隆広, 西村勝之, 山瀬利博, 丹所正孝, 清水禎
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学
  • Year and Date: 2010-03-26
• [Presentation] モリブデンポリ酸のMo(V)の固体^<95>Mo NMR (2010)
  • Author(s): 飯島隆広、西村勝之、山瀬利博、丹所正孝、清水禎
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学(大阪府)
  • Year and Date: 2010-03-26
• [Presentation] 混合原子価モリブデン(V, VI)ポリ酸の固体95Mo NMR (2009)
  • Author(s): 飯島隆広, 西村勝之, 山瀬利博, 丹所正孝, 清水禎
  • Organizer: 第48回NMR討論会
  • Place of Presentation: 九州大学
  • Year and Date: 2009-11-10
• [Presentation] 混合原子価モリブデン(V, VI)ポリ酸の固体^<95>Mo NMR (2009)
  • Author(s): 飯島隆広、西村勝之、山瀬利博、丹所正孝、清水禎
  • Organizer: 第48回NMR討論会
  • Place of Presentation: 九州大学(福岡県)
  • Year and Date: 2009-11-10
• [Presentation] モリブデン(V, VI)ポリ酸の固体^<95>Mo NMRの研究 (2009)
  • Author(s): 飯島隆広、西村勝之、山瀬利博、丹所正孝、清水禎
  • Organizer: 第45回固体NMR・材料フォーラム
  • Place of Presentation: 龍谷大学(滋賀県)
  • Year and Date: 2009-05-11
• [Presentation] Spin-1核のシフト補正QCPMG NMR (2009)
  • Author(s): 飯島隆広, 西村勝之
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 日本大学
  • Year and Date: 2009-03-27
• [Presentation] シフト項がある場合のspin-1核のQCPMG NMR (2008)
  • Author(s): 飯島隆広, 西村勝之
  • Organizer: 第47回NMR討論会
  • Place of Presentation: 筑波大学
  • Year and Date: 2008-11-12
• [Presentation] モリブデン(V, VI)ポリ酸の固体95Mo NMRの研究 (2008)
  • Author(s): 飯島隆広, 西村勝之, 山瀬利博, 丹所正孝, 清水禎
  • Organizer: 第45回固体NMR・材料フォーラム
  • Place of Presentation: 龍谷大学
  • Year and Date: 2008-05-11