Spin-spin interactions of metal-complexes within organic-pillared coordination boxes
| Project/Area Number |
20750042
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Inorganic chemistry
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
YOSHIZAWA Michito Tokyo Institute of Technology, 資源化学研究所, 准教授 (70372399)
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| Project Period (FY) |
2008 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2009: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2008: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Keywords | 自己組織化 / 集積 / スピン / 金属錯体 / 平面状金属錯体 / 集積化 / 配位結合 / スピン-スピン相互作用 / スピンースピン相互作用 |
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| Research Abstract |
Discrete homo Cu-Cu-Cu and hetero Cu-Pd-Cu or Cu-Co-Cu metal arrays are prepared within an organic-pillared coordination box by inserting M(II)-azaporphine/porphine cartridges (M=Cu(II), Pd(II) or Co(II)), where the metal arrays show unique spin interactions in ESR : in particular, Δms=3 for the Cu-Cu-Cu array.
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Report
(3 results)
Research Products
(30 results)
