| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2009: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2008: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
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| Research Abstract |
Construction of the highly active reaction field by converting the Pt(II) complex with benzenediamide (bda) derivatives, which shows characteristic reversible two-step redox behavior, as a ligand into the d^6 complex by two-electron oxidation was aimed. The oxidation potential of the bda ligand was shifted negatively by using the cyclomatallated ligand as an auxiliary ligand. The structural change of the complex from square-planar (Pt(II)) to octahedral (Pt(IV)) was considered to be promoted by further oxidation of the complex. The change was observed by the electrochemical measurement, and the result strongly suggested the construction of the highly active reaction field.
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