| Budget Amount *help |
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2009: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2008: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
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| Research Abstract |
We have developed the following reactions for a direct introduction of oxygen functionality on carbon skeletons. (1)Mn-catalyzed unified oxidation of ethers, benzylic compounds, and alcohols. (2)Direct ether oxidation using mCPBA/CCl3CN reagent system. (3)Intramolecular C-H hydroxylation using dioxirane as an oxidizing agent. For an introduction of carbon functionality on carbocycles, we have developed acylation via two-step sequence including a photocyclization.
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