Development of molecular transformation via C-H and Si-H bond activation
| Project/Area Number |
20750073
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
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| Research Institution | Nagoya University |
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Principal Investigator |
JUN-ICHI Ito Nagoya University, 大学院・工学研究科, 助教 (20402480)
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| Project Period (FY) |
2008 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2009: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2008: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
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| Keywords | 不斉分子触媒 / C-H活性化 / アルキニル化 / ルテニウム / イリジウム / 多座配位子 / 不斉触媒 / 水素化 / シクロプロパン化 / ヒドロシリル化 / ロジウム / 有機金属 / C-H結合活性化 / 酸化的付加 |
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| Research Abstract |
In this research, synthesis of novel transition metal complexes with chiral ligands and their utilization for asymmetric catalytic reaction were preformed. As a result, this study developed new chiral ruthenium complexes having nitrogen based tridentate ligands, which can be successfully utilized in several asymmetric catalytic reactions, such as reduction and C-C bond formation reactions. Furthermore, unique C-H bond activation of alkane, which is a quite stable molecule, was achieved by using iridium complexes that were synthesized in this research.
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Report
(3 results)
Research Products
(42 results)
