| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2009: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2008: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Research Abstract |
An efficient platinum-catalyzed reaction involving hydrogen-boron exchange on the carbon-carbon double bond has been established, which results in regioand stereoselective construction of organoboron compounds. A rhodium-catalyzed addition reaction of hydrosilane, which is formed in the hydrogen-boron exchange, to the carbon-carbon double bond has also been developed. Finally, sequential molecular transformation involving stereoselective construction of both carbon-carbon double bond and stereogenic carbon centers has been achieved by applying those two reactions.
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