Synthesis of Strained Macrocyclic Compounds and Their Application to Functionalized Materials
Project/Area Number |
20750079
|
Research Category |
Grant-in-Aid for Young Scientists (B)
|
Allocation Type | Single-year Grants |
Research Field |
Synthetic chemistry
|
Research Institution | Kyoto University |
Principal Investigator |
MIKI Koji Kyoto University, 大学院・工学研究科, 講師 (60422979)
|
Project Period (FY) |
2008 – 2009
|
Project Status |
Completed (Fiscal Year 2009)
|
Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2009: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2008: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
|
Keywords | 選択的合成・反応 / 大環状分子合成 / パイ共役系 / 非平面性大環状分子 / フェニレンアセチレン / 還元的芳香族化 / ナノリング |
Research Abstract |
In this study, tin-mediated reductive aromatization afforded strained π-conjugated cyclynes such as pyridine-containing strained cyclynes and p-phenyleneacetylene derivatives. The former compound emits fluorescence around 500-600 nm with a good quantum yield. The latter compounds can form 1:1 complexes with fullerene derivatives.
|
Report
(3 results)
Research Products
(12 results)