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Click Synthesis of Donor-Acceptor Type Conjugated Polymers

Research Project

Project/Area Number 20750084
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Polymer chemistry
Research InstitutionTokyo Institute of Technology

Principal Investigator

MICHINOBU Tsuyoshi  Tokyo Institute of Technology, グローバルエッジ研究院, テニュア・トラック助教 (80421410)

Project Period (FY) 2008 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2009: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2008: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywordsクリックケミストリー / 共役高分子 / 高分子反応 / 電気化学 / 電荷移動吸収
Research Abstract

A highly efficient synthetic method of donor-acceptor type conjugated polymers was developed by using the quantitative addition reaction between electron-rich alkynes and a strong acceptor molecule, tetracyanoethylene. This method is suitable for mass production of the desired polymers with low cost because of the absence of any special purification procedures. The obtained donor-acceptor type polymers featured strong charge-transfer bands in the visible absorption region, which offers the application possibility as optoelectronic materials.

Report

(3 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • Research Products

    (33 results)

All 2010 2009 2008

All Journal Article (16 results) (of which Peer Reviewed: 15 results) Presentation (13 results) Patent(Industrial Property Rights) (4 results)

  • [Journal Article] Click Synthesis of Donor-Acceptor Type Aromatic Polymers2010

    • Author(s)
      Tsuyoshi Michinobu
    • Journal Title

      Pure Appl. Chem. (印刷中)

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Blue, Green, and Red Light Emission of 1, 8-Carbazole-Based Conjugated Polymers2010

    • Author(s)
      Tsuyoshi Michinobu, Haruka Osako, Kimie Murata, Kiyotaka Shigehara
    • Journal Title

      Chem. Lett. 39

      Pages: 168-169

    • NAID

      10027177608

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Tsuyoshi Michinobu, Sequential double click reactions: a highly efficient post-functionalization method for optoelectronic polymers2010

    • Author(s)
      Yongrong Li
    • Journal Title

      Polym. Chem. 1

      Pages: 72-74

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Blue, Green, and Red Light Emission of 1,8-Carbazole-Based Conjugated Polymers2010

    • Author(s)
      Tsuyoshi Michinobu, Haruka Osako, Kimie Murata, Kiyotaka Shigehara
    • Journal Title

      Chem.Lett. 39

      Pages: 168-169

    • NAID

      10027177608

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Sequential double click reactions : a highly efficient post-functionalization method for optoelectronic polymers2010

    • Author(s)
      Yongrong Li, Tsuyoshi Michinobu
    • Journal Title

      Polym.Chem. 1

      Pages: 72-74

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Click Synthesis of Donor-Acceptor Type Aromatic Polymers2010

    • Author(s)
      Tsuyoshi Michinobu
    • Journal Title

      Pure Appl.Chem. (印刷中)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Properties of Nitrogen-Linked Poly(2, 7-carbazole)s as Hole-Transport Material for Organic Light Emitting Diodes2009

    • Author(s)
      Tsuyoshi Michinobu, Hiroe Kumazawa, Eiji Otsuki, Hiroaki Usui, Kiyotaka Shigehara
    • Journal Title

      J. Polym. Sci. Part A: Polym. Chem. 47

      Pages: 3880-3891

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Two-Dimensionally Extended Aromatic Polyamines for Optimization of Charge Transporting Properties by Partial Oxidation2009

    • Author(s)
      Tsuyoshi Michinobu, Fumiaki Kato, Jun Inui, Hiroyuki Nishide
    • Journal Title

      J. Polym. Sci. Part A: Polym. Chem. 47

      Pages: 4577-4586

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] One-Step Synthesis of Donor-Acceptor Type Conjugated Polymers from Ferrocene-Containing Poly(aryleneethynylene)s2009

    • Author(s)
      Tsuyoshi Michinobu, Hiroe Kumazawa, Keiichi Noguchi, Kiyotaka Shigehara
    • Journal Title

      Macromolecules 42

      Pages: 5903-5905

    • Related Report
      2009 Annual Research Report 2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Properties of Conjugated Poly(1, 8-carbazole)s2009

    • Author(s)
      Tsuyoshi Michinobu, Haruka Osako, Kiyotaka Shigehara
    • Journal Title

      Macromolecules 42

      Pages: 8172-8180

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Click-Type Reaction of Aromatic Polyamines2009

    • Author(s)
      道信剛志
    • Journal Title

      高分子 58

      Pages: 453-453

    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Journal Article] Synthesis and Properties of Nitrogen-Linked Poly(2,7-carbazole)s as Hole-Transport Material for Organic Light Emitting Diodes2009

    • Author(s)
      Tsuyoshi Michinobu, Hiroe Kumazawa, Eiji Otsuki, Hiroaki Usui, Kiyotaka Shigehara
    • Journal Title

      J.Polym.Sci.Part A : Polym.Chem. 47

      Pages: 3880-3891

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Two-Dimensionaly Extended Aromatic Polyamines for Optimization of Charge Transporting Properties by Partial Oxidation2009

    • Author(s)
      Tsuyoshi Michinobu, Fumiaki Kato, Jun Inui, Hiroyuki Nishide
    • Journal Title

      J.Polym.Sci.Part A : Polym.Chem. 47

      Pages: 4577-4586

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Properties of Conjugated Poly(1,8-carbazole)s2009

    • Author(s)
      Tsuyoshi Michinobu, Haruka Osako, Kiyotaka Shigehara
    • Journal Title

      Macromolecules 42

      Pages: 8172-8180

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Click-Type Reaction of Aromatic Polyamines for Improvement of Thermal and Optoelectronic Properties2008

    • Author(s)
      suyoshi Michinobu
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 14074-14075

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Click-Type Reaction of Aromatic Polyamines for Improvement of Thermal and Optoelectronic Properties2008

    • Author(s)
      T. Michinobu
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 14074-14075

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] クリック型反応によるドナーアクセプター型共役高分子の合成2010

    • Author(s)
      道信剛志
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] Click Synthesis of Donor-Acceptor Alternating Polymers from Poly(aryleneethynylene)s2010

    • Author(s)
      Tsuyoshi Michinobu
    • Organizer
      NRF-JSPS Core University Program Advanced Polymeric Materials and Technology Symposium
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2010-01-26
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] Click Synthesis of Donor-Acceptor Type Conjugated Polymers2009

    • Author(s)
      Tsuyoshi Michinobu
    • Organizer
      Symposium on Creation of Functional Materials 2009
    • Place of Presentation
      Tsukuba
    • Year and Date
      2009-12-04
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] ドナーアクセプター型共役高分子の一段階合成2009

    • Author(s)
      道信剛志、熊澤宏枝、重原淳孝
    • Organizer
      第58回高分子討論会
    • Place of Presentation
      熊本
    • Year and Date
      2009-09-18
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] カルバゾール骨格を主鎖に含む共役高分子の合成と物性2009

    • Author(s)
      道信剛志、尾嶝春香、重原淳孝
    • Organizer
      第58回高分子討論会
    • Place of Presentation
      熊本
    • Year and Date
      2009-09-17
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] Click Synthesis of Donor-Acceptor Type Aromatic Polymers2009

    • Author(s)
      Tsuyoshi Michinobu
    • Organizer
      13th International Symposium on Novel Aromatic Compounds
    • Place of Presentation
      Luxembourg
    • Year and Date
      2009-07-21
    • Related Report
      2009 Final Research Report
  • [Presentation] Click Synthesis of Donor-Acceptor Type Aromatic Polymers2009

    • Author(s)
      道信剛志
    • Organizer
      13^<th> International Symposium on Novel Aromatic Compounds
    • Place of Presentation
      Luxembourg
    • Year and Date
      2009-07-21
    • Related Report
      2009 Annual Research Report
  • [Presentation] フェロセン含有共役高分子の機能化2009

    • Author(s)
      道信剛志、熊澤宏枝、重原淳孝
    • Organizer
      平成21年度繊維学会年次大会
    • Place of Presentation
      東京
    • Year and Date
      2009-06-11
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] 共役カルバゾール高分子の合成と物性2009

    • Author(s)
      道信剛志、尾嶝春香、重原淳孝
    • Organizer
      平成21年度繊維学会年次大会
    • Place of Presentation
      東京
    • Year and Date
      2009-06-10
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] ドナーアクセプター型共役高分子の合成と電気化学特性2009

    • Author(s)
      道信剛志、熊澤宏枝、重原淳孝
    • Organizer
      第58回高分子学会年次大会
    • Place of Presentation
      神戸
    • Year and Date
      2009-05-27
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] Electronic State Tuning of Conjugated Polymers by Click-Type Reaction2008

    • Author(s)
      Tsuyoshi Michinobu
    • Organizer
      Japan-Korea Polymer Young Scientist Symposium
    • Place of Presentation
      Niigata
    • Year and Date
      2008-10-24
    • Related Report
      2009 Final Research Report
  • [Presentation] Electronic State Tuning of Conjugated Polymers by Click-Type Reaction2008

    • Author(s)
      T. Michinobu
    • Organizer
      Japan-Korea Polymer Young Scientist Symposium
    • Place of Presentation
      新潟
    • Year and Date
      2008-10-24
    • Related Report
      2008 Annual Research Report
  • [Presentation] クリック型反応による共役高分子の機能化2008

    • Author(s)
      道信剛志
    • Organizer
      第57回高分子討論会
    • Place of Presentation
      大阪
    • Year and Date
      2008-09-24
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Patent(Industrial Property Rights)] 光電子機能部位を有する高分子化合物およびその製造方法2009

    • Inventor(s)
      道信剛志、李 永〓
    • Industrial Property Rights Holder
      東京工業大学
    • Filing Date
      2009-10-30
    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] 光電子機能部位を有する高分子化合物およびその製造方法2009

    • Inventor(s)
      道信剛志、李永栄
    • Industrial Property Rights Holder
      東京工業大学
    • Industrial Property Number
      2009-250942
    • Filing Date
      2009-10-30
    • Related Report
      2009 Annual Research Report
  • [Patent(Industrial Property Rights)] 電子状態の制御された共役高分子化合物及びそれを用いた有機半導体材料2008

    • Inventor(s)
      道信剛志
    • Industrial Property Rights Holder
      東京農工大学
    • Filing Date
      2008-05-07
    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] 電子状態の制御された共役高分子化合物及びそれを用いた有機半導体材料2008

    • Inventor(s)
      道信剛志
    • Industrial Property Rights Holder
      東京農工大学
    • Industrial Property Number
      2008-121632
    • Acquisition Date
      2008-05-07
    • Related Report
      2008 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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