Functional Supramolecular/Macromolecular Hybrid Materials

• Project/Area Number: 20750097
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Polymer chemistry
• Research Institution: National Institute for Materials Science
• Principal Investigator: SUGIYASU Kazunori National Institute for Materials Science, ナノ有機センター, 主任研究員 (80469759)
• Project Period (FY): 2008 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000); Fiscal Year 2010: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000); Fiscal Year 2009: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2008: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
• Keywords: 機能性高分子 / 超分子集合体 / 導電性高分子 / 有機エレクトロニクス / ポリチオフェン / エネルギー移動 / エラストマー / ブロックコポリマー / 自己組織化 / ミクロ相分離

Research Abstract

We have designed and fabricated "supramolecular/macromolecular hybrid materials". We have succeeded in creating, for examples, (1) optoeletronic functional films and (2) mechano-responsive light-harvesting systems by means of the hybridization between supramolecular functions and polymeric networks.

Research Products

• [Journal Article] Synthesis of a Doubly Strapped Light-Harvesting Porphyrin Bearing Energy Donor Molecules Hanging on to the Straps : An Attempt toward Macroscopic Control over Molecular Conformation that Affects the Efficiency of Fluorescence Resonance Energy Transfer (2011)
  • Author(s): S.Ogi, K.Sugiyasu^*, M.Takeuchi^*
  • Journal Title: Bull.Chem.Soc.Jpn. 84 Pages: 40-40
  • NAID: 10027654198
  • Peer Reviewed
• [Journal Article] Synthesis of a Doubly Strapped Light-Harvesting Porphyrin Bearing Energy Donor Molecules Hanging on to the Straps : An Attempt toward Macroscopic Control over Molecular Conformation that Affects the Efficiency of Fluorescence Resonance Energy Transfer (2011)
  • Author(s): Soichiro Ogi, Kazunori Sugiyasu, Masayuki Takeuchi
  • Journal Title: Bulletin of the Chemical Society of Japan Volume: 84 Pages: 40-48
  • NAID: 10027654198
  • Peer Reviewed
• [Journal Article] A Self-Threading Polythiophene : Defect-Free Insulated Molecular Wires Endowed with Long Effective Conjugation Length (2010)
  • Author(s): K.Sugiyasu^*, Y.Honsho, R.M.Harrison, A.Sato, T.Yasuda, S.Seki, M.Takeuchi^*
  • Journal Title: J.Am.Chem.Soc. 132 Pages: 14754-14754
  • Peer Reviewed
• [Journal Article] Self-threading polythiophene : Defect-free insulated molecular wires endowed with long effective conjugation length (2010)
  • Author(s): Kazunori Sugiyasu, Yoshihito, Honsho, Ryan M.Harrison, Akira Sato, Takeshi Yasuda, Shu Seki, Masayuki Takeuchi
  • Journal Title: Journal of the American Chemical Society Volume: 132 Pages: 14754-14756
  • Peer Reviewed
• [Journal Article] Conducting Polymer Networks Cross-Linked by "Isolated" Functional Dyes : Design, Synthesis, and Electrochemical Polymerization of Doubly Strapped Light-Harvesting Porphyrin/Oligothiophene Monomers (2009)
  • Author(s): K.Sugiyasu^*, M.Takeuchi^*
  • Journal Title: Chem.Eur.J. 15 Pages: 6350-6350
  • Peer Reviewed
• [Journal Article] Conducting Polymer Networks Cross-Linked by "Isolated" Functional Dyes : Design, Synthesis, and Electrochemical Polymerization of Doubly Strapped Light-Harvesting Porphyrin/Oligothiophene Monomers (2009)
  • Author(s): K.Sugiyasu, M.Takeuchi
  • Journal Title: Chemistry-A European Journal 15 Pages: 6350-6362
  • Peer Reviewed
• [Journal Article] むしろ固体状態で光る分子のデザイン:そのメカニズムは? (2009)
  • Author(s): 杉安和憲
  • Journal Title: 有機合成化学協会誌 67 Pages: 1053-1054
  • NAID: 10025644919
  • Peer Reviewed
• [Journal Article] Conducting Polymer Networks Cross-Linked by "Isolated" Functional Dyes: Design, Synthesis and Electrochemical Polymerization of Doubly-Strapped Light-Harvesting Porphyrin/Oligothiophene Monomers (2009)
  • Author(s): Sugiyasu Kazunori
  • Journal Title: Chemistry-A European Journal (掲載決定)
  • Peer Reviewed
• [Presentation] Self-Threading Polythiophene : Defect-Free Insulated Molecular Wires Endowed with Long Effective Conjugation Length (2010)
  • Author(s): K.Sugiyasu^*, M.Takeuchi^*
  • Organizer: Pacifichem, Hawaii
  • Place of Presentation: 高島
  • Year and Date: 2010-12-19
• [Presentation] Self-threading polythiophene : Defect-free insulated molecular wires endowed with long effective conjugation length (2010)
  • Author(s): Kazunori Sugiyasu
  • Organizer: 2010環太平洋国際化学会議
  • Place of Presentation: ハワイコンベンションセンター
  • Year and Date: 2010-12-19
• [Presentation] 導電性高分子まわりの空間設計 (2010)
  • Author(s): 杉安和憲
  • Organizer: グローバルCOE「第7回有機元素化学セミナー」
  • Place of Presentation: 京都大学
  • Year and Date: 2010-11-02
• [Presentation] π共役系分子まわりの空間設計 (2010)
  • Author(s): 杉安和憲
  • Organizer: 有機合成化学協会若手研究者のためのセミナー(2010)
  • Place of Presentation: 千葉大学
  • Year and Date: 2010-09-25
• [Presentation] 自己貫通ポリチオフェン(口頭) (2010)
  • Author(s): 杉安和憲^*, 大内祐輝, 本庄義人, 関修平, 竹内正之^*
  • Organizer: 第59回高分子討論会
  • Place of Presentation: 北海道大学
  • Year and Date: 2010-09-15
• [Presentation] 自己貫通ポリチオフェン (2010)
  • Author(s): 杉安和憲, 大内祐輝, 本庄義人, 関修平, 竹内正之
  • Organizer: 第59回高分子討論会
  • Place of Presentation: 北海道大学
  • Year and Date: 2010-09-15
• [Presentation] 自己貫通ポリチオフェン (2010)
  • Author(s): 杉安和憲、竹内正之
  • Organizer: 高次π空間の創発と機能開発 第四回公開シンポジウム
  • Place of Presentation: つくば国際会議場
  • Year and Date: 2010-07-17
• [Presentation] π共役系分子まわりの空間設計 (2010)
  • Author(s): 杉安和憲
  • Organizer: 高次π空間の創発と機能開発 第二回若手研究会
  • Place of Presentation: 物質・材料研究機構
  • Year and Date: 2010-07-16
• [Presentation] Space Design around Conducting Polymers (口頭) (2010)
  • Author(s): K.Sugiyasu^*, Y.Ouchi, M.Takeuchi^*
  • Organizer: International Conference on Science and Technology of Synthetic Metals
  • Place of Presentation: Kyoto
  • Year and Date: 2010-07-05
• [Presentation] Space Design around Conducting Polymers (2010)
  • Author(s): Kazunori Sugiyasu、Yuki Ouchi、Masayuki Takeuchi
  • Organizer: International Conference on Science and Technology of Synthetic Metals (ICSM2010)
  • Place of Presentation: 京都国際会議場
  • Year and Date: 2010-07-05
• [Presentation] 自己貫通ポリチオフェン (2010)
  • Author(s): 杉安和憲, 大内祐輝, 竹内正之
  • Organizer: 第59高分子学会年次大会
  • Place of Presentation: パシフィコ横浜
  • Year and Date: 2010-05-27
• [Presentation] 自己貫通ポリチオフェン(口頭) (2010)
  • Author(s): 杉安和憲^*, 竹内正之^*
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学
  • Year and Date: 2010-03-26
• [Presentation] 自己貫通ビチオフェン(1):合成と構造 (2010)
  • Author(s): 杉安和憲、Ryan M.Harrison、佐藤晃、竹内正之
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学
  • Year and Date: 2010-03-26
• [Presentation] 自己貫通ビチオフェン(2):光学特性の制御 (2010)
  • Author(s): 大内祐輝、杉安和憲、大城宗一郎、竹内正之
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学
  • Year and Date: 2010-03-26
• [Presentation] 自己貫通ビチオフェン(3):重合 (2010)
  • Author(s): 杉安和憲、竹内正之
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学
  • Year and Date: 2010-03-26
• [Presentation] 自己貫通ポリチオフェンの合成と物性評価 (2010)
  • Author(s): 杉安和憲
  • Organizer: 新学術領域「配位プログラミング」第一回公開シンポジウム
  • Place of Presentation: つくば国際会議場
  • Year and Date: 2010-01-18
• [Presentation] Isolated Functional Molecules in Conjugated Polymers(口頭) (2009)
  • Author(s): K.Sugiyasu^*, M.Takeuchi^*
  • Organizer: 1st Federation of Asian Polymer Societies Polymer Congress
  • Place of Presentation: Nagoya
  • Year and Date: 2009-10-22
• [Presentation] Isolated Functional Molecules in Conjugated Polymers (2009)
  • Author(s): 杉安和憲、竹内正之
  • Organizer: 1^<st> Federation of Asian Polymer Societies of Polymer Congress
  • Place of Presentation: 名古屋国際会議場
  • Year and Date: 2009-10-22
• [Presentation] 空間的に孤立化されたπ共役系分子の合成 (2009)
  • Author(s): 杉安和憲、竹内正之
  • Organizer: 第58回高分子討論会
  • Place of Presentation: 熊本大学
  • Year and Date: 2009-09-16
• [Presentation] Polythiophene Networks Cross-Linked by "Isolated" Functional Dyes : Design, Synthesis, and Electrochemical Polymerization of Double-Strapped Light-Harvesing Porphyrin/Bithiphene Monomers (2009)
  • Author(s): 杉安和憲、竹内正之
  • Organizer: 13^<th> International IUPAC Conference on Polymers and Organic Chemistry
  • Place of Presentation: Montreal、Canada
  • Year and Date: 2009-07-06
• [Presentation] Polythiophene Networks Cross-Linked by "Isolated" Functional Dyes: Design, Synthesis, and Electrochemical Polymerization of Doubly Strapped Light-Harvesting Porphyrin/Oligothiophene Monomers (2009)
  • Author(s): K.Sugiyasu^*, M.Takeuchi^*
  • Organizer: 13^<th> International IUPAC Conference on Polymers and Organic Chemistry, Montreal
  • Place of Presentation: ポスター
  • Year and Date: 2009-07-05
• [Presentation] 孤立化機能性色素で連結されたポリチオフェンネットワーク (2009)
  • Author(s): 杉安和憲
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 日本大学理工学部船橋キャンパス、千葉県船橋市
  • Year and Date: 2009-03-28
• [Presentation] Design of Functional Conducting Polymeric Materials via Electrochemical Polymerization (2009)
  • Author(s): Sugiyasu Kazunori
  • Organizer: Japanese-German Young Researchers Workshop
  • Place of Presentation: 東京ビッグサイト、東京都江東区
  • Year and Date: 2009-02-19
• [Presentation] 機能性チオフェンの電解重合:MIT編とNIMS編 (2008)
  • Author(s): 杉安和憲
  • Organizer: 高分子関東支部・茨城地区若手の会交流会
  • Place of Presentation: レイクサイドつくば、つくば市下岩崎
  • Year and Date: 2008-10-24
• [Presentation] Double Strap Porphyrin Having Electrochemically Polymerizable Bitbiophene Groups (2008)
  • Author(s): Sugiyasu Kazunori
  • Organizer: Joint International Symposium on Macrocyclic & Supramolecular Chemistry
  • Place of Presentation: Riviera, Las Begas,NV, アメリカ合衆国
  • Year and Date: 2008-07-06
• [Remarks] ホームページ等
• [Remarks] 有機材料グループ
  • URL: http://www.nims.go.jp/macromol/
• [Remarks] Bull.Chem.Soc.Jpn., 2011, 84, 40.へのオープンアクセス
  • URL: http://www.jstage.jst.go.jp/article/bcsj/84/1/40/_pdf/-char/ja/
• [Remarks]
  • URL: http://www.nims.go.jp/macromol/SugiyasuCV.pdf
• [Patent(Industrial Property Rights)] 導電性モノマーとそのポリマー又はオリゴマーおよび (2009)
  • Inventor(s): 杉安和憲、竹内正之、大内祐輝、ライアンエムハリソン
  • Industrial Property Rights Holder: 独立行政法人物質・材料研究機構
  • Industrial Property Number: 2009-178991
  • Filing Date: 2009-07-31
• [Patent(Industrial Property Rights)] 導電性モノマーとそのポリマー又はオリゴマー及び有機蛍光体 (2009)
  • Inventor(s): 杉安和憲, 竹内正之, 大内祐輝, ライアンエ ムハリソン
  • Industrial Property Rights Holder: 独立行政法人物質・材料研究機構
  • Industrial Property Number: 2009-178991
  • Filing Date: 2009-07-31