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Study on the two-photon induced electron transfer of semiconductor nanocrystals

Research Project

Project/Area Number 20750110
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Functional materials chemistry
Research InstitutionNara Institute of Science and Technology

Principal Investigator

NAKASHIMA Takuya  Nara Institute of Science and Technology, 物質創成科学研究科, 助教 (70379543)

Project Period (FY) 2008 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2009: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2008: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywords光物性 / ナノ材料 / 合成化学 / 複合材料・物性 / 半導体ナノ結晶 / 発光 / 二光子吸収 / 微細加工
Research Abstract

Semiconductor nanocrystals were demonstrated as a potential excellent two-photon absorption sensitizer for various photochemical reactions. To achieve such efficient two-photon induced photochemical system, the detailed excited state properties of CdTe nanocrystals were investigated in this study. The size-dependent energy splitting in the excited state of CdTe nanocrystals were evaluated by the low-temperature and time-dependent spectroscopy in an ionic liquid matrix. The relationship between the split energy states and electron transfer rate was also investigated.

Report

(3 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • Research Products

    (26 results)

All 2010 2009 2008 Other

All Journal Article (12 results) (of which Peer Reviewed: 12 results) Presentation (11 results) Book (1 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Holographic assembly of semiconductor CdSe quantum dots in polymer for volume Bragg grating structures with diffraction efficiency near 100%2009

    • Author(s)
      X. Liu, Y. Tomita, J. Oshima, K. Chikama, K. Matsubara, T. Nakashima, T. Kawai
    • Journal Title

      Appl. Phys. Lett. 95

      Pages: 261109-261109

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Tuning Band Offsets of Core/shell CdS/CdTe Nanocrystals2009

    • Author(s)
      Y. Nonoguchi, T. Nakashima, T. Kawai
    • Journal Title

      Small 5

      Pages: 2403-2406

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Optical Activity and Chiral Memory of Thiol-capped CdTe Nanocrystals2009

    • Author(s)
      T. Nakashima, Y. Kobayashi, T. Kawai
    • Journal Title

      J. Am. Chem. Soc. 131

      Pages: 10342-10343

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Low-temperature Observation of Photoinduced Electron Transfer from CdTe Nanocrystals2009

    • Author(s)
      Y. Nonoguchi, T. Nakashima, T. Kawai
    • Journal Title

      J. Phys. Chem. C 113

      Pages: 11464-11468

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Optical Activity and Chiral Memory of Thiol-capped CdTe Nanocrystals2009

    • Author(s)
      T.Nakashima, Y.Kobayashi, T.Kawai
    • Journal Title

      J.Am.Chem.Soc. 131

      Pages: 10342-10343

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Low-temperature Observation of Photoinduced Electron Transfer from CdTe Nanocrystals2009

    • Author(s)
      Y.Nonoguchi, T.Nakashima, T.Kawai
    • Journal Title

      J.Phys.Chem.C 113

      Pages: 11464-11468

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Tuning Band Offsets of Core/shell CdS/CdTe Nanocrystals2009

    • Author(s)
      Y.Nonoguchi, T.Nakashima, T.Kawai
    • Journal Title

      Small 5

      Pages: 2403-2406

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Low-temperature Observation of Exciton Fine Structure of CdTe Nanocrystals2008

    • Author(s)
      Y. Nonoguchi, T. Nakashima, T. Kawai
    • Journal Title

      J. Phys. Chem. C 112

      Pages: 19263-19267

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ionic Liquid-based Luminescent Composite Materials2008

    • Author(s)
      T. Nakashima, Y. Nonoguchi, T. Kawai
    • Journal Title

      Polym. Adv. Technol. 19

      Pages: 1401-1405

    • NAID

      40015626016

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Low-temperature Observation of Exciton Fine Structure of CdTe Nanocrystals2008

    • Author(s)
      Y. Nonoguchi
    • Journal Title

      Journal of Physical Chemistry C 112

      Pages: 19263-19267

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ionic Liquid-based Luminescent Composite Materials2008

    • Author(s)
      T. Nakashima
    • Journal Title

      Polymers for Advanced Technologies 19

      Pages: 1401-1405

    • NAID

      40015626016

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photopolymerization Sensitized by CdTe Nanocrystals in Ionic Liquid : Highly Efficient Photoinduced Electron Transfer2008

    • Author(s)
      Y. Nonoguchi
    • Journal Title

      Japanese Journal of Applied Physics 47

      Pages: 1385-1388

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] 2成分系カドミウムカルコゲナイド半導体ナノロッドからのナノワイヤー構造の形成2010

    • Author(s)
      野々口斐之・中嶋琢也・河合壮
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学
    • Year and Date
      2010-03-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] キラル表面を有する半導体ナノ結晶の光励起電子移動とキラル認識能2010

    • Author(s)
      大田快・中嶋琢也・野々口斐之・河合壮
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学
    • Year and Date
      2010-03-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] Chiral Transcription and Memory on the CdTe Nanocrystal Surface2009

    • Author(s)
      中嶋琢也, 小林由季, 大田快, 河合壯
    • Organizer
      第19回日本MRS学術シンポジウム
    • Place of Presentation
      横浜
    • Year and Date
      2009-12-08
    • Related Report
      2009 Final Research Report
  • [Presentation] CdTbナノ結晶表面におけるキラル転写とキラルメモリー2009

    • Author(s)
      中嶋琢也・小林由季・大田快・河合壮
    • Organizer
      第19回日本MRS学術シンポジウム
    • Place of Presentation
      波止場会館
    • Year and Date
      2009-12-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] 擬CT発光性を有するCdS-CdTeヘテロ接合ナノ結晶の合成と形状制御2009

    • Author(s)
      野々口斐之, 中嶋琢也, 河合壯
    • Organizer
      2009年光化学討論会
    • Place of Presentation
      桐生
    • Year and Date
      2009-09-17
    • Related Report
      2009 Final Research Report
  • [Presentation] 擬CT発光性を有するCdS-CdTbヘテロ接合ナノ結晶の合成と形状制御2009

    • Author(s)
      野々口斐之・中嶋琢也・河合壮
    • Organizer
      2009年光化学討論会
    • Place of Presentation
      桐生市市民文化会館
    • Year and Date
      2009-09-17
    • Related Report
      2009 Annual Research Report
  • [Presentation] キラル表面を有するCdTeナノ結晶の光学特性とキラルメモリー特性2008

    • Author(s)
      小林由季, 中嶋琢也, 河合壯
    • Organizer
      2008年光化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2008-09-12
    • Related Report
      2009 Final Research Report
  • [Presentation] イオン液体中におけるCdTeナノ結晶の発光特性と光誘起電子移動特性2008

    • Author(s)
      野々口斐之, 中嶋琢也, 河合壯
    • Organizer
      2008年光化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2008-09-12
    • Related Report
      2009 Final Research Report
  • [Presentation] キラルなチオールにより保護されたCdTeナノ結晶の合成と特性2008

    • Author(s)
      中嶋琢也・小林由季・河合壮
    • Organizer
      第6回ナノ学会
    • Place of Presentation
      福岡、九州大学
    • Year and Date
      2008-05-07
    • Related Report
      2008 Annual Research Report
  • [Presentation] Size- and Temperature-Dependent Photoluminescence Properties of CdTe Nanocrystals2008

    • Author(s)
      Y. Nonoguchi, T. Nakashima, T. Kawai
    • Organizer
      2008 Korea-Japan Symposium on Frontier Photoscience
    • Place of Presentation
      Jeju韓国
    • Related Report
      2009 Final Research Report
  • [Presentation] キラルなチオールにより保護されたCdTeナノ結晶の合成と特性2008

    • Author(s)
      中嶋琢也, 小林由季, 河合壯
    • Organizer
      第6回ナノ学会
    • Place of Presentation
      福岡
    • Related Report
      2009 Final Research Report
  • [Book] "イオン液体におけるナノ~マイクロ界面の創成と利用", イオン液体III(大野弘幸監修)2010

    • Author(s)
      中嶋琢也
    • Publisher
      シーエムシー出版
    • Related Report
      2009 Final Research Report
  • [Remarks]

    • URL

      http://mswebs.naist.jp/center/LABs/kawai/

    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] フォトクロミック化合物及び追記型光記録分子材料2008

    • Inventor(s)
      河合壯、中嶋琢也、河合重一、中川久子
    • Industrial Property Rights Holder
      国立大学法人奈良先端科学技術大学院大学
    • Filing Date
      2008-09-09
    • Related Report
      2009 Final Research Report

URL: 

Published: 2008-04-01   Modified: 2016-04-21  

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