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Construction of Supramolecular Structures Based on Novel Multinuclear Metal Complexes Bearing π-Conjugated Systems

Research Project

Project/Area Number 20750118
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Functional materials chemistry
Research InstitutionInstitute for Molecular Science

Principal Investigator

ISHIZUKA Tomoya  Institute for Molecular Science, 大学院・数理物質科学研究科, 助教 (20435522)

Project Period (FY) 2008 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2009: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2008: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywordsπ共役系 / 遷移金属錯体 / 超分子科学 / 協同効果 / 構造・機能材料 / 自己組織化 / 磁性 / 超分子化学 / 光物性
Research Abstract

In this project, multinuclear complexes with a π-conjugated core, which consists of salophen moieties, have been synthesized and the self-integration behaviors based on the π-π stacking interactions have been investigated by microscopy techniques. In addition, the magnetic interaction between metal centers in the one-dimensional integrated structures has been studied by SQUID measurements.

Report

(3 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • Research Products

    (42 results)

All 2010 2009 2008

All Journal Article (11 results) (of which Peer Reviewed: 10 results) Presentation (31 results)

  • [Journal Article] Synthesis and Characterization of Ruthenium(II)- Pyridylamine Complexes with Catechol Pendants as Metal Binding Sites2010

    • Author(s)
      T. Kojima, N. Hirasa, D. Noguchi, T. Ishizuka, S. Miyazaki, Y. Shiota, K. Yoshizawa, S. Fukuzumi
    • Journal Title

      Inorg. Chem. 49

      Pages: 3737-3745

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Characterization of Ruthenium(II)-Pyridylamine Complexes with Catechol Pendants as Metal Binding Sites2010

    • Author(s)
      T.Kojima, N.Hirasa, D.Noguchi, T.Ishizuka, S.Miyazaki, Y.Shiota, K.Yoshizawa, S.Fukuzumi
    • Journal Title

      Inorganic Chemistry 49(in press)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly Planar Amphiphilic Porphyrins2009

    • Author(s)
      M. Oda, T. Ishizuka, S. Arai, A. Takano, D. Jiang
    • Journal Title

      Tetrahedron Lett. 50

      Pages: 7137-7140

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Single-Molecule Study on Intermolecular Interaction between C60 and Porphyrin Derivatives: Toward Understanding the Strength of the Multivalency2009

    • Author(s)
      Y. Zhang, Y. Yu, Z. Jiang, H. Xu, Z. Wang, X. Zhang, M. Oda, T. Ishizuka, D. Jiang, L. Chi, H. Fuchs
    • Journal Title

      Langmuir 25

      Pages: 6627-6632

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Noncovalently Netted, Photoconductive Sheets with Extremely High Carrier Mobility and Conduction Anisotropy from Triphenylene- Fused Metal Trigon Conjugates2009

    • Author(s)
      L. Chen, J. Kim, T. Ishizuka, Y. Honsho, A. Saeki, S. Seki, H. Ihee, D. Jiang
    • Journal Title

      J. Am. Chem. Soc. 131

      Pages: 7287-7292

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Highly Planar Amphiphilic Porphyrins2009

    • Author(s)
      M.Oda, T.Ishizuka, S.Arai, A.Takano, D.Jiang
    • Journal Title

      Tetrahedron Letters 50

      Pages: 7137-7140

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Single-Molecule Study on Intermolecular Interaction between C60 and Porphyrin Derivatives : Toward Understanding the Strength of the Multivalency2009

    • Author(s)
      Y.Zhang, Y.Yu, Z.Jiang, H.Xu, Z.Wang, X.Zhang, M.Oda, T.Ishizuka, D.Jiang, L.Chi, H.Fuchs
    • Journal Title

      Langmuir 25

      Pages: 6627-6632

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Noncovalently Netted, Photoconductive Sheets with Extremely High Carrier Mobility and Conduction Anisotropy from Triphenylene-Fused Metal Trigon Conjugates2009

    • Author(s)
      L.Chen, J.Kim, T.Ishizuka, Y.Honsho, A.Saeki, S.Seki, H.Ihee, D.Diang
    • Journal Title

      Journal of the American Chemical Society 25

      Pages: 6627-6632

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 金属錯体デンドリマーによる機能発現-光捕集・分子認識・磁気転移-2008

    • Author(s)
      石塚智也、江東林
    • Journal Title

      触媒 50巻

      Pages: 326-332

    • NAID

      10021070284

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Substitution, Dimerization, Metallation, and Ring-opening Reactions of N-Fused Porphyrins2008

    • Author(s)
      T. Ishizuka, S. Ikeda, M. Toganoh, I. Yoshida, Y. Ishikawa, A. Osuka, H. Furuta
    • Journal Title

      Tetrahedron 64

      Pages: 4037-4050

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] 金属錯体デンドリマーによる機能発現-光捕集・分子認識・磁気転移-2008

    • Author(s)
      石塚智也、江東林
    • Journal Title

      触媒 50

      Pages: 326-332

    • NAID

      10021070284

    • Related Report
      2008 Annual Research Report
  • [Presentation] N3型配位子を用いて合成した銅(II)錯体におけるピラゾールの4位に導入した置換基の効果2010

    • Author(s)
      姜華、石塚智也、藤澤清史、小島隆彦
    • Organizer
      第90回日本化学会春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-28
    • Related Report
      2009 Final Research Report
  • [Presentation] N3型配位子を用いて合成した銅(II)錯体におけるピラゾールの4位に導入した置換基の効果2010

    • Author(s)
      姜華、石塚智也、藤澤清史、小島隆彦
    • Organizer
      第90回日本化学会春季年会
    • Place of Presentation
      東大阪・近畿大学
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] 2,2'-ビピリジン部位を金属配位座として有するルテニウム(II)-ピリジルアミン錯体の合成と分子内電子移動特性2010

    • Author(s)
      矢野雄一、石塚智也、小島隆彦、福住俊一
    • Organizer
      第90回日本化学会春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-27
    • Related Report
      2009 Final Research Report
  • [Presentation] 2, 2'-ビピリジン部位を金属配位座として有するルテニウム(II)-ピリジルアミン錯体の合成と分子内電子移動特性2010

    • Author(s)
      矢野雄一、石塚智也、小島隆彦、福住俊一
    • Organizer
      第90回日本化学会春季年会
    • Place of Presentation
      東大阪・近畿大学
    • Year and Date
      2010-03-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] アニオン性N2型配位子を用いた銅錯体の構造と性質2010

    • Author(s)
      野口直人、石塚智也、藤澤清史、小島隆彦
    • Organizer
      第90回日本化学会春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-26
    • Related Report
      2009 Final Research Report
  • [Presentation] アニオン性N2型配位子を用いた銅錯体の構造と性質2010

    • Author(s)
      野口直人、石塚智也、藤澤清史、小島隆彦
    • Organizer
      第90回日本化学会春季年会
    • Place of Presentation
      東大阪・近畿大学
    • Year and Date
      2010-03-26
    • Related Report
      2009 Annual Research Report
  • [Presentation] アダマンチル基を導入した配位子を用いた銅(II)スーパーオキソ錯体の構造と性質2009

    • Author(s)
      寒沢至、石塚智也、藤澤清史、小島隆彦
    • Organizer
      第42回酸化反応討論会
    • Place of Presentation
      仙台
    • Year and Date
      2009-11-15
    • Related Report
      2009 Final Research Report
  • [Presentation] アダマンチル基を導入した配位子を用いた銅(II)スーパーオキソ錯体の構造と性質2009

    • Author(s)
      寒沢至、石塚智也、藤澤清史、小島隆彦
    • Organizer
      第42回酸化反応討論会
    • Place of Presentation
      仙台・東北大学
    • Year and Date
      2009-11-15
    • Related Report
      2009 Annual Research Report
  • [Presentation] ter-フェニルを母核とする二核シフ塩基錯体の合成と物性2009

    • Author(s)
      石塚智也、磯野裕貴子、江東林
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎
    • Year and Date
      2009-09-25
    • Related Report
      2009 Final Research Report
  • [Presentation] ter-フェニルを母核とする二核シフ塩基錯体の合成と物性2009

    • Author(s)
      石塚智也、磯野裕貴子、江東林
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎・長崎大学
    • Year and Date
      2009-09-25
    • Related Report
      2009 Annual Research Report
  • [Presentation] 異種多核共役シフ塩基錯体の超分子集積化と機能2009

    • Author(s)
      石塚智也、磯野裕貴子、江東林、三宅雄介、小川琢治、田中啓文
    • Organizer
      第58回高分子学会年次大会
    • Place of Presentation
      神戸
    • Year and Date
      2009-05-27
    • Related Report
      2009 Final Research Report
  • [Presentation] 新規両親媒性βアルキル型ポルフィリン錯体の超分子組織化の検討2009

    • Author(s)
      小田雅文、石塚智也、江東林
    • Organizer
      第58回高分子学会年次大会
    • Place of Presentation
      神戸
    • Year and Date
      2009-05-27
    • Related Report
      2009 Final Research Report
  • [Presentation] 異種多核共役シフ塩基錯体の超分子集積化と機能2009

    • Author(s)
      石塚智也、磯野裕貴子、江東林、三宅雄介、小川琢治、田中啓文
    • Organizer
      第58回高分子学会年次大会
    • Place of Presentation
      神戸・国際会議場
    • Year and Date
      2009-05-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] 新規両親媒性βアルキル型ポルフィリン錯体の超分子組織化の検討2009

    • Author(s)
      小田雅文、石塚智也、江東林
    • Organizer
      第58回高分子学会年次大会
    • Place of Presentation
      神戸・国際会議場
    • Year and Date
      2009-05-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] 新規両親媒性βアルキル型ポルフィリンの合成と超分子組織化2009

    • Author(s)
      小田雅文、石塚智也、江東林
    • Organizer
      第89回日本化学会春季年会
    • Place of Presentation
      船橋
    • Year and Date
      2009-03-30
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] 超分子集積化による異種多核シフ塩基錯体の物性制御2009

    • Author(s)
      石塚智也、磯野裕貴子、三宅雄介、田中啓文、小川琢治、江東林
    • Organizer
      第89回日本化学会春季年会
    • Place of Presentation
      船橋
    • Year and Date
      2009-03-30
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] Design and Supramolecular Assembly of Conjugated Multinuclear Schiff-base Complexes2009

    • Author(s)
      Tomoya Ishizuka
    • Organizer
      3rd Annual Meeting of JSPS Asia Core Program
    • Place of Presentation
      北京・中国
    • Year and Date
      2009-03-23
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] 両親媒性βアルキル型ポルフィリンの合成と超分子組織化2008

    • Author(s)
      小田雅文、石塚智也、江東林
    • Organizer
      第19回基礎有機化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2008-10-04
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] 異種多核共役シフ塩基錯体の設計と超分子集積化2008

    • Author(s)
      石塚智也、磯野裕貴子、江東林
    • Organizer
      第19回基礎有機化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2008-10-04
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] 両親媒性ベータアルキル型ポルフィリン金属錯体の合成と超分子組織化2008

    • Author(s)
      小田雅文、石塚智也、江東林
    • Organizer
      第57回錯体化学討論会
    • Place of Presentation
      金沢
    • Year and Date
      2008-09-20
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] 異種多核共役シフ塩基錯体の設計と超分子集積化2008

    • Author(s)
      石塚智也、磯野裕貴子、江東林
    • Organizer
      第57回錯体化学討論会
    • Place of Presentation
      金沢
    • Year and Date
      2008-09-20
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] Engineering of Intensely Absorbing, Long-Lived Excited-States in Conjugated Oligo (porphinato)zinc-(Polypyridyl) metal Complexes2008

    • Author(s)
      Timothy V. Duncan, Tomoya Ishizuka, Michael J. Therien
    • Organizer
      236th ACS National Meeting
    • Place of Presentation
      Philadelphia, USA
    • Year and Date
      2008-08-21
    • Related Report
      2009 Final Research Report
  • [Presentation] Engineering of Intensely Absorbing, Long-Lived Excited-States in Conjugated Oligo(porphinato) zinc -(Polypyridyl) metal Complexes2008

    • Author(s)
      Timothy V. Duncan,Tomoya Ishizuka, Michael J. Therien
    • Organizer
      236th ACS National Meeting
    • Place of Presentation
      Philadelphia, USA
    • Year and Date
      2008-08-21
    • Related Report
      2008 Annual Research Report
  • [Presentation] Design and Supramolecular Assembly of Conjugated Multinuclear Schiff-base Complexes2008

    • Author(s)
      Tomoya Ishizuka, Yukiko Isono, Dong-lin Jiang
    • Organizer
      236th ACS National Meeting
    • Place of Presentation
      Philadelphia, USA
    • Year and Date
      2008-08-20
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] Design and Supramolecular Assembly of Conjugated Multinuclear Schiff-base Complexes2008

    • Author(s)
      Tomoya Ishizuka, Yukiko Isono, Dong-Lin Jiang
    • Organizer
      5th International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments
    • Place of Presentation
      草津
    • Year and Date
      2008-06-10
    • Related Report
      2009 Final Research Report
  • [Presentation] Design and Supramolecular Assembly of Conjugated Multinuclear Schiff-base Complexes2008

    • Author(s)
      Tbmoya Ishizuka, Yukiko Isono, Dong-Lin Jiang
    • Organizer
      5th International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments
    • Place of Presentation
      滋賀
    • Year and Date
      2008-06-10
    • Related Report
      2008 Annual Research Report
  • [Presentation] 異種多核共役シフ塩基錯体の設計と超分子集積化2008

    • Author(s)
      石塚智也、磯野裕貴子、江東林
    • Organizer
      第57回高分子討論会
    • Place of Presentation
      横浜
    • Year and Date
      2008-05-30
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] Conjugated Disk-Like Multi-Schiff Base-A Motif to Access Multinuclear Complexatioll and Metallo-Cluster Self-Assembly2008

    • Author(s)
      陳龍、石塚智也、田中啓文、江東林
    • Organizer
      第57回高分子討論会
    • Place of Presentation
      横浜
    • Year and Date
      2008-05-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] Conjugated Disk-Like Multi-Schiff Base-A Motif to Access Multinuclear Complexation and Metallo-Cluster Self-Assembly2008

    • Author(s)
      陳龍、石塚智也、田中啓文、江東林
    • Organizer
      第57回高分子討論会
    • Place of Presentation
      横浜
    • Year and Date
      2008-05-29
    • Related Report
      2009 Final Research Report
  • [Presentation] Coupled- Oscillator Photophysics and the Elaboration of Chromophores with Exceptional Molecular Hyperpolarizabilities and 2-Photon Absorptive Cross- Sections2008

    • Author(s)
      Timothy V. Duncan, Tomoya Ishizuka, Michael J. Therien, 他8名
    • Organizer
      235th ACS National Meeting
    • Place of Presentation
      New Orleans, USA
    • Year and Date
      2008-04-28
    • Related Report
      2009 Final Research Report
  • [Presentation] Coupled-Oscillator Photophysics and the Elaboration of Chromophores with Exceptional Molecular Hyperpolarizabilities and 2-Photon Absorptive Cross-Sections2008

    • Author(s)
      Timothy V. Duncan, Tomva Ishizuka,○Michael J. Therien, 他8名
    • Organizer
      235th ACS National Meeting
    • Place of Presentation
      New Orleans, USA
    • Year and Date
      2008-04-08
    • Related Report
      2008 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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