| Project/Area Number |
20750119
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Functional materials chemistry
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| Research Institution | Institute for Molecular Science |
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Principal Investigator |
NISHIJO Junichi Institute for Molecular Science, 物質分子科学研究領域, 助教 (00390641)
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| Project Period (FY) |
2008 – 2010
|
| Project Status |
Completed (Fiscal Year 2010)
|
| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2010: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2009: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2008: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
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| Keywords | アセチリド / 分子性磁性体 / 複合機能性 / tetrathiafulvalene / 遷移金属錯体 / 弱強磁性 / TTF / フェリ磁性 / 強磁性 |
|---|
| Research Abstract |
New magnetic materials containing chromium-acetylide complexes were developed. Based on the result, a new chromium acetylide complex was synthesized where TTF-type molecules, which is a typical conductive organic molecule, was employed as ligands. In the oxidation state of the complex, an extraordinary strong exchange interaction is observed between a chromium cation and TTF-type ligands, indicating that the complex is promising to construct strongly interacting π-d systems.
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