Development of Environmentally-Friendly Asymmetric Reaction System Based on Solvent -Free Organic Reactions
Project/Area Number |
20750122
|
Research Category |
Grant-in-Aid for Young Scientists (B)
|
Allocation Type | Single-year Grants |
Research Field |
Environmental chemistry
|
Research Institution | Kyushu University |
Principal Investigator |
FURUNO Hiroshi Kyushu University, 先導物質化学研究所, 助教 (90335993)
|
Project Period (FY) |
2008 – 2010
|
Project Status |
Completed (Fiscal Year 2010)
|
Budget Amount *help |
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2010: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2009: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2008: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
|
Keywords | 合成化学 / 不斉合成 / 環境調和型反応 / 触媒設計 / 無溶媒反応 / 回収・再利用可能触媒 / 無溶媒不均一反応 / 自己組織化型錯体触媒 / 希土類金属錯体 / 環境調和型合成 / 再利用可能ルイス酸触媒 |
Research Abstract |
In order to develop environmentally-friendly asymmetric reaction systems, novel polymeric rare earth metal complexes were prepared from rare earth metal ions and ligands with multi-way spacers in a self-organized manner. These complexes effectively worked as a Lewis acid catalyst under solvent-free conditions, and could be recovered after the reaction and reused to the next one. Also, organic polymers could be used as a substitute reaction media for an organic solvent.
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Report
(4 results)
Research Products
(18 results)