Development of Environmentally-Friendly Asymmetric Reaction System Based on Solvent -Free Organic Reactions

• Project/Area Number: 20750122
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Environmental chemistry
• Research Institution: Kyushu University
• Principal Investigator: FURUNO Hiroshi Kyushu University, 先導物質化学研究所, 助教 (90335993)
• Project Period (FY): 2008 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000); Fiscal Year 2010: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000); Fiscal Year 2009: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000); Fiscal Year 2008: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
• Keywords: 合成化学 / 不斉合成 / 環境調和型反応 / 触媒設計 / 無溶媒反応 / 回収・再利用可能触媒 / 無溶媒不均一反応 / 自己組織化型錯体触媒 / 希土類金属錯体 / 環境調和型合成 / 再利用可能ルイス酸触媒

Research Abstract

In order to develop environmentally-friendly asymmetric reaction systems, novel polymeric rare earth metal complexes were prepared from rare earth metal ions and ligands with multi-way spacers in a self-organized manner. These complexes effectively worked as a Lewis acid catalyst under solvent-free conditions, and could be recovered after the reaction and reused to the next one. Also, organic polymers could be used as a substitute reaction media for an organic solvent.

Research Products

• [Journal Article] 精密有機合成を目的とした希土類金属錯体触媒の開発 (2010)
  • Author(s): 古野裕史
  • Journal Title: 希土類 56 Pages: 122-123
  • NAID: 10027671126
• [Journal Article] 精密有機合成を目的とした希土類金属錯体触媒の開発 (2010)
  • Author(s): 古野裕史
  • Journal Title: 希土類 Volume: 56 Pages: 122-123
  • NAID: 10027671126
• [Journal Article] Heterogeneous Lewis Acid Catalysis with Self-Organized Polymeric Rare Earth Arylsulfonates under Solvent-Free Conditions (2009)
  • Author(s): H.Furuno, S.Ishida, S.Suzuki, T.Hayano, S.Onitsuka, J.Inanaga
  • Journal Title: Heterocycles 77 Pages: 1007-1018
  • NAID: 40016454340
  • Peer Reviewed
• [Journal Article] Heterogeneous Lewis Acid Catalysis with Self-Organized Polymeric Rare Earth Arvlsulfonates under Solvent-Free Conditions (2009)
  • Author(s): Hiroshi Furuno, et.al.
  • Journal Title: Heterocycles 77 Pages: 1007-1018
  • Peer Reviewed
• [Presentation] Heterogeneous Lewis Acid Catalysis with Polymeric Rare Earth Sulfonates and Phosphates (2011)
  • Author(s): H.Furuno, T.Horitani, S.Ishida, T.Hayano, S.Onitsuka, J.Inanaga
  • Organizer: The 1st International Conference on MEXT Project of Integrated Research on Chemical Synthesis
  • Place of Presentation: Sapporo, Japan
  • Year and Date: 2011-01-24
• [Presentation] Heterogeneous Lewis Acid Catalysis with Polymeric Rare Earth Sulfonates and Phosphates (2011)
  • Author(s): 古野裕史
  • Organizer: The 1st International Conference on MEXT Project of Integrated Research on Chemical Synthesis
  • Place of Presentation: 北海道大学触媒化学研究センター(札幌)
  • Year and Date: 2011-01-24
• [Presentation] スルホ置換BINOL誘導体を配位子とする自己組織化型キラルルイス酸触媒 (2010)
  • Author(s): 堀谷拓未, 塘依理子, 古野裕史, 鬼束聡明, 稲永純二
  • Organizer: 第47回化学関連支部合同九州大会
  • Place of Presentation: 北九州
  • Year and Date: 2010-07-10
• [Presentation] 精密有機合成を目的とした希土類金属錯体触媒の開発 (2010)
  • Author(s): 古野裕史
  • Organizer: 第27回希土類討論会
  • Place of Presentation: 北九州
  • Year and Date: 2010-05-28
• [Presentation] 精密有機合成を目的とした希土類金属錯体触媒の開発 (2010)
  • Author(s): 古野裕史
  • Organizer: 第27回希土類討論会
  • Place of Presentation: 北九州国際会議場(北九州)
  • Year and Date: 2010-05-28
• [Presentation] Self-Organized Polymeric Rare Earth Arylsulfonates as a Reusable Heterogeneous Lewis Acid Catalyst (2009)
  • Author(s): H.Furuno, S.Ishida, S.Suzuki, S.Onitsuka, J.Inanaga
  • Organizer: 12th Kyushu International Symposium on Physical Organic Chemistry (KISPOC-XII)
  • Place of Presentation: Fukuoka, Japan
  • Year and Date: 2009-12-16
• [Presentation] Self-Organized Polymeric Rare Earth Arylsulfonates as a Reusable Heterogeneous Lewis Acid Catalyst (2009)
  • Author(s): 古野裕史
  • Organizer: 12th Kyushu International Symposium on Physica 1 Organic Chemistry (KISPOC-XII)
  • Place of Presentation: 福岡
  • Year and Date: 2009-12-16
• [Presentation] キラル及びアキラルな含フッ素配位子を装着した希土金属錯体を用いる触媒反応 (2009)
  • Author(s): 古野裕史
  • Organizer: 第16回有機フッ素化学セミナー
  • Place of Presentation: 岡山
  • Year and Date: 2009-09-12
• [Presentation] 希土類ナノ粒子および希土類イオンーモンモリロナイト担持触媒を用いる不斉合成反応の開発 (2009)
  • Author(s): 鬼束聡明, 古野裕史, 稲永純二
  • Organizer: 第26回希土類討論会
  • Place of Presentation: 札幌
  • Year and Date: 2009-05-29
• [Presentation] 自己組織化型アリールスルホン酸スカンジウムを触媒とする無溶媒反応 (2009)
  • Author(s): 古野裕史, 石田修一, 鈴木祥子, 鬼束聡明, 稲永純二
  • Organizer: 第4回物質合成シンポジウム
  • Place of Presentation: 名古屋
  • Year and Date: 2009-01-23
• [Presentation] 自己組織化型アリールスルホン酸スカンジウムを触媒とする無溶媒反応 (2009)
  • Author(s): 古野裕史
  • Organizer: 第4回物質合成シンポジウム「合成化学とナノ科学の接点」
  • Place of Presentation: 名古屋
  • Year and Date: 2009-01-23
• [Presentation] 自己組織化型希土類金属錯体触媒を用いる無溶媒不均一反応 (2008)
  • Author(s): 古野裕史, 石田修一, 鈴木祥子, 鬼束聡明, 稲永純二
  • Organizer: 2008年日本化学会西日本大会
  • Place of Presentation: 長崎
  • Year and Date: 2008-11-15
• [Presentation] 自己組織化型高分子希土類ルイス酸触媒を用いる無溶媒不均一反応 (2008)
  • Author(s): 古野裕史, 石田修一, 鈴木祥子, 鬼束聡明, 稲永純二
  • Organizer: 第25回有機合成化学セミナー
  • Place of Presentation: 熊本
  • Year and Date: 2008-09-08
• [Presentation] 自己組織化型高分子希土類ルイス酸触媒を用いる無溶媒不均一反応 (2008)
  • Author(s): 古野裕史
  • Organizer: 第25回有機合成化学セミナー
  • Place of Presentation: 阿蘇(熊本)
  • Year and Date: 2008-09-08