Development of Highly Active Catalyst for Oxygen Evolution
Project/Area Number |
20750123
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Research Category |
Grant-in-Aid for Young Scientists (B)
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Allocation Type | Single-year Grants |
Research Field |
Environmental chemistry
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Research Institution | Institute for Molecular Science |
Principal Investigator |
WADA Tohru Institute for Molecular Science, 生命・錯体分子科学研究領域, 助教 (30342637)
|
Project Period (FY) |
2008 – 2009
|
Project Status |
Completed (Fiscal Year 2009)
|
Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2009: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2008: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
|
Keywords | 高機能触媒 / エネルギー変換 / 水の酸化反応 / 触媒 / 複核錯体 / 反応機構 / 共鳴ラマン / 酸化還元 / 酸素 / 水 / 再生可能エネルギー / 酵素反応 / 人工光合成 |
Research Abstract |
There is much attention to water-oxidation catalyst from a view point of environmental and energy problems. In this project, dinuclear ruthenium complex was prepared as a water oxidation catalyst. The mechanism of O-O bond formation from two water molecules was elucidated by a spectroscopic analysis.
|
Report
(3 results)
Research Products
(13 results)
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[Journal Article] Characterization of Redox States of Ru(OH2)(Q)(tpy)2+ (Q = 3, 5-di-tert-butyl-1, 2-benzoquinone, tpy = 2, 2':6', 2''-terpyridine) and Related Species through Experimental and Theoretical Studies.2009
Author(s)
Tsai, M. -K.; Rochford, J.; Polyansky, D.E.; Wada, T.; Tanaka, K.; Fujita, E.
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Journal Title
J.T. Inorg. Chem. 48
Pages: 4372-4383
Related Report
Peer Reviewed
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[Journal Article] Characterization of Redox States of Ru(OH_2)(Q)(tpy)^<2+>(Q=3,5-di-tert-butyl-1,2-benzoquinone, tpy=2,2':6',2"-terpyridine)and Related Species through Experimental and Theoretical Studies2009
Author(s)
Tsai, M.-K., Rochford, J., Polyansky, D.E., Wada, T., Tanaka, K., Fujita, E., Muckerman, J.T.
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Journal Title
Inorganic Chemistry 48
Pages: 4172-4383
Related Report
Peer Reviewed
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