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Synthesis of Fluorescent Metal Complexes Possessing Solid-state Photoelectronic Properties and their Applications to Optoelectronic Devices

Research Project

Project/Area Number 20750161
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Organic industrial materials
Research InstitutionHiroshima University

Principal Investigator

OOYAMA Yousuke  Hiroshima University, 大学院・工学研究科, 助教 (60403581)

Project Period (FY) 2008 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2009: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2008: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords機能性有機材料 / 蛍光性色素 / 光物性 / 蛍光性金属錯体 / 色素増感太陽電子 / 光電子デバイス / 固体蛍光 / 色素増感太陽電池
Research Abstract

We have designed and synthesized novel fluorescent dye ligand (1) and their ruthenium complex (2), and their photophysical and electrochemical properties have been investigated. Furthermore, dye-sensitized solar cells (DSSCs) were fabricated using the fluorescent dye ligand (1) and their metal complex (2). The solar energy-to-electricity conversion yields (η) are 0.2% for fluorescent dye ligand (1) and 0.1% for ruthenium complex (2) respectively.

Report

(3 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • Research Products

    (31 results)

All 2010 2009 2008

All Journal Article (9 results) (of which Peer Reviewed: 6 results) Presentation (22 results)

  • [Journal Article] Solvatochromism of novel donor-π-acceptor type pyridinium dyes in halogenated and non-halogenated solvents2009

    • Author(s)
      Y. Ooyama, R. Asada, S. Inoue, I. Imae, K. Komaguchi, Y. Harima
    • Journal Title

      New J. Chem 33

      Pages: 2311-2316

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Molecular Designs and Syntheses of Organic Dyes for Dye-Sensitized Solar Cells2009

    • Author(s)
      Y. Ooyama, Y. Harima
    • Journal Title

      Eur. J. Org. Chem 18

      Pages: 2903-2934

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] 蛍光性色素の色素増感太陽電池への応用2009

    • Author(s)
      大山陽介、播磨裕
    • Journal Title

      化学工業 60(4)

      Pages: 286-292

    • Related Report
      2009 Final Research Report
  • [Journal Article] Photovoltaic performance of dye-sensitized solar cells based on a series of new-type donor-acceptorπ-conjugated sensitizer, benzofuro[2, 3-c]oxazolo[4, 5-a]carbazole fluorescent dyes2009

    • Author(s)
      Y. Ooyama, Y. Shimada, G. Ito, A. Ishii, Y. Kagawa, I. Imae, K. Komaguchi, Y. Harima
    • Journal Title

      J. Photochem. Photobiol. A 203

      Pages: 177-185

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Molecular Designs and Syntheses of Organic Dyes for Dye-Sensitized Solar Cells2009

    • Author(s)
      大山陽介
    • Journal Title

      European Journal of Organic Chemistry 18

      Pages: 2903-2934

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 蛍光性色素の色素増感太陽電池への応用2009

    • Author(s)
      大山陽介
    • Journal Title

      化学工業 60(4)

      Pages: 286-292

    • Related Report
      2009 Annual Research Report
  • [Journal Article] Solvatochromism of novel donor-π-acceptor type pyridinium dyes in halogenated and non-halogenated solvents2009

    • Author(s)
      大山陽介
    • Journal Title

      New Journal of Chemistry 33

      Pages: 2311-2316

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 蛍光性色素の色素増感太陽電池への応用2009

    • Author(s)
      大山陽介
    • Journal Title

      化学工業 60(印刷中)

    • Related Report
      2008 Annual Research Report
  • [Journal Article] Photovoltaic performance of dye-sensitized solar cells based on a series of new-type donor-acceptor π-conjugated sensitizer, benzofuro [2, 3-c] oxazolo [4, 5-a] carbazole fluorescent dyes2009

    • Author(s)
      大山陽介
    • Journal Title

      Journal of Photochemistry and Photobiology A : Chemistry (印刷中)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] 蛍光性色素を用いた有機溶媒中の微量水分検出2010

    • Author(s)
      李木美菜子・大山陽介・駒口健治・今栄一郎・播磨裕
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学
    • Year and Date
      2010-03-29
    • Related Report
      2009 Final Research Report
  • [Presentation] カルバゾオキサゾール系蛍光性色素のメカノフルオロクロミズム2010

    • Author(s)
      大山陽介・伊藤玄太・香川裕介・福岡宏・駒口健治・今栄一郎・播磨裕
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学
    • Year and Date
      2010-03-28
    • Related Report
      2009 Final Research Report
  • [Presentation] カルバゾオキサゾール系蛍光性色素のメカノフルオロクロミズム2010

    • Author(s)
      大山陽介
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] 新規なピリジン系蛍光性色素を用いた色素増感太陽電池2010

    • Author(s)
      永野智也・井上将吾・大山陽介・駒口健治・今栄一郎・播磨裕
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学
    • Year and Date
      2010-03-26
    • Related Report
      2009 Final Research Report
  • [Presentation] Dye-Sensitized Solar Cells based on Arrangement and Orientation of Fluorescent Dyes2009

    • Author(s)
      Y. Ooyama, Y. Shimada, K. Komaguchi, I. Imae, Y. Harima
    • Organizer
      The 11th International Kyoto Conference on New Aspects of Organic Chemistry
    • Place of Presentation
      in Kyoto, Japan
    • Year and Date
      2009-11-10
    • Related Report
      2009 Final Research Report
  • [Presentation] Dye-Sensitized Solar Cells Based on Novel Fluorescent Pyridine Dye and Near Infrared Pyridinium Dye Forming Strong Interaction with Nanocrystalline TiO2 Films2009

    • Author(s)
      S. Inoue, R. Asada, Y. Ooyama, K. Komaguchi, I. Imae, Y. Harima
    • Organizer
      The 11th International Kyoto Conference on New Aspects of Organic Chemistry
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2009-11-10
    • Related Report
      2009 Final Research Report
  • [Presentation] Mechanofluorochromism of a Series of Donor-π-Acceptor-type Benzofuro[2, 3-c]oxazolo[4, 5-a] carbazole- type Fluorescent Dyes2009

    • Author(s)
      G. Ito, Y. Ooyama, H. Fukuoka, K. Komaguchi, I. Imae, Y. Harima
    • Organizer
      The 11th International Kyoto Conference on New Aspects of Organic Chemistry
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2009-11-10
    • Related Report
      2009 Final Research Report
  • [Presentation] D-π-A系蛍光色素のメカノフルオロクロミズム2009

    • Author(s)
      伊藤玄太・大山陽介・福岡宏・駒口健治・今栄一郎・播磨裕
    • Organizer
      2009年日本化学会西日本大会
    • Place of Presentation
      長崎大学
    • Year and Date
      2009-11-08
    • Related Report
      2009 Final Research Report
  • [Presentation] 新規なピリジン系蛍光性色素およびピリジニウム系近赤外吸収色素を用いた色素増感太陽電池2009

    • Author(s)
      井上将吾・浅田里沙・大山陽介・駒口健治・今榮一郎・播磨裕
    • Organizer
      2009年日本化学会西日本大会
    • Place of Presentation
      長崎大学
    • Year and Date
      2009-11-07
    • Related Report
      2009 Final Research Report
  • [Presentation] Synthesis of Novel Pyridine and Pyridinium Dyes and their Photovoltaic Performance of Dye-Sensitized Solar Cells2009

    • Author(s)
      S. Inoue, R. Asada, Y. Shimada, Y. Ooyama, K. Komaguchi, I. Imae, Y. Harima
    • Organizer
      Fourth East Asia Symposium on Functional Dyes and Advanced Materials
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      2009-06-04
    • Related Report
      2009 Final Research Report
  • [Presentation] Mechanofluorochromism of a Series of Benzofuro[2,3-c]oxazolo[4,5-a]carbazole-type Fluorescent Dyes by Controlling Intermolecular π-π Interactions2009

    • Author(s)
      大山陽介
    • Organizer
      Fourth East Asia Symposium on Functional Dyes and Advanced Materials
    • Place of Presentation
      大阪
    • Year and Date
      2009-06-04
    • Related Report
      2009 Annual Research Report
  • [Presentation] Mechanofluorochromism of a Series of Benzofuro[2, 3-c]oxazolo[4, 5-a] carbazole- type Fluorescent Dyes by Controlling Intermolecularπ-πInteractions2009

    • Author(s)
      Y. Ooyama, H. Fukuoka, K. Komaguchi, I. Imae, Y. Harima
    • Organizer
      Fourth East Asia Symposium on Functional Dyes and Advanced Materials
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      2009-06-03
    • Related Report
      2009 Final Research Report
  • [Presentation] カルバゾオキサゾール系色素を用いた色素増感太陽電池の光電変換特性2009

    • Author(s)
      嶋田義仁・大山陽介・駒口健治・今栄一郎・播磨裕
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学
    • Year and Date
      2009-03-29
    • Related Report
      2009 Final Research Report
  • [Presentation] メカノフルオロクロミック特性を有するカルバゾオキサゾール系蛍光性色素の分子設計と合成2009

    • Author(s)
      大山陽介・伊藤玄太・香川裕介・福岡宏・駒口健治・今栄一郎・播磨裕
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学
    • Year and Date
      2009-03-29
    • Related Report
      2009 Final Research Report
  • [Presentation] 分子間π-π相互作用を制御したカルバゾオキサゾール系蛍光色素のメカノフルオロクロミック特性2009

    • Author(s)
      伊藤玄太・大山陽介・福岡宏・駒口健治・今栄一郎・播磨裕
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学
    • Year and Date
      2009-03-28
    • Related Report
      2009 Final Research Report
  • [Presentation] 新規なピリジニウム塩系近赤外吸収色素の合成と色素増感太陽電池への応用2009

    • Author(s)
      大山陽介・浅田里沙・駒口健治・今栄一郎・播磨裕
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学
    • Year and Date
      2009-03-28
    • Related Report
      2009 Final Research Report
  • [Presentation] カルバゾオキサゾール系蛍光色素のメカノフルオロクロミズム2008

    • Author(s)
      大山陽介・香川裕介・駒口健治・今栄一郎・播磨裕
    • Organizer
      第2回有機π電子系シンポジウム
    • Place of Presentation
      広島
    • Year and Date
      2008-12-05
    • Related Report
      2009 Final Research Report
  • [Presentation] 固体発光型オキサゾール系蛍光色素のメカノフルオロクロミック特性2008

    • Author(s)
      伊藤玄太・大山陽介・駒口健治・今榮一郎・播磨裕
    • Organizer
      2008年日本化学会西日本大会
    • Place of Presentation
      長崎大学
    • Year and Date
      2008-11-15
    • Related Report
      2009 Final Research Report
  • [Presentation] ピリジニルオキサゾール系蛍光性色素の合成, 光物性, 電気化学的特性2008

    • Author(s)
      浅田里沙・大山陽介・駒口健治・今栄一郎・播磨裕
    • Organizer
      2008年日本化学会西日本大会
    • Place of Presentation
      長崎大学
    • Year and Date
      2008-11-15
    • Related Report
      2009 Final Research Report
  • [Presentation] Mechanofluorochromism of a Series of Benzofuro[2, 3-c]oxazolocarbazole- type Fluorescent Dyes2008

    • Author(s)
      Y. Ooyama, Y. Kagawa, H. Fukuoka, K. Komaguchi, I. Imae,, Y. Harima
    • Organizer
      8th International symposium on Functionalπ-Electron Systems
    • Place of Presentation
      Graz, Austria
    • Year and Date
      2008-07-21
    • Related Report
      2009 Final Research Report
  • [Presentation] Mechanofluorochromism of a Series of Benzofuro [2, 3-c] oxazolocarbazole-type Fluorescent Dyes2008

    • Author(s)
      大山陽介
    • Organizer
      8^<th> International symposium on Functional π-Electron Systems
    • Place of Presentation
      グラーツ, オーストリア
    • Year and Date
      2008-07-21
    • Related Report
      2008 Annual Research Report
  • [Presentation] カルボキシル基を2つ有する新規なdonor-π-acceptor型蛍光色素の合成と色素増感太陽電池への応用2008

    • Author(s)
      伊藤玄太・大山陽介・駒口健治・今榮一郎・播磨裕
    • Organizer
      第32回有機電子移動化学討論会-エレクトロオーガニックケミストリー討論会
    • Place of Presentation
      大阪
    • Year and Date
      2008-06-26
    • Related Report
      2009 Final Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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