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Developnent of functional ceria nanosheets catalyst using two dimensional reaction filed

Research Project

Project/Area Number 20750167
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Inorganic industrial materials
Research InstitutionThe University of Tokushima

Principal Investigator

NAKAGAWA Keizo  The University of Tokushima, 大学院・ソシオテクノサイエンス研究部, 講師 (60423555)

Project Period (FY) 2008 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2009: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2008: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords無機合成 / 触媒 / セリアナノ粒子 / ナノワイヤー / 界面活性剤 / 水熱合成法 / 酸素ストレージ能 / 炭素燃焼反応 / セリア / ナノシート / ナノロッド
Research Abstract

Novel functional ceria (CeO_2) nanoparitices with different morphology in hydrothermal solution including carbonate ion have been developed. Cerium carbonate with nanowires, nanorods, nanosheets morphology has been successfully synthesized using surfactants. Their morphologies were sustained after thermal decomposition-oxidation to ceria. Each ceria nanoparticles synthesized using surfactant exhibited higher oxygen storage capacity than ceria nanoparticles synthesized without surfactants. These ceria nanoparticles showed superior activity for the carbon combustion than JRC-CEO-1.

Report

(3 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • Research Products

    (18 results)

All 2010 2009 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (11 results) Remarks (2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Sintering Resistance and Catalytic Activity of Platinum Nanoparticles Covered with a Microporous Silica Layer using Methyltriethoxysilane2010

    • Author(s)
      Keizo Nakagawa, Yusuke Tanimoto, Tetsuya Okayama, Ken-Ichiro Sotowa, Shigeru Sugiyama, Sakae Takenaka, Masahiro Kishida
    • Journal Title

      Catalysis Letters Vol.136,No.1-2

      Pages: 71-76

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Control of Morphology and Surface Property of Flaky Layered Titanate Nanosheets using Surfactant in Hydrothermal Solution2010

    • Author(s)
      Keizo Nakagawa, Toshimasa Ogata, Ken-Ichiro Sotowa, Shigeru Sugiyama, Motonari Adachi
    • Journal Title

      International Journal of Modern Physics B Vol.24,No.12-13(in press)

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Sintering Resistance and Catalytic Activity of Platinum Nanoparticles Covered with a Microporous Silica Layer using Methyltriethoxysilane2010

    • Author(s)
      Keizo Nakagawa, et al
    • Journal Title

      Catalysis Letters 136(in press)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Control of Morphology and Surface Property of Flaky Layered Titanate Nanosheets using Surfactant in Hydrothermal Solution2010

    • Author(s)
      Keizo Nakagawa, et al
    • Journal Title

      International Journal of Modern Physics B 24(in press)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] アミン系界面活性剤を用いた水熱合成法によるセリアナノワイヤーの調製と炭素燃焼特性2010

    • Author(s)
      尾方敏匡, 中川敬三, 外輪健一郎, 杉山茂
    • Organizer
      第105回触媒討論会(触媒討論会A)
    • Year and Date
      2010-03-24
    • Related Report
      2009 Final Research Report
  • [Presentation] アミン系界面活性剤を用いた水熱合成法によるセリアナノワイヤーの調製と炭素燃焼特性2010

    • Author(s)
      中川敬三
    • Organizer
      第105回触媒討論会(触媒討論会A)
    • Place of Presentation
      京都テルサ(京都市)
    • Year and Date
      2010-03-24
    • Related Report
      2009 Annual Research Report
  • [Presentation] Preparation of Ceria Nanoparticles Using Surfactant Assisted Method and Thier Combustion Properties of Carbon2009

    • Author(s)
      Toshimasa Ogata, Keizo Nakagawa, Ken-Ichiro Sotowa, Shigeru Sugiyama
    • Organizer
      22th Symposium on Chemical Engineering, Kyushu-Taejon/Chungnam
    • Place of Presentation
      Daejean
    • Year and Date
      2009-12-05
    • Related Report
      2009 Final Research Report
  • [Presentation] Preparation of Ceria Nanoparticles Using Surfactant Assisted Method and Thier Combustion Properties of Carbon2009

    • Author(s)
      Toshimasa Ogata
    • Organizer
      22th Symposium on Chemical Engineering, Kyushu-Taejon/Chungnam
    • Place of Presentation
      Daejon Convention Center (Daejeon, Republic of Korea)
    • Year and Date
      2009-12-05
    • Related Report
      2009 Annual Research Report
  • [Presentation] 界面活性剤を利用した水熱合成法によるセリアナノ粒子の合成と炭酸イオン添加効果2009

    • Author(s)
      尾方敏匡, 中川敬三, 外輪健一郎, 杉山茂
    • Organizer
      化学工学会第41回秋季大会
    • Year and Date
      2009-09-16
    • Related Report
      2009 Final Research Report
  • [Presentation] 界面活性剤を利用した水熱合成法によるセリアナノ粒子の合成と炭酸イオン添加効果2009

    • Author(s)
      尾方敏匡
    • Organizer
      化学工学会第41回秋季大会
    • Place of Presentation
      広島大学(東広島市)
    • Year and Date
      2009-09-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] 炭酸セリウムを前駆体としたセリアナノワイヤーの合成と炭素燃焼活性2009

    • Author(s)
      尾方敏匡, 中川敬三, 外輪健一郎, 杉山茂
    • Organizer
      化学工学会第3回中四国若手CE合宿
    • Year and Date
      2009-08-06
    • Related Report
      2009 Final Research Report
  • [Presentation] 炭酸セリウムを前駆体としたセリアナノワイヤーの合成と炭素燃焼活性2009

    • Author(s)
      尾方敏匡
    • Organizer
      化学工学会第3回中四国若手CE合宿
    • Place of Presentation
      かんぽの宿徳島(徳島市)
    • Year and Date
      2009-08-06
    • Related Report
      2009 Annual Research Report
  • [Presentation] 界面活性剤を利用した異なる形状を持つセリアナノ粒子の調製と炭素燃焼特性2009

    • Author(s)
      尾方敏匡, 中川敬三, 外輪健一郎, 杉山茂
    • Organizer
      触媒学会弟3回触媒道場
    • Year and Date
      2009-07-03
    • Related Report
      2009 Final Research Report
  • [Presentation] 界面活性剤を利用した異なる形状を持つセリアナノ粒子の調製と炭素燃焼特性2009

    • Author(s)
      尾方敏匡
    • Organizer
      触媒学会第3回触媒道場
    • Place of Presentation
      ホテルセントラーザ博多(福岡市)
    • Year and Date
      2009-07-03
    • Related Report
      2009 Annual Research Report
  • [Presentation] 界面活性剤を利用した水熱合成法によるセリアナノシートの創製2009

    • Author(s)
      尾方敏匡, 中川敬三ら, 他
    • Organizer
      第三回Chem-Eng研究会ミニシンポジウム
    • Place of Presentation
      神戸研究学園都市UNITY
    • Year and Date
      2009-03-27
    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://pub2.db.tokushima-u.ac.jp/ERD/person/155080/profile-ja.html

    • Related Report
      2009 Final Research Report
  • [Remarks]

    • URL

      http://pub2.db.tokushima-u.ac.jp/ERD/person/155080/profile-ja.html

    • Related Report
      2009 Annual Research Report
  • [Patent(Industrial Property Rights)] 薄片様層状化合物2009

    • Inventor(s)
      中川敬三, 杉山茂, 外輪健一郎
    • Industrial Property Rights Holder
      国立大学法人徳島大学
    • Industrial Property Number
      2009-208349
    • Filing Date
      2009-09-09
    • Related Report
      2009 Final Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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