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Structure and Ionic Conduction of Solid Electrolyte Confined in Nanopores

Research Project

Project/Area Number 20750168
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Inorganic industrial materials
Research InstitutionNagasaki University

Principal Investigator

YAMADA Hirotoshi  Nagasaki University, 工学部, 准教授 (10359961)

Project Period (FY) 2008 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2009: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2008: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywordsイオン交換体・伝導体 / 固体電解質 / 全固体型電池 / 界面 / 空間電荷層 / 結晶歪み
Research Abstract

In this study, structure and ionic conductivity at nano hetero interfaces are studied. As for AgI/mesoporous Al_2O_3 system, which shows peculiar ionic conduction, it was revealed that AgI confined in nanopores is amorphous and molten Ag ions move in a rigit I-ion framework freely like Ag ion in alpha AgI. For the interface of solid electrolyte and electrochemically active materials, difference of chemical potentials of ions induces change in composition and ionic conductivity.

Report

(3 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • Research Products

    (17 results)

All 2010 2009 2008 Other

All Journal Article (8 results) (of which Peer Reviewed: 4 results) Presentation (9 results)

  • [Journal Article] Fast Li-ion insertion into nanosized LiMn2O4 without domain boundaries2010

    • Author(s)
      M. Okubo, Y. Mizuno, H. Yamada, J. Kim, E. Hosono, H. Zhou, T. Kudo, I. Honma
    • Journal Title

      ACS Nano 4(2)

      Pages: 741-752

    • Related Report
      2009 Final Research Report
  • [Journal Article] Organic-Inorganic Hybrid Material as New Matrices of Proton Conducting Membranes2010

    • Author(s)
      H.Yamada
    • Journal Title

      Chemistry Letters (in press)(掲載確定)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fast Li-ion insertion into nanosized LiMn2O4 without domain boundaries2010

    • Author(s)
      M.Okubo
    • Journal Title

      ACS Nano 4

      Pages: 741-752

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of surface acidity and pore size of mesoporous alumina on degree of loading and controlled release of ibuprofen2009

    • Author(s)
      S.K. Das, S. Kapoor, H. Yamada, A.J. Bhattacharyya
    • Journal Title

      Microporous and Mesoporous Materials 118(1-3)

      Pages: 267-272

    • Related Report
      2009 Final Research Report
  • [Journal Article] Effects of surface acidity and pore size of mesoporous alumina on degre e of loading and controlled release of ibuprofen2009

    • Author(s)
      S. K. Das
    • Journal Title

      Microporous Mesoporous Mater. 118

      Pages: 267-272

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Colloidal Crystal-Derived Nanoporous Electrode Materials of Cut SWNTs-Assembly and TiO2/SWNTs Nanocomposite2008

    • Author(s)
      I. Moriguchi, Y. Shono, H. Yamada, T. Kudo
    • Journal Title

      J. Phys. Chem. B 112(46)

      Pages: 14560-14565

    • Related Report
      2009 Final Research Report
  • [Journal Article] Colloidal Crystal-Derived Nanoporous Electrode Materials of Cut SWNT s-Assembly and TiO_2/SWNTs Nanocomposite2008

    • Author(s)
      I. Moriguchi
    • Journal Title

      J. Phys. Chem. B 112

      Pages: 14560-14565

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Organic-Inorganic Hybrid Material as New Matrices of Proton Conducting Membranes

    • Author(s)
      H. Yamada, S. Aono, I. Moriguchi
    • Journal Title

      Chemistry Letters (in press)

    • Related Report
      2009 Final Research Report
  • [Presentation] Ionic Conduction at Interfaces of Solid Electrolytes and Electrodes2010

    • Author(s)
      Yusuke Oga
    • Organizer
      Nagasaki Symposium on Nano Dynamics 2010
    • Place of Presentation
      長崎大学
    • Year and Date
      2010-01-21
    • Related Report
      2009 Annual Research Report
  • [Presentation] Ionic Conduction at Interfaces of Solid Electrolytes and Electrodes2010

    • Author(s)
      Yusuke Oga, Isamu Saruwatari, Hirotoshi Yamada, Isamu Moriguchi
    • Organizer
      Nagasaki Symposium on Nano-Dymamics 2010
    • Place of Presentation
      Nagasaki
    • Related Report
      2009 Final Research Report
  • [Presentation] 固体電解質・電極活物質界面におけるイオン導電挙動2009

    • Author(s)
      山田博俊
    • Organizer
      第35回固体イオニクス討論会
    • Place of Presentation
      大阪国際会議場
    • Year and Date
      2009-12-07
    • Related Report
      2009 Annual Research Report
  • [Presentation] AgI:Al2O3複合体の構造とイオン伝導性2009

    • Author(s)
      大賀雄介, 山田博俊, 森口勇
    • Organizer
      第46回化学関連支部合同九州大会
    • Place of Presentation
      北九州
    • Related Report
      2009 Final Research Report
  • [Presentation] 固体電解質・電極活物質界面におけるイオン導電挙動2009

    • Author(s)
      山田博俊, 大賀雄介, 猿渡勇, 森口 勇
    • Organizer
      第35回固体イオニクス討論会
    • Place of Presentation
      大阪
    • Related Report
      2009 Final Research Report
  • [Presentation] リチウムイオン伝導性固体電解質/電極活物質界面における構造とイオン伝導2008

    • Author(s)
      猿渡勇
    • Organizer
      2008年日本化学会西日本大会
    • Place of Presentation
      長崎大学
    • Year and Date
      2008-11-16
    • Related Report
      2008 Annual Research Report
  • [Presentation] Local structure of high Ag ion conductors loaded in nanopores2008

    • Author(s)
      H. Yamada
    • Organizer
      PRiME 2008
    • Place of Presentation
      ホノルル(アメリカ)
    • Year and Date
      2008-10-15
    • Related Report
      2008 Annual Research Report
  • [Presentation] Local structure of high Ag ion conductors loaded in nanopores2008

    • Author(s)
      Hirotoshi Yamada, Isamu Moriguchi, Tetsuichi Kudo, Naoaki Kuwata, Jun-ichi Kawamura
    • Organizer
      PRiME 2008
    • Place of Presentation
      Honolulu
    • Related Report
      2009 Final Research Report
  • [Presentation] リチウムイオン伝導性固体電解質/電極活物質界面における構造とイオン伝導2008

    • Author(s)
      猿渡勇, 山田博俊, 森口勇
    • Organizer
      2008年日本化学会西日本大会
    • Place of Presentation
      長崎
    • Related Report
      2009 Final Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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