| Project/Area Number |
20750173
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Polymer/Textile materials
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| Research Institution | Tokyo University of Agriculture and Technology |
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Principal Investigator |
MAEYAMA Katsuya Tokyo University of Agriculture and Technology, 大学院・理工学研究科, 准教授 (20311657)
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| Project Period (FY) |
2008 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2009: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2008: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
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| Keywords | 高分子材料合成 / 発光材料 / ジナフトフラン / ビナフチル化合物 / 鈴木カップリング反応 / 溶解性付与 / 1, 1'-ビナフチル化合物 / 位置選択的ジブロモ化 / 位置選択的ジアシル化 / Sonogashiraカップリング重合 / 鈴木カップリング重合 |
|---|
| Research Abstract |
3,3'-Dibromodinaphthofuran and 6,6'-dibromodinaphthofuran were prepared from binaphthol through acid-catalyzed cyclization and regioselective dibromination. Although nickel halide/zinc-mediated aromatic homocoupling polymerization of the dibromodinapfthofurans was attempted, no poly(dinaphthofuran) was obtained. Pd(PPh3)4/CuI-catalyzed Sonogashira coupling polymerization of the dibromodinaphthofurans with aromatic diynes also yielded no desired polymers.
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