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Hierarchical structures in block copolymer thin film analyzed by glazing incidence SAXS/WAXS simultaneously measurement

Research Project

Project/Area Number 20750176
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Polymer/Textile materials
Research InstitutionNagoya Institute of Technology

Principal Investigator

YAMAMOTO Katsuhiro  Nagoya Institute of Technology, 大学院・工学研究科, 准教授 (30314082)

Project Period (FY) 2008 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2009: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2008: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywordsポリマーアロイ / 高分子構造 / 微小角入射小角X線散乱 / ブロック共重合体 / 階層構造 / 薄膜 / 配向構造 / 相分離構造 / 微小角入射X線散乱 / 構造解析 / 配向挙動
Research Abstract

Simultaneous small and wide angle X-ray scattering method is very useful technique to analyze a hierarchy structure in polymeric materials and formation mechanism in wide length scale. Recently, it is important to know physical properties and structures in a local and narrow region of polymeric material when various devices are required to be much smaller. Grazing incidence X-ray SAXS/WAXS technique as much useful method has been developed and the hierarchy structure in a thin polymeric film has been analyzed by GISAXS/WAXS.

Report

(3 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • Research Products

    (26 results)

All 2010 2009 2008 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (23 results) Remarks (1 results)

  • [Journal Article] Phase-Separated Conetwork Structure Induced by Radical Copolymerization of Poly(dimethylsiloxane)-α,ω-diacrylate and N, N-Dimethylacrylamide2009

    • Author(s)
      Katsuhiro Yamamoto, Eri Ito, Shuhei Fukaya, Hideaki Takagi
    • Journal Title

      Macromolecules vol.42,No.24

      Pages: 9561-9567

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Phase-Separated Conetwork Structure Induced by Radical Copolymerization of Poly(dimethylsiloxane)-α,ω-diacrylate and N,N-Dimethylacrylamide2009

    • Author(s)
      Katsuhiro Yamamoto, 他3人
    • Journal Title

      Macromolecules 42

      Pages: 9561-9567

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 両親媒性ジブロック共重合体/親水性オリゴマーブレンド薄膜のミクロ相分離構造配向挙動の溶媒アニール効果2010

    • Author(s)
      松谷泰斗、山本勝宏
    • Organizer
      第27回PFシンポジウム
    • Place of Presentation
      つくば市
    • Year and Date
      2010-03-09
    • Related Report
      2009 Annual Research Report
  • [Presentation] 両親媒性ジブロック共重合体/親水性オリゴマーブレンド薄膜のミクロ相分離構造配向挙動の溶媒アニール効果2010

    • Author(s)
      松谷泰斗, 山本勝宏
    • Organizer
      第27回PFシンポジウム
    • Place of Presentation
      つくば国際会議場
    • Related Report
      2009 Final Research Report
  • [Presentation] Orientation of microphase separated structure of block copolymer thin film coated from solution blended with nonvolatile selective solvent.2009

    • Author(s)
      梅垣直哉、山本勝宏, 他2名
    • Organizer
      第一回FAPS Polymer Congress
    • Place of Presentation
      名古屋
    • Year and Date
      2009-10-23
    • Related Report
      2009 Annual Research Report
  • [Presentation] Development of nano phase-separated structure induced by radical copolymerization2009

    • Author(s)
      深谷周平、山本勝宏, 他2名
    • Organizer
      第一回FAPS Polymer Congress
    • Place of Presentation
      名古屋
    • Year and Date
      2009-10-23
    • Related Report
      2009 Annual Research Report
  • [Presentation] Orientational behavior of microphase-separated structure of amphiphilic diblock copolymer/water-soluble oligomer blend2009

    • Author(s)
      松谷泰斗、山本勝宏, 他3名
    • Organizer
      第一回FAPS Polymer Congress
    • Place of Presentation
      名古屋
    • Year and Date
      2009-10-23
    • Related Report
      2009 Annual Research Report
  • [Presentation] 不揮発性選択溶媒ブレンドによるブロック共重合体薄膜のミクロ相分離構造の配向化2009

    • Author(s)
      梅垣直哉、山本勝宏, 他2名
    • Organizer
      第58回高分子討論会
    • Place of Presentation
      熊本
    • Year and Date
      2009-09-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] Microphase Separated Structures of Block Copolymer in Thin Film with Nonvolatile Selective Solvent2009

    • Author(s)
      山本勝宏、梅垣直哉, 他2名
    • Organizer
      Synchrotron Radiation in Polymer Science IV
    • Place of Presentation
      オランダ
    • Year and Date
      2009-09-10
    • Related Report
      2009 Annual Research Report
  • [Presentation] ラジカル共重合反応により誘起される相分離構造形成2009

    • Author(s)
      山本勝宏, 他2名
    • Organizer
      平成21年度繊維学会年次大会
    • Place of Presentation
      東京
    • Year and Date
      2009-06-11
    • Related Report
      2009 Annual Research Report
  • [Presentation] 不揮発性選択溶媒添加による相転移に誘起されるブロック共重合体薄膜中のミクロ相分離構造の配向化2009

    • Author(s)
      山本勝宏、梅垣直哉, 他2名
    • Organizer
      第58回高分子学会年次大会
    • Place of Presentation
      神戸
    • Year and Date
      2009-05-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] 両親媒性ジブロック共重合体/水溶性オリゴマーブレンドの相分離構造配向挙動2009

    • Author(s)
      松谷泰斗、山本勝宏, 他2名
    • Organizer
      第58回高分子学会年次大会
    • Place of Presentation
      神戸
    • Year and Date
      2009-05-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] Orientation of microphase separated structure of block copolymer thin film coated from solution blended with nonvolatile selective solvent2009

    • Author(s)
      Naoya Umegaki, Katasuhiro Yamamoto, Shigeru Okamoto, Shinichi Sakurai
    • Organizer
      The 1st FAPS Polymer Congress
    • Place of Presentation
      Nagoya
    • Related Report
      2009 Final Research Report
  • [Presentation] Orientational behavior of microphase-separated structure of amphiphilic diblock copolymer / water-soluble oligomer blend2009

    • Author(s)
      Taito Matsutani, Naoya Umegaki, Katsuhiro Yamamoto, Shinichi Sakurai, Isamu Akiba
    • Organizer
      The 1st FAPS Polymer Congress
    • Place of Presentation
      Nagoya
    • Related Report
      2009 Final Research Report
  • [Presentation] 不揮発性選択溶媒ブレンドによるブロック共重合体薄膜のミクロ相分離構造の配向化2009

    • Author(s)
      梅垣直哉, 山本勝宏, 岡本茂, 櫻井伸一
    • Organizer
      第58回高分子討論会
    • Place of Presentation
      熊本大学
    • Related Report
      2009 Final Research Report
  • [Presentation] Microphase Separated Structures of Block Copolymer in Thin Film with Nonvolatile Selective Solvent2009

    • Author(s)
      Katsuhiro Yamamoto, Naoya Umegaki, Shinichi Sakurai
    • Organizer
      Synchrotron Radiation in Polymer Science IV (SRPS4)
    • Place of Presentation
      Rolduc Abby, Maastricht, Netherland
    • Related Report
      2009 Final Research Report
  • [Presentation] Phase Separated Co-network Structure Induced by Radical Copolymerization of Poly(dimethylsiloxane)-α,ω-diacrylate and N, N-Dimethylacrylamide2009

    • Author(s)
      Katsuhiro Yamamoto, Eri Ito, Shuhei Fukaya, Hideaki Takagi
    • Organizer
      XIV International Conference on Small-Angle Scattering
    • Place of Presentation
      Oxford, UK
    • Related Report
      2009 Final Research Report
  • [Presentation] 両親媒性ジブロック共重合体/水溶性オリゴマーブレンドの相分離構造配向挙動2009

    • Author(s)
      松谷泰斗・梅垣直哉・山本勝宏, 櫻井伸一, 秋葉勇
    • Organizer
      第58回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場
    • Related Report
      2009 Final Research Report
  • [Presentation] 不揮発性選択溶媒添加による相転移に誘起されるブロック共重合体薄膜中のミクロ相分離構造の配向化2009

    • Author(s)
      梅垣直哉, 山本勝宏, 岡本茂, 櫻井伸一
    • Organizer
      第58回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場
    • Related Report
      2009 Final Research Report
  • [Presentation] GISAXSによるジブロック共重合体薄膜のミクロ相分離構造解析2008

    • Author(s)
      梅垣直哉, 高木秀彰, 山本勝宏
    • Organizer
      第57回高分子討論会
    • Place of Presentation
      阪市立大学
    • Related Report
      2009 Final Research Report
  • [Presentation] フルオロアルキル側鎖を有するポリエチレンマレイミド薄膜の表面特性と凝集構造2008

    • Author(s)
      山本勝宏
    • Organizer
      第17回繊維連合研究会
    • Place of Presentation
      奈良女子大
    • Related Report
      2009 Final Research Report
  • [Presentation] エチレンマレイミド共重合体薄膜の凝集構造と表面特性-フルオロアルキル鎖含有量の効果2008

    • Author(s)
      山本勝宏, 近藤健司, 岡本茂
    • Organizer
      第57回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Related Report
      2009 Final Research Report
  • [Presentation] エチレンマレイミド共重合体薄膜の凝集構造と表面特性-フルオロアルキル鎖含有量の効果2008

    • Author(s)
      山本勝宏, 近藤健司, 岡本茂
    • Organizer
      高分子学会
    • Place of Presentation
      パシフィコ横浜
    • Related Report
      2008 Annual Research Report
  • [Presentation] フルオロアルキル側鎖を有するポリエチレンマレイミド薄膜の表面特性と凝集構造2008

    • Author(s)
      山本勝宏
    • Organizer
      繊維連合研究会
    • Place of Presentation
      奈良女子大学
    • Related Report
      2008 Annual Research Report
  • [Presentation] GISAXSによるジブロック共重合体薄膜のミクロ相分離構造解析2008

    • Author(s)
      梅垣直哉, 高木秀彰, 山本勝宏
    • Organizer
      高分子学会
    • Place of Presentation
      大阪市立大学
    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://yamamotolab.web.nitech.ac.jp/

    • Related Report
      2009 Final Research Report

URL: 

Published: 2008-04-01   Modified: 2016-04-21  

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