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Formation mechanism of grown-in defects in Czochralski germanium crystal growth

Research Project

Project/Area Number 20760003
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Applied materials science/Crystal engineering
Research InstitutionTohoku University

Principal Investigator

TAISHI Toshinori  Tohoku University, 金属材料研究所, 助教 (90397307)

Co-Investigator(Renkei-kenkyūsha) YONENAGA Ichiro  東北大学, 金属材料研究所, 教授 (20134041)
OHNO Yutaka  東北大学, 金属材料研究所, 准教授 (80243129)
TOKUMOTO Yuki  東北大学, 金属材料研究所, 助教 (20546866)
MURAO Yu  東北大学, 大学院・理学部, 修士課程2年
ISE Hideaki  東北大学, 理学部, 4年
OHSAWA Takayuki  東北大学, 理学部, 4年
Project Period (FY) 2008 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2008: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords結晶成長 / 結晶評価 / ゲルマニウム / 成長時導入欠陥 / 転位 / 不純物添加 / 析出物 / 欠陥形成機構 / 引き上げ法
Research Abstract

Germanium (Ge) has been expected as materials for high-speed ULSI devices and for the substrate or the bottom cell of III-V-based solar cells. In this study, grown-in defects, such as dislocation, precipitates and void, in Ge crystals grown by the Czochralski (CZ) method were experimentally evaluated and formation mechanisms of such defects were investigated.
As typical results, we succeeded in growing dislocation-free Ge crystals, and the new growth technique was proposed. An equilibrium segregation coefficient of B in Ge was found to be 6.2. When As concentration in a Ge crystal exceeded 1×10^<19>cm^<-3>, plate-like GeAs precipitates were formed along {111} plane.

Report

(3 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • Research Products

    (19 results)

All 2010 2009 2008 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (10 results) Remarks (2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Equilibrium segregation coefficient and solid solubility of B in Czochralski Ge crystal growth2010

    • Author(s)
      T. Taishi, Y. Ohno, I. Yonenaga
    • Journal Title

      Thin Solid Films 518

      Pages: 2409-2412

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Equilibrium segregation coefficient and solid solubility of B in Czochralski Ge crystal growth2010

    • Author(s)
      T.Taishi, Y.Ohno, I.Yonenaga
    • Journal Title

      Thin Solid Films 518

      Pages: 2409-2412

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reduction of grown-in dislocation density in Ge Czochralski-grown from the B2O3-partially- covered melt2009

    • Author(s)
      T. Taishi, Y. Ohno, I. Yonenaga
    • Journal Title

      Journal of Crystal Growth 311

      Pages: 4615-4618

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Reduction of grown-in dislocation density in Ge Czochralski-grown from the B_2O_3-partially-covered melt2009

    • Author(s)
      T.Taishi, Y.Ohno, I.Yonenaga
    • Journal Title

      Journal of Crystal Growth 311

      Pages: 4615-4618

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Segregation of boron in germanium2008

    • Author(s)
      T. Taishi, Y. Murao, Y. Ohno, I. Yonenaga
    • Journal Title

      Journal of Crystal Growth 311

      Pages: 59-61

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Segregation of boron in germanium2008

    • Author(s)
      T. Taishi, Y. Murao, Y Ohno, Y. Yonenaza
    • Journal Title

      Journal of Crystal Growth 311

      Pages: 59-61

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] CZ-Ge結晶成長における酸素の混入と偏析現象2010

    • Author(s)
      太子敏則, 伊勢秀彰, 大澤隆亨, 徳本有紀, 米永一郎
    • Organizer
      第57回応用物理学関係連合講演会
    • Place of Presentation
      平塚
    • Year and Date
      2010-03-17
    • Related Report
      2009 Final Research Report
  • [Presentation] B2O3被覆融液からの無転位Ge単結晶成長と評価2009

    • Author(s)
      太子敏則, 伊勢秀彰, 大野裕, 徳本有紀米永一郎
    • Organizer
      第39回結晶成長国内会議
    • Place of Presentation
      名古屋
    • Year and Date
      2009-11-12
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] B2O3被覆Ge融液からの低転位密度CZ-Ge結晶成長2009

    • Author(s)
      太子敏則, 伊勢秀彰, 大野裕, 米永一郎
    • Organizer
      第70回応用物理学会学術講演会
    • Place of Presentation
      富山
    • Year and Date
      2009-09-08
    • Related Report
      2009 Final Research Report
  • [Presentation] B_2O_3被覆Ge融液からの低転位密度CZ-Ge結晶成長2009

    • Author(s)
      太子敏則、伊勢秀彰、大野裕、米永一郎
    • Organizer
      第70回応用物理学会学術講演会
    • Place of Presentation
      富山
    • Year and Date
      2009-09-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] Relationship between morphological features of the growth interface and growth conditions in heavily-impurity doped Si and Ge crystal growth2009

    • Author(s)
      T. Taishi, Y. Ohno, I. Yonenaga
    • Organizer
      The 17th American Conference on Crystal Growth and Epitaxy
    • Place of Presentation
      Lake Geneva, USA
    • Year and Date
      2009-08-13
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] Characteristics of Czochralski-grown B- doped Ge crystal2009

    • Author(s)
      T. Taishi, Y. Murao, Y. Ohno, I. Yonenaga
    • Organizer
      European Materials Research Society 2009 Spring Meeting
    • Place of Presentation
      Strasbourg, France
    • Year and Date
      2009-06-08
    • Related Report
      2009 Final Research Report
  • [Presentation] Characteristics of Czochralski-grown B-doped Ge crystal2009

    • Author(s)
      T.Taishi, Y.Murao, Y.Ohno, I.Yonenaga
    • Organizer
      European Materials Research Society 2009 Spring Meeting
    • Place of Presentation
      Strasbourg, France
    • Year and Date
      2009-06-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] 高濃度As添加CZ-Ge結晶成長におけるGeAs析出挙動の解明2009

    • Author(s)
      太子敏則, 村尾優, 大野裕, 米永一郎
    • Organizer
      第56回応用物理学関係連合講演会
    • Place of Presentation
      つくば
    • Year and Date
      2009-04-01
    • Related Report
      2009 Final Research Report
  • [Presentation] 引き上げ法Ge結晶成長におけるBの偏析と固溶限2008

    • Author(s)
      太子敏則, 村尾優, 大野裕, 米永一郎
    • Organizer
      第37回結晶成長国内会議
    • Place of Presentation
      仙台
    • Year and Date
      2008-11-05
    • Related Report
      2009 Final Research Report
  • [Presentation] 引き上げ法Ge結晶成長におけるBの偏析と固溶限2008

    • Author(s)
      太子敏則, 村尾優, 大野裕, 米永一郎
    • Organizer
      第37回結晶成長国内会議
    • Place of Presentation
      仙台市戦災復興記念館
    • Year and Date
      2008-11-05
    • Related Report
      2008 Annual Research Report
  • [Remarks] 東北大学のホームぺージにて掲載

    • URL

      http://www.tohoku.ac.jp/japanese/2009/09/press20090908.html

    • Related Report
      2009 Final Research Report
  • [Remarks]

    • URL

      http://www.tohoku.ac.jp/japanese/2009/09/press20090908.html

    • Related Report
      2009 Annual Research Report
  • [Patent(Industrial Property Rights)] 低転位密度ゲルマニウム単結晶の製造方法2009

    • Inventor(s)
      米永一郎, 太子敏則
    • Industrial Property Rights Holder
      東北大学
    • Industrial Property Number
      2009-109980
    • Filing Date
      2009-04-28
    • Related Report
      2009 Annual Research Report 2009 Final Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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