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Elucidation of the mechanism of the surface nano relief formation of azo-polymers using metallic tip enhanced near-field light

Research Project

Project/Area Number 20760040
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Applied optics/Quantum optical engineering
Research InstitutionThe Institute of Physical and Chemical Research

Principal Investigator

ISHITOBI Hidekazu  The Institute of Physical and Chemical Research, 河田ナノフォトニクス研究室, 協力研究員 (20372633)

Project Period (FY) 2008 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2009: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2008: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywords近接場光 / アゾポリマー / 光異性化 / 光誘起表面レリーフ / 金属チップ電場増強 / 光勾配力
Research Abstract

I found that the surface relief pattern induced by a single light spot having only a longitudinal electric field (Ez) was strongly dependent on the film thickness. Such a film thickness dependence was not observed in the case of a lateral electric field (Ex, y). I have also succeeded in inducing polymer nanomovement of an azo polymer film by combining metal tip enhancement and radial polarization. I found that the induced surface relief was dependent on the tip force which exerted on the polymer surface. It is considered that adsorption force between the tip end and the polymer surface plays an important role.

Report

(3 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • Research Products

    (61 results)

All 2010 2009 2008 Other

All Journal Article (13 results) (of which Peer Reviewed: 13 results) Presentation (44 results) Book (2 results) Remarks (2 results)

  • [Journal Article] Orientational Imaging of Single Molecules by Using Azimuthal and Radial Polarizations2010

    • Author(s)
      H. Ishitobi, I. Nakamura, N. Hayazawa, Z. Sekkat, S. Kawata
    • Journal Title

      Journal of Physical Chemistry B 114

      Pages: 2565-2571

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Surface Nanofabrication in Photosensitive Polymers at the diffraction limit of light and down to 47 nm by Metal Tip-Enhanced Near Field light: Light Induced Nanomovement of Polymers2009

    • Author(s)
      Z. Sekkat, H. Ishitobi, M. Tanabe, S. Shoji, S. Kawata
    • Journal Title

      Moroccan Journal of Condensed Matter 11

      Pages: 111-117

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Deep-UV tip-enhanced Raman scattering2009

    • Author(s)
      Taguchi, N. Hayazawa, K. Furusawa, H. Ishitobi, S. Kawata
    • Journal Title

      Journal of Raman Spectroscopy 40

      Pages: 1324-1330

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Controlling the plasmon resonance wavelength in metal-coated probe using refractive index modification2009

    • Author(s)
      A. Taguchi, N. Hayazawa, Y. Saito, H. Ishitobi, A. Tarun, S. Kawata
    • Journal Title

      Optics Express 17

      Pages: 6509-6518

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] On Fluorescence Blinking of Single Molecules in Polymers2009

    • Author(s)
      H. Ishitobi, T. Kai, K. Fujita, Z. Sekkat, S. Kawata
    • Journal Title

      Chemical Physics Letters 468

      Pages: 234-238

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Controlling the plasmon resonance wavelength in metal-coated probe using refractive index modification2009

    • Author(s)
      A.Taguchi
    • Journal Title

      Optics Express 17

      Pages: 6509-6518

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Deek-UV tip-enhanced Raman scattering2009

    • Author(s)
      A.Taguchi
    • Journal Title

      Journal of Raman Spectroscopy 40

      Pages: 1324-1330

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface Nanofabrication in Photosensitive Polymers at the diffraction limit of light and down to 47nm by Metal Tip-Enhanced Near Field light : Light Induced Nanomovement of Polymers2009

    • Author(s)
      Z.Sekkat
    • Journal Title

      Moroccan Journal of Condensed Matter 11

      Pages: 111-117

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] On Fluorescence Blinking of Single Molecules in Polymers2009

    • Author(s)
      H. Ishitobi
    • Journal Title

      Chemical Physics Letters 468

      Pages: 234-238

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Two-photon induced polymer nanomovement2008

    • Author(s)
      H. Ishitobi, S. Shoji, T. Hiramatsu, H. -B. Sun, Z. Sekkat, S. Kawata
    • Journal Title

      Optics Express 16

      Pages: 14106-14114

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Active control of the oxidization of a silicon cantilever for the characterization of silicon-based senmiconductors2008

    • Author(s)
      A. Ono
    • Journal Title

      Chemistry Letters 37

      Pages: 122-123

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Two-photon induced polymer nanomovement2008

    • Author(s)
      H. Ishitobi
    • Journal Title

      Optics Express 16

      Pages: 14106-14114

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Orientational Imaging of Single Molecules by Using Azimuthal and Radial Polarizations

    • Author(s)
      H.Ishitobi
    • Journal Title

      Journal of Physical Chemistry B (in press)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 近接場光誘起表面レリーフとナノファブリケーションへの応用2009

    • Author(s)
      石飛秀和、河田聡
    • Organizer
      理化学研究所基幹研究所先端光科学研究領域「エクストリームフォトニクス研究、テラヘルツ光研究」第I期研究成果報告会-シンポジウム-
    • Place of Presentation
      仙台
    • Year and Date
      2009-12-15
    • Related Report
      2009 Final Research Report
  • [Presentation] 「金属プローブを用いた深紫外共鳴ラマン散乱の増強」、理化学研究所基幹研究所先端光科学研究領域「エクストリームフォトニクス研究2009

    • Author(s)
      田口敦清、早澤紀彦、古澤健太郎、石飛秀和、河田聡
    • Organizer
      テラヘルツ光研究」第I期研究成果報告会-シンポジウム-
    • Place of Presentation
      仙台
    • Year and Date
      2009-12-15
    • Related Report
      2009 Final Research Report
  • [Presentation] 近接場光誘起表面レリーフとナノファブリケーションへの応用2009

    • Author(s)
      石飛秀和、河田聡
    • Organizer
      理化学研究所 基幹研究所 先端光科学研究領域「エクストリームフォトニクス研究、テラヘルツ光研究」第I期 研究成果報告会-シンポジウム-
    • Place of Presentation
      仙台国際センター@仙台市
    • Year and Date
      2009-12-15
    • Related Report
      2009 Annual Research Report
  • [Presentation] 金属プローブを用いた深紫外共鳴ラマン散乱の増強2009

    • Author(s)
      田口敦清、早澤紀彦、古澤健太郎、石飛秀和、河田聡
    • Organizer
      理化学研究所 基幹研究所 先端光科学研究領域「エクストリームフォトニクス研究、テラヘルツ光研究」第I期 研究成果報告会-シンポジウム-
    • Place of Presentation
      仙台国際センター@仙台市
    • Year and Date
      2009-12-15
    • Related Report
      2009 Annual Research Report
  • [Presentation] Two-photon induced polymer nanomovement2009

    • Author(s)
      H.Ishitobi, T.Hiramatsu, Z.Sekkat, S.Kawata
    • Organizer
      The Annual Meeting of the Spectroscopical Society of Japan
    • Place of Presentation
      東工大@東京都
    • Year and Date
      2009-11-18
    • Related Report
      2009 Annual Research Report
  • [Presentation] Method of optimizing plasmon resonance wavelength in metal coated TERS probe using refractive index modification2009

    • Author(s)
      田口敦清、早澤紀彦、齊藤結花、石飛秀和、河田聡
    • Organizer
      The Annual Meeting of the Spectroscopical Society of Japan
    • Place of Presentation
      東工大@東京都
    • Year and Date
      2009-11-17
    • Related Report
      2009 Annual Research Report
  • [Presentation] 光異性化分子の光誘起物質移動2009

    • Author(s)
      石飛秀和、中村一誠、早澤紀彦、河田聡
    • Organizer
      第8回ナノフォトニクス&メタマテリアルシンポジウム
    • Place of Presentation
      和光
    • Year and Date
      2009-11-06
    • Related Report
      2009 Final Research Report
  • [Presentation] 近接場光学顕微鏡のためのプラズモニックナノプローブの設計研究2009

    • Author(s)
      田口敦清、早澤紀彦、齊藤結花、石飛秀和、河田聡
    • Organizer
      第8回ナノフォトニクス&メタマテリアルシンポジウム
    • Place of Presentation
      和光
    • Year and Date
      2009-11-06
    • Related Report
      2009 Final Research Report
  • [Presentation] 光異性化分子の光誘起物質移動2009

    • Author(s)
      石飛秀和、中村一誠、早澤紀彦、河田聡
    • Organizer
      第8回ナノフォトニクス&メタマテリアルシンポジウム
    • Place of Presentation
      理研@和光市
    • Year and Date
      2009-11-06
    • Related Report
      2009 Annual Research Report
  • [Presentation] 近接場光学顕微鏡のためのプラズモニックナノプローブの設計研究2009

    • Author(s)
      田口敦清、早澤紀彦、齊藤結花、石飛秀和、河田聡
    • Organizer
      第8回ナノフォトニクス&メタマテリアルシンポジウム
    • Place of Presentation
      理研@和光市
    • Year and Date
      2009-11-06
    • Related Report
      2009 Annual Research Report
  • [Presentation] 偏光操作による単一蛍光分子の3次元分子配向角測定2009

    • Author(s)
      石飛秀和、中村一誠、早澤紀彦、河田聡
    • Organizer
      第10回エクストリーム・フォトニクス研究会
    • Place of Presentation
      ホテル竹島@蒲郡市
    • Year and Date
      2009-11-04
    • Related Report
      2009 Annual Research Report
  • [Presentation] 単一集光スポット照射によるアゾ系フォトクロミックポリマーの光誘起物質移動2009

    • Author(s)
      石飛秀和
    • Organizer
      特定領域研究「フォトクロミズムの攻究とメカニカル機能の創出」第4回公開シンポジウム
    • Place of Presentation
      仙台国際センター@仙台市
    • Year and Date
      2009-09-02
    • Related Report
      2009 Annual Research Report
  • [Presentation] 単一蛍光分子の3次元配向イメージング2009

    • Author(s)
      石飛秀和、中村一誠、早澤紀彦、河田聡
    • Organizer
      エクストリームフォトニクスシンポジウム、-光で繋ぐ理研の基礎科学-
    • Place of Presentation
      理研@和光市
    • Year and Date
      2009-05-20
    • Related Report
      2009 Annual Research Report
  • [Presentation] 金属プローブによる深紫外共鳴ラマン散乱の増強2009

    • Author(s)
      田口敦清、早澤紀彦、古澤健太郎、石飛秀和、河田聡
    • Organizer
      エクストリームフォトニクスシンポジウム、-光で繋ぐ理研の基礎科学-
    • Place of Presentation
      理研@和光市
    • Year and Date
      2009-05-20
    • Related Report
      2009 Annual Research Report
  • [Presentation] Two-photon induced polymer nanomovement2009

    • Author(s)
      H. Ishitobi, T. Hiramatsu, Z. Sekkat, S. Kawata
    • Organizer
      The Annual Meeting of the Spectroscopical Society of Japan
    • Place of Presentation
      Tokyo, Japan
    • Related Report
      2009 Final Research Report
  • [Presentation] Method of optimizing plasmon resonance wavelength in metal coated TERS probe using refractive index modification2009

    • Author(s)
      A. Taguchi, N. Hayazawa, Y. Saito, H. Ishitobi, S. Kawata
    • Organizer
      The Annual Meeting of the Spectroscopical Society of Japan
    • Place of Presentation
      Tokyo, Japan
    • Related Report
      2009 Final Research Report
  • [Presentation] 偏光操作による単一蛍光分子の3次元分子配向角測定2009

    • Author(s)
      石飛秀和、中村一誠、早澤紀彦、河田聡
    • Organizer
      第10回エクストリーム・フォトニクス研究会
    • Place of Presentation
      蒲郡
    • Related Report
      2009 Final Research Report
  • [Presentation] 単一集光スポット照射によるアゾ系フォトクロミックポリマーの光誘起物質移動2009

    • Author(s)
      石飛秀和
    • Organizer
      特定領域研究「フォトクロミズムの攻究とメカニカル機能の創出」第4回公開シンポジウム
    • Place of Presentation
      札幌
    • Related Report
      2009 Final Research Report
  • [Presentation] 単一蛍光分子の3次元配向イメージング2009

    • Author(s)
      石飛秀和、中村一誠、早澤紀彦、河田聡
    • Organizer
      エクストリームフォトニクスシンポジウム、-光で繋ぐ理研の基礎科学-
    • Place of Presentation
      和光
    • Related Report
      2009 Final Research Report
  • [Presentation] 金属プローブによる深紫外共鳴ラマン散乱の増強2009

    • Author(s)
      田口敦清、早澤紀彦、古澤健太郎、石飛秀和、河田聡
    • Organizer
      エクストリームフォトニクスシンポジウム、-光で繋ぐ理研の基礎科学-
    • Place of Presentation
      和光
    • Related Report
      2009 Final Research Report
  • [Presentation] Orientational Imaging of Single Fluorescence Molecules by Using Radial and Azimuthal Polarizations2008

    • Author(s)
      H. Ishitobi, I. Nakamura, N. Hayazawa, and S. Kawata
    • Organizer
      The Annual Meeting of the Spectroscopical Society of Japan
    • Place of Presentation
      東北大学@仙台
    • Year and Date
      2008-11-21
    • Related Report
      2008 Annual Research Report
  • [Presentation] Optimization of plasmon resonance wavelength in metal coated TERS probe by refractive index modification2008

    • Author(s)
      A. Taguchi, N. Hayazawa, Y. Saito, H. Ishitobi, and S. Kawata
    • Organizer
      The Annual Meeting of the Spectroscopical Society of Japan
    • Place of Presentation
      東北大学@仙台
    • Year and Date
      2008-11-21
    • Related Report
      2008 Annual Research Report
  • [Presentation] Gap-Mode Tip-Enhanced Spectroscopy2008

    • Author(s)
      H. Ishitobi, N. Hayazawa. A. Taguchi, and S. Kawata
    • Organizer
      The Annual Meeting of the Spectroscopical Society of Japan
    • Place of Presentation
      東北大学@仙台
    • Year and Date
      2008-11-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] Highly efficient gap-mode TERS based on focused SPP excitations2008

    • Author(s)
      早澤紀彦, 石飛秀和, 田口敦清, 河田聡
    • Organizer
      第8回エクストリーム・フォトニクス研究会
    • Place of Presentation
      ホテル竹島@蒲郡
    • Year and Date
      2008-11-11
    • Related Report
      2008 Annual Research Report
  • [Presentation] Two-photon Induced Polymer Nanomovement2008

    • Author(s)
      H. Ishitobi, Z. Sekkat, S. Kawata
    • Organizer
      RIKEN symposium, 7th Nanophotonics & Metamaterials Symposium
    • Place of Presentation
      Wako, Japan
    • Year and Date
      2008-11-07
    • Related Report
      2009 Final Research Report
  • [Presentation] Orientational Imaging of Single Fluorescence Molecules by Using Radial and Azimuthal Polarizations2008

    • Author(s)
      H. Ishitobi, I. Nakamura, N. Hayazawa, S. Kawata
    • Organizer
      RIKEN symposium, 7th Nanophotonics & Metamaterials Symposium
    • Place of Presentation
      Wako, Japan
    • Year and Date
      2008-11-07
    • Related Report
      2009 Final Research Report
  • [Presentation] Highly Efficient Gap-mode TERS Based on Focused SPP Excitations2008

    • Author(s)
      N. Hayazawa, H. Ishitobi, S. Kawata
    • Organizer
      RIKEN symposium, 7th Nanophotonics & Metamaterials Symposium
    • Place of Presentation
      Wako, Japan
    • Year and Date
      2008-11-07
    • Related Report
      2009 Final Research Report
  • [Presentation] Optimization of Plasmon Resonance Wavelength in TERS Probe by Refractive Index Modification2008

    • Author(s)
      A. Taguchi, N. Hayazawa, Y. Saito, H. Ishitobi, S. Kawata
    • Organizer
      RIKEN symposium, 7th Nanophotonics & Metamaterials Symposium
    • Place of Presentation
      Wako, Japan
    • Year and Date
      2008-11-07
    • Related Report
      2009 Final Research Report
  • [Presentation] Two-photon Induced Polymer Nanomovement2008

    • Author(s)
      H. Ishitobi, Z. Sekkat, and S. Kawata
    • Organizer
      RIKEN symposium, 7th Nanophotonics & Metamaterials Symposium
    • Place of Presentation
      理研@和光
    • Year and Date
      2008-11-07
    • Related Report
      2008 Annual Research Report
  • [Presentation] Orientational Imaging of Single Fluorescence Molecules by Using Radial and Azimuthal Polarizations2008

    • Author(s)
      H. Ishitobi, I. Nakamura, N. Hayazawa, and S. Kawata
    • Organizer
      RIKEN symposium, 7th Nanophotonics & Metamaterials Symposium
    • Place of Presentation
      理研@和光
    • Year and Date
      2008-11-07
    • Related Report
      2008 Annual Research Report
  • [Presentation] Highly Efficient Gap-mode TERS Based on Focused SPP Excitations2008

    • Author(s)
      N. Hayazawa, H. Ishitobi, and S. Kawata
    • Organizer
      RIKEN symposium, 7th Nanophotonics & Metamaterials Symposium
    • Place of Presentation
      理研@和光
    • Year and Date
      2008-11-07
    • Related Report
      2008 Annual Research Report
  • [Presentation] Optimization of Plasmon Resonance Wavelength in TERS Probe by Refractive Index Modification2008

    • Author(s)
      A. Taguchi, N. Hayazawa, Y. Saito, H. Ishitobi, and S. Kawata
    • Organizer
      RIKEN symposium, 7th Nanophotonics & Metamaterials Symposium
    • Place of Presentation
      理研@和光
    • Year and Date
      2008-11-07
    • Related Report
      2008 Annual Research Report
  • [Presentation] Excitation of Gap-mode based on focused surface plasmon polariton for tip-enhanced spectroscopy2008

    • Author(s)
      N. Hayazawa, H. Ishitobi, A. Tarun, A. Taguchi, and S. Kawata
    • Organizer
      10th International Conference on Near-field Optics,Nanophotonics and Related Techniques (NFO10)
    • Place of Presentation
      Buenos Aires, Argentina
    • Year and Date
      2008-09-03
    • Related Report
      2008 Annual Research Report
  • [Presentation] Two-photon orientation and nanofabrication in photoresponsive polymers2008

    • Author(s)
      Z. Sekkat, H. Ishitobi. M. Tanabe, S. Shoji, and S. Kawata
    • Organizer
      International Conference on Organic Photonics and Electronics 2008 (ICOPE2008) & The 10th International Conference on Organic Nonlinear optics (ICONO'10)
    • Place of Presentation
      Santa Fe, USA
    • Year and Date
      2008-05-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] ギャップモードチップ増強ラマン顕微鏡2008

    • Author(s)
      石飛秀和, 早澤紀彦, 河田聡
    • Organizer
      第7回エクストリーム・フォトニクス研究会
    • Place of Presentation
      理研@和光
    • Year and Date
      2008-05-15
    • Related Report
      2008 Annual Research Report
  • [Presentation] シリコン酸化膜厚制御による近接場プラズモニックプローブの共鳴波長制御2008

    • Author(s)
      田口敦清, 早澤紀彦, 齊藤結花, 石飛秀和, 河田聡
    • Organizer
      第7回エクストリーム・フォトニクス研究会
    • Place of Presentation
      理研@和光
    • Year and Date
      2008-05-15
    • Related Report
      2008 Annual Research Report
  • [Presentation] Orientational Imaging of Single Fluorescence Molecules by Using Radial and Azimuthal Polarizations2008

    • Author(s)
      H. Ishitobi, I. Nakamura, N. Hayazawa, S. Kawata
    • Organizer
      The Annual Meeting of the Spectroscopical Society of Japan
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2009 Final Research Report
  • [Presentation] Gap-Mode Tip-Enhanced Spectroscopy2008

    • Author(s)
      H. Ishitobi, N. Hayazawa, A. Taguchi, S. Kawata
    • Organizer
      The Annual Meeting of the Spectroscopical Society of Japan
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2009 Final Research Report
  • [Presentation] Optimization of plasmon resonance wavelength in metal coated TERS probe by refractive index modification2008

    • Author(s)
      A. Taguchi, N. Hayazawa, Y. Saito, H. Ishitobi, S. Kawata
    • Organizer
      The Annual Meeting of the Spectroscopical Society of Japan
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2009 Final Research Report
  • [Presentation] Excitation of Gap-mode based on focused surface plasmon polariton for tip-enhanced spectroscopy2008

    • Author(s)
      N. Hayazawa, H. Ishitobi, A. Tarun, A. Taguchi, S. Kawata
    • Organizer
      10th International Conference on Near-field Optics, Nanophotonics and Related Techniques (NFO10)
    • Place of Presentation
      Buenos Aires, Argentina
    • Related Report
      2009 Final Research Report
  • [Presentation] Two-photon orientation and nanofabrication in photoresponsive polymers2008

    • Author(s)
      Z. Sekkat, H. Ishitobi, M. Tanabe, S. Shoji, S. Kawata
    • Organizer
      International Conference on Organic Photonics and Electronics 2008 (ICOPE2008) & The 10th International Conference on Organic Nonlinear Optics (ICONO'10)
    • Place of Presentation
      Santa Fe, US
    • Related Report
      2009 Final Research Report
  • [Presentation] Highly efficient gap-mode TERS based on focused SPP excitations2008

    • Author(s)
      早澤紀彦、石飛秀和、河田聡
    • Organizer
      第8回エクストリーム・フォトニクス研究会
    • Place of Presentation
      蒲郡
    • Related Report
      2009 Final Research Report
  • [Presentation] ギャップモードチップ増強ラマン顕微鏡2008

    • Author(s)
      石飛秀和、早澤紀彦、田口敦清、河田聡
    • Organizer
      第7回エクストリーム・フォトニクス研究会
    • Place of Presentation
      和光
    • Related Report
      2009 Final Research Report
  • [Presentation] シリコン酸化膜厚制御による近接場プラズモニックプローブの共鳴波長制御2008

    • Author(s)
      田口敦清、早澤紀彦、齊藤結花、石飛秀和、河田聡
    • Organizer
      第7回エクストリーム・フォトニクス研究会
    • Place of Presentation
      和光
    • Related Report
      2009 Final Research Report
  • [Book] 単一光スポット照射による光学異方性発現と光誘起物質移動2010

    • Author(s)
      石飛秀和
    • Publisher
      シーエムシー出版
    • Related Report
      2009 Final Research Report
  • [Book] 光配向テクノロジーの開発動向2009

    • Author(s)
      石飛秀和
    • Publisher
      シーエムシー出版
    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://optsun.riken.jp/ishitobi/index.html

    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://optsun.riken.jp/ishitobi/index.html

    • Related Report
      2008 Annual Research Report

URL: 

Published: 2008-04-01   Modified: 2016-04-21  

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