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Correlation between oxygen vacancy and mechanical properties in oxideunder chemical potential

Research Project

Project/Area Number 20760061
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Materials/Mechanics of materials
Research InstitutionTohoku University

Principal Investigator

SATO Kazuhisa  Tohoku University, 多元物質科学研究所, 助教 (50422077)

Project Period (FY) 2008 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2009: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2008: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords固体酸化物形燃料電池 / 機能性酸化物 / 酸素不定比性 / 機械的特性 / 電気化学的特性 / 固体酸化物燃料電池 / 酸素イオン導電体 / 混合導電体 / 化学ポテンシャル / 縦弾性係数 / 破壊強度
Research Abstract

For the commercialization of solid oxide fuel cell (SOFC), in addition to the electrical reliability, it is also important to ensure the mechanical reliability of SOFC. Thus, the establishment of a suitable mechanical testing method under various temperatures and oxygen partial pressure conditions is a prerequisite for the development of reliable SOFCs. This paper presents the experimental results of the investigation of elastic modulus and fracture strength on the SOFC components under reducing conditions. An in-situ mechanical testing method was developed in order to investigate the elastic modulus and fracture strength of solid oxide fuel cells components under high oxidizing/reducing environments. The elastic modulus was shown to change under reducing condition, and the behavior was most likely due to non-stoichiometry. It was demonstrated that the in-situ mechanical testing method enabled us to estimate the internal stress in the SOFC cell and stack.

Report

(3 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • Research Products

    (25 results)

All 2009 2008 Other

All Journal Article (12 results) (of which Peer Reviewed: 12 results) Presentation (11 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Effect of Y2O3 addition on the conductivity and elastic modulus of (CeO2)1-x(YO1. 5)x2009

    • Author(s)
      Kazuhisa Sato, Ken Suzuki, Keiji Yashiro, Tatsuya Kawada, Hiroo Yugami, Toshiyuki Hashida, Alan Atkinson, Junichiro Mizusaki
    • Journal Title

      Solid State Ionics 180

      Pages: 1220-1225

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Design Concept for the High Temperature Photoelectronic Devices Using SrTiO32009

    • Author(s)
      Fumimasa Horikiri, Kazuhisa Sato, Keiji Yashiro, Tatsuya Kawada, Junichiro Mizusaki
    • Journal Title

      Journal of the Electrochemical Society 156(7)

      Pages: 107-113

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Thermodynamic quantities and defect equilibrium in La2-xSrxNiO4+δ2009

    • Author(s)
      Takashi Nakamura, Keiji Yashiro, Kazuhisa Sato, Junichiro Mizusaki
    • Journal Title

      Journal of Solid State Chemistry 182

      Pages: 1121-1128

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Defect structure analysis of B-site doped perovskite-type proton conducting oxide BaCeO3 Part1:The defect concentration of BaCe0. 9M0. 1O3-δ(M=Y and Yb)2009

    • Author(s)
      Masatsugu Oishi, Satoshi Akoshima, Keiji Yashiro, Kazuhisa Sato, Junichiro Mizusaki, Tatsuya Kawada
    • Journal Title

      Solid State Ionics 180

      Pages: 127-131

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Y2O3 addition on the conductivity and elastic modulus of(CeO_2)_<1-x>(YO_<1.5>)_x2009

    • Author(s)
      Kazuhisa Sato
    • Journal Title

      Solid State Ionics 180

      Pages: 1220-1225

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Design Concept for the High Temperature Photoelectronic Devices Using SrTiO_32009

    • Author(s)
      Fumimasa Horikiri
    • Journal Title

      Journal of the Electrochemical Society 1156(7)

      Pages: 107-113

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermodynamic quantities and defect equilibrium in La_<2-x>Sr_xNiO_<4+δ>2009

    • Author(s)
      Takashi Nakamura
    • Journal Title

      Journal of Solid State Chemistry 182

      Pages: 1121-1128

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Defect structure analysis of B-site doped perovskite-type proton conducting oxide BaCeO_3 Part1 : The defect concentration of BaCe_<0.9>M_<0.1>O_<3-δ>(M=Y and Yb)2009

    • Author(s)
      Masatsugu Oishi
    • Journal Title

      Solid State Ionics 180

      Pages: 127-131

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Oxygen nonstoichiometry of the perovskite-type oxides BaCe0. 9M0. 1O3-δ(M:Y, Yb, Sm, Tb, and Nd)2008

    • Author(s)
      Masatsugu Oishi, Keiji Yashiro, Kazuhisa Sato, Junichiro Mizusaki, Naoto Kitamura, Koji Amezawa, Tatsuya Kawada, Yoshiharu Uchimoto
    • Journal Title

      Solid State Ionics 179

      Pages: 529-535

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Defect structure analysis of B-site doped perocskite-type proton conducting oxide BaCeO32008

    • Author(s)
      Masatsugu Oishi, Satoshi Akoshima, Keiji Yashiro, Kazuhisa Sato, Junichiro Mizusaki, Tatsuya Kawada
    • Journal Title

      Solid State Ionics 179

      Pages: 2240-2247

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Defect structure analysis of B-site doped perovskite-type proton conducting oxide BaCeO_3 : Part 2 : The electrical conductivity and diffusion coefficient of BaCe_<0.9>Y_<0.1>O_<3_δ>2008

    • Author(s)
      Masatsugu Oishi
    • Journal Title

      Solid State Ionics 179

      Pages: 2240-2247

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Oxygen nonstoichiometry of the perovskite-type oxides BaCe_<0.9>M_<0.1>O_<3_δ>(M : Y, Yb, Sm, Tb, and Nd)2008

    • Author(s)
      Masatugu Oishi
    • Journal Title

      Solid State Ionics 179

      Pages: 529-535

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] SOFCの信頼性・耐久性向上に向けた機械的解析2009

    • Author(s)
      佐藤一永
    • Organizer
      第77回sofc研究会
    • Place of Presentation
      東京
    • Year and Date
      2009-11-12
    • Related Report
      2009 Final Research Report
  • [Presentation] SOFCの信頼性・耐久性向上に向けた機械的解析2009

    • Author(s)
      佐藤一永
    • Organizer
      第77回SOFC研究会
    • Place of Presentation
      笹川記念会館
    • Year and Date
      2009-11-12
    • Related Report
      2009 Annual Research Report
  • [Presentation] AE法と電気化学的手法を併用した固体酸化物燃料電池の劣化挙動評価2009

    • Author(s)
      佐藤一永, 熊田圭吾, 橋田俊之, 水崎純一郎
    • Organizer
      日本機械学会2009年度年次大会
    • Place of Presentation
      日本, 盛岡
    • Year and Date
      2009-09-16
    • Related Report
      2009 Final Research Report
  • [Presentation] AE法と電気化学的手法を併用した固体酸化物燃料電池の劣化挙動評価2009

    • Author(s)
      佐藤一永
    • Organizer
      日本機械学会2009年度年次大会
    • Place of Presentation
      岩手大学
    • Year and Date
      2009-09-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] Chemically-induced stress of fuel cell laminate under oxidizing/reducing gradient condition2009

    • Author(s)
      佐藤一永
    • Organizer
      17th International Conference on Composite Materials
    • Place of Presentation
      Edinburgh, United Kigdom
    • Year and Date
      2009-07-29
    • Related Report
      2009 Annual Research Report
  • [Presentation] Chemically-induced stress of fuel cell laminate under oxidizing/reducing gradient condition2009

    • Author(s)
      Kazuhisa Sato, Keiji Yashiro, Toshiyuki Hashida, Junichiro Mizusaki
    • Organizer
      17th International Conference on Composite Materials
    • Place of Presentation
      Edinburgh, UK
    • Year and Date
      2009-06-29
    • Related Report
      2009 Final Research Report
  • [Presentation] Thermal and chemically induced stress of solid oxide fuel cell laminate under oxidizing / reducing gradient condition2009

    • Author(s)
      Kazuhisa Sato, Keiji Yashiro, Toshiyuki Hashida, Junichiro Mizusaki
    • Organizer
      8th International Congress on THERMAL STRESSES
    • Place of Presentation
      Illinois, USA
    • Year and Date
      2009-06-03
    • Related Report
      2009 Final Research Report
  • [Presentation] Thermal and chemically induced stress of solid oxide fuel cell laminat eunder oxidizing/reducinggradient condition2009

    • Author(s)
      佐藤一永
    • Organizer
      8th International Congress on THERMAL STRESSES
    • Place of Presentation
      University of Illinois at Urbana-Champaign, Illinois, USA
    • Year and Date
      2009-06-02
    • Related Report
      2009 Annual Research Report
  • [Presentation] SOFCの信頼性評価のための機械的解析(Mechanical analysis for reliability evaluation of SOFC)2008

    • Author(s)
      佐藤一永, 八代圭司, 井口史匡, 古山通久, 雨澤浩史, 寺田賢二郎, 湯上浩雄, 橋田俊之, 水崎純一郎, 川田達也
    • Organizer
      第17回SOFC研究発表会
    • Place of Presentation
      日本, 東京
    • Year and Date
      2008-12-19
    • Related Report
      2009 Final Research Report
  • [Presentation] Evaluation Method for Mechanical Performance of Solid Oxide Fuel Cell under Simulated Operating Conditions2008

    • Author(s)
      Kazuhisa Sato, Keiji Yashiro, Tatsuya Kawada, Hiroo Yugami, Toshiyuki Hashida, Junichiro Mizusaki
    • Organizer
      ASME 6th International Fuel Cell Science, Engineering & Technology Conference
    • Place of Presentation
      USA, Denver
    • Year and Date
      2008-06-17
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] SOFCの信頼性評価のための機械的解析2008

    • Author(s)
      佐藤一永
    • Organizer
      第17回SOFC研究発表会
    • Place of Presentation
      東京
    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://www.tagen.tohoku.ac.jp/labo/mizusaki/index-j.html

    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] 複合金属酸化物およびその製造法、並びにそれを用いた電極材料、電極および固体酸化物形燃料電池2009

    • Inventor(s)
      水崎純一郎、佐藤一永、八代圭司
    • Industrial Property Rights Holder
      水崎純一郎、佐藤一永、八代圭司
    • Industrial Property Number
      2009-199934
    • Filing Date
      2009-08-31
    • Related Report
      2009 Annual Research Report 2009 Final Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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