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Local structure of crystalline and non-crystalline metal-hydrides

Research Project

Project/Area Number 20760470
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Structural/Functional materials
Research InstitutionKyoto University

Principal Investigator

ITOH Keiji  Kyoto University, 原子炉実験所, 助教 (80324713)

Project Period (FY) 2008 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2009: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2008: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords非晶質合金 / 水素吸蔵合金 / 中性子回折 / X線回折 / 非晶質 / 原子構造 / 水素
Research Abstract

Neutron and X-ray diffraction and reverse Monte Carlo (RMC) simulation were performed on Ni-Zr amorphous alloys to investigate the rearrangement of metal atoms due to the deuterium absorption. The results showed that the Zr-Zr distances slightly increase but the Zr-Ni and Ni-Ni distances remain virtually unchanged after the deuterium absorption. Additionally, the Voronoi polyhedral analysis of the RMC configurations showed that there is not much difference in the local structure around Zr and Ni before and after the deuterium absorption.
Moreover, neutron diffraction results showed that V-D distance in α-VDx is independent with x.

Report

(3 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • Research Products

    (5 results)

All 2009 2008

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (2 results)

  • [Journal Article] Structural study on Zr0. 39 Ni0. 61 and (Zr0. 39 Ni0. 61)D0. 59 amorphous alloys by neutron and X-ray diffraction2009

    • Author(s)
      K. Itoh, T. Watanabe, T. Otomo, M. Sugiyama, K. Mori, T. Fukunaga
    • Journal Title

      Journal of Alloys and Compounds 483

      Pages: 213-216

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Structural study on Zr0.39 Ni0.61 and (Zr0.39 Ni0.61) D0.59 amorphous alloys by neutron and X-ray diffraction2009

    • Author(s)
      K.Itoh, T.Watanabe, T.Otomo, M.Sugiyama, K.Mori, T.Fukunaga
    • Journal Title

      Journal of Alloys and Compounds 483

      Pages: 213-216

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural study of amorphous LaNi5Dx : In situ neutron and X-ray diffraction experiments in deuterium gas2009

    • Author(s)
      K.Itoh, T.Shoumura, M.Sugiyama, K.Mori, T.Fukunaga
    • Journal Title

      Journal of Alloys and Compounds 474

      Pages: 4-8

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 水素吸蔵によるNi-Zr非晶質合金の構造変化2008

    • Author(s)
      伊藤恵司、森広、杉山正明、福永俊晴
    • Organizer
      日本金属学会2008年秋季(143回)大会
    • Place of Presentation
      熊本大学
    • Year and Date
      2008-09-24
    • Related Report
      2009 Final Research Report
  • [Presentation] 水素吸蔵によるNi-Zr非晶質合金の構造変化2008

    • Author(s)
      伊藤恵司
    • Organizer
      日本金属学会秋期(第143回)大会
    • Place of Presentation
      熊本大学
    • Year and Date
      2008-09-24
    • Related Report
      2008 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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