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Sonochemical preparation of photocatalyst supporting core-shellstructured nanoparticles and the analysis on their catalytic mechanism

Research Project

Project/Area Number 20760525
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Catalyst/Resource chemical process
Research InstitutionTohoku University

Principal Investigator

MIZUKOSHI Yoshiteru  Tohoku University, 金属材料研究所, 助教 (60342523)

Project Period (FY) 2008 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2009: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2008: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Keywordsナノ粒子 / 超音波 / 合金化 / 光触媒 / 合金ナノ粒子 / 助触媒 / コア・シェル構造 / 金 / パラジウム / 二酸化チタン
Research Abstract

Bimetallic nanoparticles consisting of gold and palladium were successfully immobilized on titanium dioxide surface by unique sonochemical reduction method. The photocatalytic activities depended on the inner structure of the immobilized bimetallic particles, in other words, the distribution of the constituent metals in each particle, even with same components. Alloying two or more metals and designing their inner structure were found to provide superior catalyst to the constituent metals.

Report

(3 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • Research Products

    (16 results)

All 2010 2009 2008 Other

All Journal Article (11 results) (of which Peer Reviewed: 11 results) Presentation (4 results) Remarks (1 results)

  • [Journal Article] Dependence of Photocatalytic Activities upon the Structures of Au/Pd Bimetallic Nanoparticles Immobilized on TiO2 Surface2010

    • Author(s)
      Y. Mizukoshi、K. Sato、T.J. Konno, N. Masahashi
    • Journal Title

      Applied Catalysis B Environmenta 94

      Pages: 248-253

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dependence of photocatalytic activities upon the structures of Au/Pd bimetallic nanoparticles immobilized on TiO_2 surface2010

    • Author(s)
      Yoshiteru Mizukoshi
    • Journal Title

      Applied Catalysis B : Environmental 94

      Pages: 248-253

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of biocompatible superparamagnetic magnetite nanoparticles by reverse precipitation method: Contribution of sonochemically generated oxidants2009

    • Author(s)
      Y. Mizukoshi、T. Shuto、N. Masahashi, S. Tanabe
    • Journal Title

      Ultrasonics Sonochemistry 16

      Pages: 525-531

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Hydrogen Permeable Membrane Using Nanoparticles Electrophoresis Technique2009

    • Author(s)
      A. Tominaga、Y. Mizukoshi、O. Nakagoe, S. Tanabe
    • Journal Title

      Topics in Catalysis 52

      Pages: 860-864

    • NAID

      120006984733

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of hydrogen permeablemembrane using nanoparticles electrophoresis technique2009

    • Author(s)
      Aki Tominaga
    • Journal Title

      Topics in Catalysis 52

      Pages: 860-864

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Visible light responses of sulfur-doped rutile titanium dioxide photocatalysts fabricated by anodic oxidation2009

    • Author(s)
      Yoshiteru Mizukoshi
    • Journal Title

      Applied Catalysis B : Environmental 91

      Pages: 152-156

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of biocompatible superparamagnetic magnetite nanoparticles by reverse precipitation method : Contribution of sonochemically generated oxidants2009

    • Author(s)
      Yoshiteru Mizukoshi
    • Journal Title

      Ultrasonics Sonochemistry 16

      Pages: 525-531

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Sonochemical immobilization of noble metal nanoparticles on the surface of maghemite: Mechanism and morphological control of the products2008

    • Author(s)
      Y. Mizukoshi, Y. Tsuru、A. Tominaga、S. Seino、N. Masahashi、S. Tanabe, T.A. Yamamoto
    • Journal Title

      Ultrasonics Sonochemistry 15

      Pages: 875-880

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Magnetically Retrievable Palladium/Maghemite Nanocomposite Catalysts Prepared by Sonochemical Reduction Method2008

    • Author(s)
      Y. Mizukoshi、K. Sato、T.J. Konno、N. Masahashi, S. Tanabe
    • Journal Title

      Chemistry Letters 37

      Pages: 922-923

    • NAID

      10024282076

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Magnetically Retrievable Palladium/ Maghemite Nanocomposite Catalysts Prepared by Sonochemical Reduction Method2008

    • Author(s)
      Yoshiteru Mizukoshi
    • Journal Title

      Chemistry Letters 37

      Pages: 922-923

    • NAID

      10024282076

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Superhydrophilicity of Rutile TiO2 Prepared by Anodic Oxidation in High Concentration Sulfuric Acid Electrolyte2008

    • Author(s)
      Naoya Masahashi
    • Journal Title

      Chemistry Letters 37

      Pages: 1126-1127

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] 二酸化チタン光触媒に担持した金・パラジウム二元金属ナノ粒子の構造と助触媒効果2009

    • Author(s)
      水越克彰
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学理工学部船橋キャンパス
    • Year and Date
      2009-03-29
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] Structural analyses of Au/Pd bimetallic nanoparticles supported on TiO2 and their promotion effects for photocatalytic activities2009

    • Author(s)
      Y. Mizukoshi
    • Organizer
      ICCE2009(12th EuCheMS International Conference on Chemistry and the Environment)
    • Place of Presentation
      ストックホルム大学(スウェーデン)
    • Related Report
      2009 Final Research Report
  • [Presentation] Structural analyses of Au/Pd bimetallic nanoparticles supported on TiO_2 and their promotion effects for photocatalytic activities2009

    • Author(s)
      Yoshiteru Mizukoshi
    • Organizer
      ICCE2009(12^<th> EuCheMS International Conference on Chemistry and the Environment)
    • Place of Presentation
      ストックホルム大学(スウェーデン)
    • Related Report
      2009 Annual Research Report
  • [Presentation] 超音波によって担持したコア・シェル型金・パラジウム二元金属ナノ粒子の二酸化チタン光触媒活性に対する助触媒効果2008

    • Author(s)
      水越克彰
    • Organizer
      第17回ソノケミストリー討論会
    • Place of Presentation
      電気通信大学
    • Year and Date
      2008-12-06
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Remarks]

    • URL

      http://polar.imr.tohoku.ac.jp/

    • Related Report
      2009 Final Research Report

URL: 

Published: 2008-04-01   Modified: 2016-04-21  

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