Development of carbon-based solid acid with nanotube structure

• Project/Area Number: 20760533
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Catalyst/Resource chemical process
• Research Institution: Kanagawa Academy of Science and Technology
• Principal Investigator: KITANO Masaaki Kanagawa Academy of Science and Technology, 応用セラミックス研究所, 特任助教 (50470117)
• Project Period (FY): 2008 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000); Fiscal Year 2010: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000); Fiscal Year 2009: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000); Fiscal Year 2008: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
• Keywords: 固体酸触媒 / チタン酸ナノチューブ / ルイス酸 / ブレンステッド酸 / アルキル化反応 / 異種元素ドープ / チタニアナノチューブ / 酸化チタンナノワイヤー / カーボン系固体酸触媒 / 酸触媒

Research Abstract

Protonated titanate nanotubes with an inner diameter of 6 nm were successfully synthesized by hydrothermal treatment of TiO2 with NaOH and subsequent proton exchange. This material exhibited much higher catalytic activity that conventional solid acid catalysts such as zeolite and ion-exchange resins. Friedel-Crafts alkylation proceeded effectively over protonated titanate nanotubes at room temperature. The remarkable catalytic performance is due to the synergetic combination of Bronsted and Lewis acid sites.

Research Products

• [Journal Article] Protonated Titanate Nanotubes as Solid Acid Catalyst (2010)
  • Author(s): Kitano M. ; Nakajima K. ; Kondo J. N. ; Hayashi S. ; Hara M.
  • Journal Title: J.Am.Chem.Soc 132 Pages: 6622-6623
  • Peer Reviewed
• [Journal Article] チタン酸ナノチューブの固体酸触媒特性 (2010)
  • Author(s): 北野政明・和田江美子・中島清隆・野村淳子・林繁信・原亨和
  • Journal Title: 触媒 52(6) Pages: 366-368
  • NAID: 10029659908
  • Peer Reviewed
• [Journal Article] Protonated Titanate Nanotubes as Solid Acid Catalyst (2010)
  • Author(s): M.Kitano, K.Nakajima, J.N.Kondo, S.Hayashi, M.Hara
  • Journal Title: Journal of the American Chemical Society Volume: 132 Pages: 6622-6623
  • Peer Reviewed
• [Journal Article] チタン酸ナノチューブの固体酸触媒特性 (2010)
  • Author(s): 北野政明・和田江美子・中島清隆・野村淳子・林繁信・原亨和
  • Journal Title: 触媒 Volume: 52 Pages: 366-368
  • NAID: 10029659908
  • Peer Reviewed
• [Presentation] ニオブ含有チタン酸ナノチューブの合成と酸触媒特性 (2011)
  • Author(s): 和田江美子・北野政明・中島清隆・野村淳子・林繁信・原亨和
  • Organizer: 第107回触媒討論会
  • Place of Presentation: 首都大学東京
  • Year and Date: 2011-03-29
• [Presentation] ニオブ含有チタン酸ナノチューブの合成と酸触媒特性 (2011)
  • Author(s): 和田江美子・北野政明・中島清隆・野村淳子・林繁信・原亨和
  • Organizer: 第107回触媒討論会
  • Place of Presentation: 首都大学東京、東京
  • Year and Date: 2011-03-29
• [Presentation] チタン酸ナノチューブの固体酸触媒特性 (2010)
  • Author(s): 北野政明・和田江美子・中島清隆・野村淳子・林繁信・原亨和
  • Organizer: 第106回触媒討論会
  • Place of Presentation: ベルクラシック甲府、山梨
  • Year and Date: 2010-09-15
• [Presentation] Preparation of Protonated Titanate Nanotubes and Its Application as Efficient Solid Acid Catalyst (2010)
  • Author(s): M.Kitano, E.Wada, K.Nakajima, J.N.Kondo, S.Hayashi, M.Hara
  • Organizer: The Sixth Tokyo Conference on Advanced Catalytic Science and Technology & The Fifth Asia Pacific Congress on Catalysis (TOCAT6 & APCAT7)
  • Place of Presentation: Sapporo Convention Center, Sapporo, Japan
  • Year and Date: 2010-07-22
• [Presentation] Protonated Titanate Nanotubes as Strong Acid Catalyst (2010)
  • Author(s): M.Kitano, E.Wada, K.Nakajima, J.N.Kondo, S.Hayashi, M.Hara
  • Organizer: 16^<th> International Zeolite Conference join with 7^<th> International Mesostructured Materials Symposium (IZC16 & IMMS7)
  • Place of Presentation: Hilton Sorrento Palace、Sorrento, Italy
  • Year and Date: 2010-07-08
• [Presentation] チタニアナノチューブの合成と固体酸触媒としての応用 (2010)
  • Author(s): 北野政明
  • Organizer: 日本化学会第90回春季年会
  • Place of Presentation: 近畿大学、大阪
  • Year and Date: 2010-03-26
• [Presentation] チタン酸ナノチューブの固体酸触媒特性 (2010)
  • Author(s): 北野政明・和田江美子・中島清隆・野村淳子・林繁信・原亨和
  • Organizer: 第106回触媒討論会
  • Place of Presentation: ベルクラシック甲府
• [Presentation] Preparation of Protonated Titanate Nanotubes and Its Application as Efficient Solid Acid Catalyst (2010)
  • Author(s): Masaaki Kitano, Emiko Wada, Kiyotaka Nakajima, Jyunko N. Kondo, Shigenobu Hayashi, Michikazu Hara
  • Organizer: The Sixth Tokyo Conference on Advanced Catalytic Science and Technology & The Fifth Asia Pacific Congress on Catalysis (TOCAT6 & APCAT7)
  • Place of Presentation: Hokkaido, Japan
• [Presentation] Protonated Titanate Nanotubes as Strong Acid Catalyst (2010)
  • Author(s): Masaaki Kitano, Emiko Wada, Kiyotaka Nakajima, Jyunko N. Kondo, Shigenobu Hayashi, Michikazu Hara
  • Organizer: 16th International Zeolite Conference join with 7th International Mesostructured Materials Symposium (IZC16 & IMMS7)
  • Place of Presentation: Sorrento, Italy
• [Presentation] チタニアナノチューブの合成と固体酸触媒としての応用 (2010)
  • Author(s): 北野政明・和田江美子・中島清隆・野村淳子・林繁信・原亨和
  • Organizer: 日本化学会第90回春季年会
  • Place of Presentation: 近畿大学
• [Presentation] 固体酸触媒としてのチタニアナノチューブ (2009)
  • Author(s): 北野政明
  • Organizer: 第104回触媒討論会
  • Place of Presentation: 宮崎大学、宮崎
  • Year and Date: 2009-09-29
• [Presentation] 固体酸触媒としてのチタニアナノチューブ (2009)
  • Author(s): 北野政明・中島清隆・野村淳子・林繁信・原亨和
  • Organizer: 第104回触媒討論会
  • Place of Presentation: 宮崎大学
• [Patent(Industrial Property Rights)] ナノワイヤー構造を有するチタニア系高性能固体酸触媒 (2009)
  • Inventor(s): 北野政明、原亨和
  • Industrial Property Rights Holder: 財団法人神奈川科学技術アカデミー、国立大学法人東京工業大学
  • Industrial Property Number: 2009-009465
  • Filing Date: 2009-01-20
• [Patent(Industrial Property Rights)] ナノチューブ構造を有する固体酸触媒 (2009)
  • Inventor(s): 北野政明、原亨和
  • Industrial Property Rights Holder: 財団法人神奈川科学技術アカデミー、国立大学法人東京工業大学
  • Filing Date: 2009-09-24
  • Overseas
• [Patent(Industrial Property Rights)] ナノチューブ構造を有する固体酸触媒 (2009)
  • Inventor(s): 北野政明, 原亨和
  • Industrial Property Rights Holder: 財団法人神奈川科学技術アカデミー、国立大学法人東京工業大学
  • Filing Date: 2009-09-24
  • Overseas
• [Patent(Industrial Property Rights)] ナノワイヤー構造を有するチタニア系高性能固体酸触媒 (2009)
  • Inventor(s): 北野政明, 原亨和
  • Industrial Property Rights Holder: 財団法人神奈川科学技術アカデミー、国立大学法人東京工業大学
  • Industrial Property Number: 2009-009465
  • Filing Date: 2009-01-20