Regioselective Carbometalation of Alkenes Using a Unique Feature of Cationic Scandium Species
| Project/Area Number |
20790026
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Chemical pharmacy
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| Research Institution | The Institute of Physical and Chemical Research |
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Principal Investigator |
TAKIMOTO Masanori The Institute of Physical and Chemical Research, 侯有機金属化学研究室, 専任研究員 (50312377)
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| Project Period (FY) |
2008 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2009: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2008: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
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| Keywords | 触媒反応 / 希土類 / 有機アルミニウム / アルケン / アルキン / カルボメタル化 |
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| Research Abstract |
A scandium-based catalyst system for the regio^- and stereoselective carboalumination of alkenes and internal alkynes having an ether tether group have been developed in this research. In most cases, the achieved selectivities are unique to the present catalyst system and could not be achieved by previously known catalysts.
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Report
(3 results)
Research Products
(9 results)
