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Fundamental Study on Gas Separation and Storage Techniques by use of Clathrate Hydrate

Research Project

Project/Area Number 20810016
Research Category

Grant-in-Aid for Young Scientists (Start-up)

Allocation TypeSingle-year Grants
Research Field Environmental technology/Environmental materials
Research InstitutionOsaka University

Principal Investigator

HASHIMOTO Shunsuke  Osaka University, 大学院・基礎工学研究科, 助教 (00506446)

Co-Investigator(Renkei-kenkyūsha) SUGAHARA Takeshi  大阪大学, 大学院・基礎工学研究科, 助教 (20335384)
Project Period (FY) 2008 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥3,289,000 (Direct Cost: ¥2,530,000、Indirect Cost: ¥759,000)
Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2008: ¥1,729,000 (Direct Cost: ¥1,330,000、Indirect Cost: ¥399,000)
Keywords環境技術・環境材料 / 省エネルギー / クラスレートハイドレート / 水素貯蔵 / 化学工学 / 環境技術 / 環境材料 / 水素
Research Abstract

It was revealed that the reversible H_2 storage and release could be performed by H_2 pressure swing without destroying hydrate-cages. H_2 absorption process contains the following two steps : H_2 adsorption and diffusion for hydrate. In both steps, the difference of H_2 fugacity between inside and outside of hydrate may play a role as the driving force. In the present study, the storage amount and absorption period of H_2 are about 1.0 mass% and 3 hours, respectively.

Report

(3 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • Research Products

    (28 results)

All 2010 2009 2008

All Journal Article (14 results) (of which Peer Reviewed: 13 results) Presentation (14 results)

  • [Journal Article] Hydrogen Storage in Trimethylamine Mixed Semi-clathrate Hydrate2010

    • Author(s)
      K. Ogata, T. Tsuda, S. Amano, S. Hashimoto, T. Sugahara, K. Ohgaki
    • Journal Title

      Chemical Engineering Science 65

      Pages: 1616-1620

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Thermodynamic Stabilities of Tetra-n-butyl Ammonium Bromide Semi-Clathrate Hydrate2010

    • Author(s)
      S. Hashimoto, T. Tsuda, K. Ogata, T. Sugahara, Y. Inoue, K. Ohgaki
    • Journal Title

      Journal of Thermodynamics ID

      Pages: 170819-170819

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Thermodynamic Stabilities of Tetra-n-butyl Ammonium Bromide Semi-Clathrate Hydrate2010

    • Author(s)
      S.Hashimoto, T.Tsuda, K.Ogata, T.Sugahara, Y.Inoue, K.Ohgaki
    • Journal Title

      Journal of Thermodynamics ID : 170819

      Pages: 1-5

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrogen Storage in Trimethylamine Mixed Semi-clathrate Hydrate2010

    • Author(s)
      K.Ogata, T.Tsuda, S.Amano, S.Hashimoto, T.Sugahara, K.Ohgaki
    • Journal Title

      Chemical Engineering Science 65

      Pages: 1616-1620

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Storage Capacity of Hydrogen in Tetrahydrothiophene and Furan Clathrate Hydrates2009

    • Author(s)
      T. Tsuda, K. Ogata, S. Hashimoto, T. Sugahara, M. Moritoki, K. Ohgaki
    • Journal Title

      Chemical Engineering Science 64

      Pages: 4150-4154

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] ガスハイドレートの水素貯蔵能力-現状と課題-2009

    • Author(s)
      橋本俊輔、菅原武、佐藤博、大垣一成
    • Journal Title

      触媒 51

      Pages: 298-303

    • NAID

      10024766755

    • Related Report
      2009 Annual Research Report
  • [Journal Article] Storage Capacity of Hydrogen in Tetrahydrothiophene and Furan Clathrate Hydrates2009

    • Author(s)
      T.Tsuda, K.Ogata, S.Hashimoto, T.Sugahara, M.Moritoki, K.Ohgaki
    • Journal Title

      Chemical Engineering Science 64

      Pages: 4150-4154

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Storage Capacity of Hydrogen in Tetrahydrofuran Hydrate2008

    • Author(s)
      橋本俊輔, 菅原武, 佐藤博, 大垣一成
    • Journal Title

      Chemical Engineering Science 63

      Pages: 5714-5718

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Storage Capacity of Hydrogen in Tetrahydrofuran Hydrate2008

    • Author(s)
      K. Ogata, S. Hashimoto, T. Sugahara, M. Moritoki, H. Sato, K. Ohgaki
    • Journal Title

      Chemical Engineering Science 63

      Pages: 5714-5718

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Thermodynamic and Raman Spectroscopic Studies on Hydrogen + Tetra-n-Butyl Ammonium Fluoride Semi-Clathrate Hydrates2008

    • Author(s)
      J. Sakamoto, S. Hashimoto, T. Tsuda, T. Sugahara, Y. Inoue, K. Ohgaki
    • Journal Title

      Chemical Engineering Science 63

      Pages: 5789-5794

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Thermodynamic Stability on Mixed Gas Hydrates Containing Hydrogen2008

    • Author(s)
      S. Hashimoto, T. Sugahara, M. Moritoki, H. Sato, K. Ohgaki
    • Journal Title

      Journal of Physics: Conference Series 121

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Storage Capaci ty of Hydrogen in Tetrahydrofuran Hydrate2008

    • Author(s)
      K. Ogata, S. Hashimoto, T. Sugahara, M. Moritoki, H. Sato, K. Ohgaki
    • Journal Title

      Chemical Engineering Sci ence 63

      Pages: 5714-5718

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermodynamic and Raman Spectroscopic studies on Hydrog en + Tetra-n-Butyl Ammoninium Fluoride Sem-Clathrate Hydrates2008

    • Author(s)
      J. Sakamoto, s. Hashimot o, T. Tsuda, T. Sugahara Y. Inoue, K. Ohgaki
    • Journal Title

      Chemical Engineering Science 63

      Pages: 5789-5794

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermodynamic Stability on Mixed Gas Hydrates Contai nin g Hydrogen2008

    • Author(s)
      S. Hashimoto, T. Sugahar a, M. Mori tokioki, H. Sato, K. Ohgaki
    • Journal Title

      Journal of Physics : Conference Series 121

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] Gas Hydrateの物性・機能とそれにまつわる応用技術(招待講演)2009

    • Author(s)
      橋本俊輔, 大垣一成
    • Organizer
      第15回関西地区分離技術見学討論会
    • Place of Presentation
      神戸製鋼所(株)
    • Year and Date
      2009-08-05
    • Related Report
      2009 Final Research Report
  • [Presentation] Gas Hydrateの物性・機能とそれにまつわる応用技術2009

    • Author(s)
      橋本俊輔、大垣一成
    • Organizer
      第15回関西地区分離技術見学討論会
    • Place of Presentation
      神戸製鋼所(株),兵庫
    • Year and Date
      2009-08-05
    • Related Report
      2009 Annual Research Report
  • [Presentation] Storage Capacity of Hydrogen in Gas Hydrates2009

    • Author(s)
      T. Tsuda, K. Ogata, S. Hashimoto, T. Sugahara, H. Sato, K. Ohgaki
    • Organizer
      Joint AIRAPT-22 & HPCJ-50 International Conference on "High Pressure Science and Technology"
    • Place of Presentation
      Odai-ba, Tokyo
    • Year and Date
      2009-07-30
    • Related Report
      2009 Final Research Report
  • [Presentation] Storage Capacity of Hydrogen in Gas Hydrates2009

    • Author(s)
      T.Tsuda, K.Ogata, S.Hashimoto, T.Sugahara, H.Sato, K.Ohgaki
    • Organizer
      Joint AIRAPT-22 & HPCJ-50 International Conference on"High Pressure Science and Technology"
    • Place of Presentation
      Odai-ba, Tokyo
    • Year and Date
      2009-07-30
    • Related Report
      2009 Annual Research Report
  • [Presentation] 水素系混合ガスハイドレートの水素吸蔵能力2008

    • Author(s)
      緒方恭平, 橋本俊輔, 松井祐樹, 菅原武, 大垣一成
    • Organizer
      第49回高圧討論会
    • Place of Presentation
      姫路商工会議所
    • Year and Date
      2008-11-13
    • Related Report
      2009 Final Research Report
  • [Presentation] 水素+第四級アンモニウム塩混合ハイドレートの構造相転移と水素占有性2008

    • Author(s)
      橋本俊輔, 坂本惇, 菅原武, 大垣一成
    • Organizer
      第49回高圧討論会
    • Place of Presentation
      姫路商工会議所
    • Year and Date
      2008-11-13
    • Related Report
      2009 Final Research Report
  • [Presentation] Tetrahydrothiopheneハイドレートの水素吸蔵能力2008

    • Author(s)
      津田崇暁, 緒方恭平, 橋本俊輔, 菅原武, 大垣一成
    • Organizer
      第49回高圧討論会
    • Place of Presentation
      姫路商工会議所
    • Year and Date
      2008-11-12
    • Related Report
      2009 Final Research Report
  • [Presentation] The Property of Clathrate Hydrates as a Hydrogen Storage Material (Invited Speech)2008

    • Author(s)
      S. Hashimoto, J. Sakamoto, K. Ogata, T. Tsuda, T. Sugahara, Y. Inoue, K. Ohgaki
    • Organizer
      The 2nd SSCCI / SCEJ (Kansai-Branch) Joint International Conference on Chemical Engineering
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2008-11-04
    • Related Report
      2009 Final Research Report
  • [Presentation] Cage Occupancies of Hydrogen Molecule and Thermodynamic Stabilities of Hydrogen-Containing Hydrates2008

    • Author(s)
      T. Sugahara, S. Hashimoto, H. Mori, J. Sakamoto, K. Ogata, K. Ohgaki
    • Organizer
      The 6th International Congerence on Gas Hydrates (ICGH6)
    • Place of Presentation
      Vancouver, Canada
    • Year and Date
      2008-07-09
    • Related Report
      2009 Final Research Report
  • [Presentation] 水素十第四級アンモニウム塩混合バイトレートの構造相転移と水素占有性2008

    • Author(s)
      橋本俊輔, 坂本 惇, 菅原武, 大垣一成
    • Organizer
      第49回 高圧討論会
    • Place of Presentation
      姫路商工会議所
    • Related Report
      2008 Annual Research Report
  • [Presentation] 水素系混合ガスハイドレニトの水素吸蔵能力2008

    • Author(s)
      緒方恭平, 橋本俊輔, 松井祐樹, 菅原 武, 大垣一成
    • Organizer
      第49回 高圧討論会
    • Place of Presentation
      姫路商工会議所
    • Related Report
      2008 Annual Research Report
  • [Presentation] Tetrahydrothiopheneバイトレートの水素吸蔵能力2008

    • Author(s)
      津田崇暁, 緒方恭平, 橋本俊輔, 菅原 武, 大垣一成
    • Organizer
      第49回 高圧討論会
    • Place of Presentation
      姫路商工会議所
    • Related Report
      2008 Annual Research Report
  • [Presentation] Cage Occupancies of Hydrogen Molecule and Thermodynaniic Stabilities of Hydrogen-Containing Hydrates2008

    • Author(s)
      T. Sugahara, S. Hashimot 0, H. Mori, J. Sakamoto, K. Ogata, K. Ohgaki
    • Organizer
      The 6th International Congerence on Gas Hydrates(ICGH6)
    • Place of Presentation
      Vancouver, Canada
    • Related Report
      2008 Annual Research Report
  • [Presentation] The Property of Clathirate Hydratesas a. Hydrogen Storage Material (Invited speech)2008

    • Author(s)
      S. Hashimoto, J. Sakamot 0, K. Ogata, T, Tsuda, T . Sugahara, Y. Inoue, K. Ohgaki
    • Organizer
      The 2nd SSCCI / SCEJ (Kansai-Branch) J oint Internati onal Conference on Chemi cal Engi neering
    • Place of Presentation
      Shanghai, China
    • Related Report
      2008 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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