• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Surface effect on Li-ion diffusion in nano-sized electrodes

Research Project

Project/Area Number 20810029
Research Category

Grant-in-Aid for Young Scientists (Start-up)

Allocation TypeSingle-year Grants
Research Field Nanomaterials/Nanobioscience
Research InstitutionChuo University

Principal Investigator

OKUBO Masashi  Chuo University, エネルギー技術研究部門, 研究員 (20453673)

Project Period (FY) 2008 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥3,276,000 (Direct Cost: ¥2,520,000、Indirect Cost: ¥756,000)
Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2008: ¥1,716,000 (Direct Cost: ¥1,320,000、Indirect Cost: ¥396,000)
Keywordsリチウムイオン2次電池 / 電極 / ナノサイズ効果 / 正極材料 / ナノ粒子 / ナノイオニクス / リチウムイオン電池
Research Abstract

High charge/discharge rate Li-ion batteries require short Li-ion diffusion length in electrodes, thus the nano-sized electrodes. The hydrothermal synthesis of the nano-sized electrodes such as LiCoO_2 or LiMn_2O_4 has been established in this study. Nano-sized LiCoO_2 has revealed to exhibit low charge/discharge capacity and voltage due to the surface Co(II) atom. In contrast, nano-sized LiMn_2O_4 showed higher charge/discharge capacity than the bulk one, since the surface energy compete with the lattice distortion during the redox process.

Report

(3 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • Research Products

    (40 results)

All 2010 2009 2008

All Journal Article (13 results) (of which Peer Reviewed: 12 results) Presentation (27 results)

  • [Journal Article] Fast Li-ion insertion into nanosized LiMn2O4 without domain boundaries.2010

    • Author(s)
      M. Okubo, Y. Mizuno, H. Yamada, J.-D. Kim, E. Hosono, H.S. Zhou, T. Kudo, I. Honma
    • Journal Title

      ACS nano 4

      Pages: 741-752

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of triaxial LiFePO4 nanowire with a VGCF core column and a carbon shell through the electrospinning method.2010

    • Author(s)
      E. Hosono, Y. Wang, N. Kida, M. Enomoto, N. Kojima, M. Okubo, H. Matsuda, Y. Saito, T. Kudo, I. Honma, H.S. Zhou
    • Journal Title

      ACS Appl. Mater. Inter 2

      Pages: 212-218

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Fast Li-ion insertion into nanosized LiMn2O4 without domain boundaries.2010

    • Author(s)
      大久保將史
    • Journal Title

      ACS NANO 4

      Pages: 741-752

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of triaxial LiFePO4 nanowire with a VGCF core column and a carbon shell through the electrospinning method.2010

    • Author(s)
      細野英司
    • Journal Title

      ACS Applied Materials and Interfaces 2

      Pages: 212-218

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Anisotropic surface effect on electronic structures and electrochemical properties of LiCoO2 nanoelectrode.2009

    • Author(s)
      M. Okubo, J.D. Kim, T. Kudo, H.S. Zhou, I. Honma
    • Journal Title

      J. Phys. Chem. C 113

      Pages: 15337-15342

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Determination of activatiaon energy for Li ion diffusion in electrodes.2009

    • Author(s)
      M. Okubo, T. Kudo, H.S. Zhou, I. Honma
    • Journal Title

      J. Phys. Chem. B 113

      Pages: 2840-2847

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Size effect on electrochemical property of nanocrystalline LiCoO2 synthesized from rapid thermal annealing method.2009

    • Author(s)
      M. Okubo, E. Hosono, T. Kudo, H.S. Zhou, I. Honma
    • Journal Title

      Solid State Ionics 180

      Pages: 612-615

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Anisotropic surface effect on electrode structures and electrochemical properties of LiCoO2 nanoelectrode.2009

    • Author(s)
      大久保將史
    • Journal Title

      Journal of Physical Chemistry C 113

      Pages: 15337-15342

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Determination of activation energy for Li ion diffusion in electrodes2009

    • Author(s)
      Masashi Okubo, et al.
    • Journal Title

      Journal of Physical Chemistry B 113

      Pages: 2840-2847

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Control of charge transfer phase transition and ferroma gnetism by photoisomerization of spiropyran for an organic-inorganic hybrid system, ( SP) [ Fe^〈II〉 Fe^〈III〉( dto)^3]( SP=spiropyran, dto = C_2O_2S_2)2009

    • Author(s)
      Noriyuki Kida, et al.
    • Journal Title

      Journal of the American Chemical Society 131

      Pages: 212-220

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Phonon confinement effect on nanocrystalline LiCoO2 studied with Raman Spectroscopy.2008

    • Author(s)
      M. Okubo, E. Hosono, T. Kudo, H.S. Zhou, I. Honma
    • Journal Title

      J. Phys. Chem. Solids 69

      Pages: 2911-2915

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Phonon confinement effect on nanocrystalline LiCo02 synthesized from rapid thermal annealing method2008

    • Author(s)
      Masashi Okubo, et al.
    • Journal Title

      Journal of Physics and Chemistry of Solid 69

      Pages: 2911-2915

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ナノ結晶LiCoO_2の合成と電極特性2008

    • Author(s)
      大久保将史, 他
    • Journal Title

      電気化学および工業物理化学 76

      Pages: 349-353

    • NAID

      10020737959

    • Related Report
      2008 Annual Research Report
  • [Presentation] ナノ結晶LiMn2O4の2相共存領域における相境界移動現象の解析2010

    • Author(s)
      大久保將史, 工藤徹一, 本間格
    • Organizer
      電気化学会第77回大会
    • Place of Presentation
      富山
    • Year and Date
      2010-03-29
    • Related Report
      2009 Final Research Report
  • [Presentation] ナノ結晶LiMn2O4の2相共存領域における相境界移動現象の解析2010

    • Author(s)
      大久保將史
    • Organizer
      電気化学会第77回大会
    • Place of Presentation
      富山・富山大学
    • Year and Date
      2010-03-29
    • Related Report
      2009 Annual Research Report
  • [Presentation] LiMn2O4におけるリチウム挿入反応へのナノサイズ効果2010

    • Author(s)
      大久保將史, 工藤徹一, 本間格
    • Organizer
      日本セラミックス協会2010年年会
    • Place of Presentation
      東京
    • Year and Date
      2010-03-22
    • Related Report
      2009 Final Research Report
  • [Presentation] LiMn2O4におけるリチウム挿入反応へのナノサイズ効果2010

    • Author(s)
      大久保將史
    • Organizer
      日本セラミックス協会2010年年会
    • Place of Presentation
      東京・東京農工大学
    • Year and Date
      2010-03-22
    • Related Report
      2009 Annual Research Report
  • [Presentation] LixMn2O4 (1<x<2)における2相共存領域へのナノサイズ効果の解析2009

    • Author(s)
      大久保將史, 工藤徹一, 本間格
    • Organizer
      第35回固体イオニクス討論会
    • Place of Presentation
      大阪
    • Year and Date
      2009-12-07
    • Related Report
      2009 Final Research Report
  • [Presentation] LixMn2O4における2相共存領域へのナノサイズ効果の解析2009

    • Author(s)
      大久保將史
    • Organizer
      第35回固体イオニクス討論会
    • Place of Presentation
      大阪・国際会議場
    • Year and Date
      2009-12-07
    • Related Report
      2009 Annual Research Report
  • [Presentation] LiMn2O4における2相共存領域へのナノサイズ効果の解析2009

    • Author(s)
      大久保將史, 水野善文, 細野英司, 周豪慎, 工藤徹一, 本間格
    • Organizer
      第50回電池討論会
    • Place of Presentation
      京都
    • Year and Date
      2009-11-30
    • Related Report
      2009 Final Research Report
  • [Presentation] LiMn2O4における2相共存領域へのナノサイズ効果の解析2009

    • Author(s)
      大久保將史
    • Organizer
      第50回電池討論会
    • Place of Presentation
      京都・国際会議場
    • Year and Date
      2009-11-30
    • Related Report
      2009 Annual Research Report
  • [Presentation] High power electrode properties of size-controlled nanocrystalline LiMn2O4.2009

    • Author(s)
      大久保將史
    • Organizer
      The 2^<nd> international conference on Advanced Lithium batteries for automobile applications
    • Place of Presentation
      東京・学術総合センター
    • Year and Date
      2009-11-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] 水熱法を用いたナノ結晶LiMn2O4の合成と電極特性2009

    • Author(s)
      大久保將史, 工藤徹一, 本間格
    • Organizer
      第22回セラミックス協会秋季シンポジウム
    • Place of Presentation
      愛媛
    • Year and Date
      2009-09-17
    • Related Report
      2009 Final Research Report
  • [Presentation] 水熱法を用いたナノ結晶LiMn2O4の合成と電極特性2009

    • Author(s)
      大久保將史
    • Organizer
      第22回セラミックス協会秋季シンポジウム
    • Place of Presentation
      愛媛・愛媛大学
    • Year and Date
      2009-09-17
    • Related Report
      2009 Annual Research Report
  • [Presentation] LiMn2O4における電極特性へのナノサイズ効果2009

    • Author(s)
      大久保將史, 工藤徹一, 本間格
    • Organizer
      2009年電気化学秋季大会
    • Place of Presentation
      東京
    • Year and Date
      2009-09-10
    • Related Report
      2009 Final Research Report
  • [Presentation] LiMn2O4における電極特性へのナノサイズ効果2009

    • Author(s)
      大久保將史
    • Organizer
      2009年電気化学会秋季大会
    • Place of Presentation
      東京・東京農工大学
    • Year and Date
      2009-09-10
    • Related Report
      2009 Annual Research Report
  • [Presentation] Surface effect on electronic structure and electrochemical property of nanocrystalline electrode materials.2009

    • Author(s)
      大久保將史
    • Organizer
      The 17^<th> international conference on solid state ionics
    • Place of Presentation
      カナダ・トロント
    • Year and Date
      2009-06-29
    • Related Report
      2009 Annual Research Report
  • [Presentation] ナノサイズ電極におけるリチウムイオン拡散現象の解析2009

    • Author(s)
      大久保將史, 工藤徹一, 本間格
    • Organizer
      電気化学会第76回大会
    • Place of Presentation
      京都
    • Year and Date
      2009-03-30
    • Related Report
      2009 Final Research Report
  • [Presentation] 水熱法を利用したナノサイズ電極の合成と電気化学特性変化2009

    • Author(s)
      大久保將史, 工藤徹一, 本間格
    • Organizer
      日本セラミックス協会2009年年会
    • Place of Presentation
      千葉
    • Year and Date
      2009-03-18
    • Related Report
      2009 Final Research Report
  • [Presentation] High power electrode properties of size-controlled nanocrystalline LiMn2O4.2009

    • Author(s)
      M. Okubo, T. Kudo, I. Honma
    • Organizer
      The 2nd International Conference on Advanced Lithium Batteries for Automobile Applications (ABAA)
    • Place of Presentation
      Tokyo, Japan
    • Related Report
      2009 Final Research Report
  • [Presentation] Surface effect on electronic structure and electrochemical property of nanocrystalline electrode materials.2009

    • Author(s)
      M. Okubo, T. Kudo, I. Honma
    • Organizer
      The 17th International Conference on Solid State Ionics (SSI-17)
    • Place of Presentation
      Tronto, Canada(口頭発表)
    • Related Report
      2009 Final Research Report
  • [Presentation] ナノ正極材料におけるリチウムイオン拡散速度の解析2008

    • Author(s)
      大久保將史, 工藤徹一, 本間格
    • Organizer
      第34回固体イオニクス討論会
    • Place of Presentation
      東京
    • Year and Date
      2008-12-03
    • Related Report
      2009 Final Research Report
  • [Presentation] ナノ正極材料におけるリチウムイオン拡散速度の解析2008

    • Author(s)
      大久保将史, 他
    • Organizer
      第34回固体イオニクス討論会
    • Place of Presentation
      東京大学生産技術研究所
    • Year and Date
      2008-12-03
    • Related Report
      2008 Annual Research Report
  • [Presentation] ナノ正極活物質の水熱合成と高出力電極特性2008

    • Author(s)
      大久保將史, 工藤徹一, 本間格
    • Organizer
      第49回電池討論会
    • Place of Presentation
      大阪
    • Year and Date
      2008-11-07
    • Related Report
      2009 Final Research Report
  • [Presentation] ナノ正極活物質の水熱合成と高出力電極特性2008

    • Author(s)
      大久保将史, 他
    • Organizer
      第49回電池討論会
    • Place of Presentation
      堺リーガロイヤルホテル
    • Year and Date
      2008-11-07
    • Related Report
      2008 Annual Research Report
  • [Presentation] 水熱法を用いたリチウムイオン2次電池用ナノ正極材料の合成2008

    • Author(s)
      大久保将史, 他
    • Organizer
      日本セラミックス協会第21回秋季シンポジウム
    • Place of Presentation
      北九州国際会議場
    • Year and Date
      2008-09-17
    • Related Report
      2008 Annual Research Report
  • [Presentation] Size effect of nanocrystalline LiCoO2 electrodes for a high power battery application.2008

    • Author(s)
      M. Okubo, H.S. Zhou, T. Kudo, I. Honma
    • Organizer
      The IUMRS International Conference in Asia 2008 (IUMRS-ICA 2008)
    • Place of Presentation
      Nagoya, Japan(口頭発表)
    • Related Report
      2009 Final Research Report
  • [Presentation] Enhanced Li-ion diffusion via surface effect on nanocrystalline LiCoO2.2008

    • Author(s)
      M. Okubo, T. Kudo, I. Honma
    • Organizer
      Pacific Rim Meeting on Electrochemical and Solid-State Science (PRIME 2008)
    • Place of Presentation
      Honolulu, USA(口頭発表)
    • Related Report
      2009 Final Research Report
  • [Presentation] 水熱法を用いたリチウムイオン2次電池用ナノ正極材料の合成2008

    • Author(s)
      大久保將史, 工藤徹一, 本間格
    • Organizer
      日本セラミックス協会第21回秋季シンポジウム
    • Place of Presentation
      北九州
    • Related Report
      2009 Final Research Report
  • [Presentation] Nano-size control of LiCoO2 electrodes for a high power battery application.2008

    • Author(s)
      M. Okubo, T. Kudo, I. Honma
    • Organizer
      International Meeting on Lithium Batteries (IMLB2008)
    • Place of Presentation
      Tianjin, China
    • Related Report
      2009 Final Research Report

URL: 

Published: 2008-04-01   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi