Preparation of nano-structured oxide materials in non-aqueous reverse micelle solution

• Project/Area Number: 20810036
• Research Category: Grant-in-Aid for Young Scientists (Start-up)
• Allocation Type: Single-year Grants
• Research Field: Nanostructural science
• Research Institution: Kanagawa University
• Principal Investigator: YOSHIDA Akihiro Kanagawa University, 工学部, 助手 (30514434)
• Co-Investigator(Renkei-kenkyūsha): NAITO Shuichi 神奈川大学, 工学部, 教授 (20011710)
• Project Period (FY): 2008 – 2009
• Project Status: Completed (Fiscal Year 2009)
• Budget Amount: ¥3,276,000 (Direct Cost: ¥2,520,000、Indirect Cost: ¥756,000); Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000); Fiscal Year 2008: ¥1,716,000 (Direct Cost: ¥1,320,000、Indirect Cost: ¥396,000)
• Keywords: ナノ構造触媒 / ゾル・ゲル法

Research Abstract

Spherical titania nano particles, macroporous silica and titania were successfully prepared by using reverse micelles in non-aqueous solution as templates The non-aqueous reverse micelle systems were formed by the addition of the highly polar solvent into the anionic surfactant solution of the non-polar solvent. The hydrolysis reaction of metal alkoxide was retarded by controlling the water content in the non-aqueous reverse micelle systems, which lead to the prevention of the formation of amorphous metal oxide products.