Structure control of molecular assembly by cooperative effect of coordination bond and hydrogen bond.
| Project/Area Number |
20850003
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| Research Category |
Grant-in-Aid for Young Scientists (Start-up)
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| Allocation Type | Single-year Grants |
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| Research Field |
Inorganic chemistry
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| Research Institution | University of Tsukuba |
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Principal Investigator |
KUWABARA Junpei University of Tsukuba, 大学院・数理物質科学研究科, 助教 (70466655)
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| Project Period (FY) |
2008 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
|
| Budget Amount *help |
¥3,185,000 (Direct Cost: ¥2,450,000、Indirect Cost: ¥735,000)
Fiscal Year 2009: ¥1,508,000 (Direct Cost: ¥1,160,000、Indirect Cost: ¥348,000)
Fiscal Year 2008: ¥1,677,000 (Direct Cost: ¥1,290,000、Indirect Cost: ¥387,000)
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| Keywords | 配位結合 / 水素結合 / りん光発光 / DNA / ゲル / 配立結合 |
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| Research Abstract |
The bifunctional ligands with a thymine moiety were synthesized for construction of DNA mimic using coordination bond. The reaction of the ligands and Pd precursor affords coordination polymers with a thymine moiety. The structure can be changed by external environment such as solvent. The pincer Pt complex with amide groups affords an assembled structure by hydrogen bonding. The relationship between the structure and emissive properties were investigated.
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Report
(3 results)
Research Products
(42 results)
