Properties and Structural Changes of Aromatic Molecules within a Self-Assembled Coordination Cage
| Project/Area Number |
20850008
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| Research Category |
Grant-in-Aid for Young Scientists (Start-up)
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| Allocation Type | Single-year Grants |
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| Research Field |
Functional materials chemistry
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| Research Institution | The University of Tokyo |
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Principal Investigator |
MURASE Takashi The University of Tokyo, 大学院・工学系研究科, 特任助教 (70508184)
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| Project Period (FY) |
2008 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥3,276,000 (Direct Cost: ¥2,520,000、Indirect Cost: ¥756,000)
Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2008: ¥1,716,000 (Direct Cost: ¥1,320,000、Indirect Cost: ¥396,000)
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| Keywords | 自己組織化 / 配位結合 / π共役系分子 / フォールディング / ナノ空間 |
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| Research Abstract |
An asymmetric alignment of electron-donating (D) and accepting (A) aromatics is a formidable challenge in the self-assembly of aromatic stacks because self-assembled aromatic stacks usually give alternating aromatic arrays, D-A-D-A-…. Here, we show that appropriate D-A guest pairs settle down in an electron-deficient aromatic box to yield an asymmetric quadruple A-D-A-A stacking sequence quantitatively. The inner D-A guest pair rapidly swaps their positions to create a dynamic aromatic array, and the swift guest motion largely depends on the donor aromatics.
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Report
(3 results)
Research Products
(20 results)
