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Properties and Structural Changes of Aromatic Molecules within a Self-Assembled Coordination Cage

Research Project

Project/Area Number 20850008
Research Category

Grant-in-Aid for Young Scientists (Start-up)

Allocation TypeSingle-year Grants
Research Field Functional materials chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

MURASE Takashi  The University of Tokyo, 大学院・工学系研究科, 特任助教 (70508184)

Project Period (FY) 2008 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥3,276,000 (Direct Cost: ¥2,520,000、Indirect Cost: ¥756,000)
Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2008: ¥1,716,000 (Direct Cost: ¥1,320,000、Indirect Cost: ¥396,000)
Keywords自己組織化 / 配位結合 / π共役系分子 / フォールディング / ナノ空間
Research Abstract

An asymmetric alignment of electron-donating (D) and accepting (A) aromatics is a formidable challenge in the self-assembly of aromatic stacks because self-assembled aromatic stacks usually give alternating aromatic arrays, D-A-D-A-…. Here, we show that appropriate D-A guest pairs settle down in an electron-deficient aromatic box to yield an asymmetric quadruple A-D-A-A stacking sequence quantitatively. The inner D-A guest pair rapidly swaps their positions to create a dynamic aromatic array, and the swift guest motion largely depends on the donor aromatics.

Report

(3 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • Research Products

    (20 results)

All 2010 2009

All Journal Article (7 results) (of which Peer Reviewed: 4 results) Presentation (12 results) Book (1 results)

  • [Journal Article] Pairwise Selective Formation of Aromatic Stacks in a Coordination Cage2010

    • Author(s)
      Takashi Murase, Kosuke Otsuka, Makoto Fujita
    • Journal Title

      J.Am.Chem.Soc.

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Both [2+2] and [2+4] additions of inert aromatics via identical ternary host-guest complexes2010

    • Author(s)
      Shinnosuke Horiuchi, Yuki Nishioka, Takashi Murase, Makoto Fujita
    • Journal Title

      Chem.Commun. 46

      Pages: 3460-3462

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Naphthalene Diels-Alder in a Self-Assembled Molecular Flask2010

    • Author(s)
      Takashi Murase, Shinnosuke Horiuchi, Makoto Fujita
    • Journal Title

      J.Am.Chem.Soc. 132

      Pages: 2866-2867

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Naphthalene Diels-Alder in a Self-Assembled Molecular Flask2010

    • Author(s)
      村瀬隆史, Shinnosuke Horiuchi, 藤田誠
    • Journal Title

      J.Am.Chem.Soc. 132

      Pages: 2866-2867

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 自己集合性中空錯体内で進行する特異的化学反応2009

    • Author(s)
      村瀬隆史, 藤田誠
    • Journal Title

      有機合成化学協会誌 67

      Pages: 465-474

    • NAID

      10024968656

    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Journal Article] 自己組織化空間内での特異的化学反応2009

    • Author(s)
      村瀬隆史, 藤田誠
    • Journal Title

      月刊ファインケミカル 38

      Pages: 37-44

    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Journal Article]2009

    • Author(s)
      村瀬隆史、藤田誠
    • Journal Title

      「錯体化学会選書5 超分子金属錯体」"超分子自己集合"(三共出版)

    • Related Report
      2009 Annual Research Report
  • [Presentation] 自己組織化空間における芳香環ゲスト分子のペア認識と動的挙動2010

    • Author(s)
      大塚浩介, 村瀬隆史, 藤田誠
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学
    • Year and Date
      2010-03-27
    • Related Report
      2009 Final Research Report
  • [Presentation] 自己組織化空間における芳香族ゲスト分子のペア認識と動的挙動2010

    • Author(s)
      大塚浩介、村瀬隆史、藤田誠
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学(本部キャンパス)
    • Year and Date
      2010-03-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] Diels-Alder Reactions of Naphthalenes in an Aqueous Molecular Host2009

    • Author(s)
      Takashi Murase, Shinnosuke Horiuchi, Makoto Fujita
    • Organizer
      The 4th International Conference on Cutting-Edge Organic Chemistry in Asia (ICCEOCA-4)
    • Place of Presentation
      Chulabhorn Research Institute (Thailand)
    • Year and Date
      2009-12-12
    • Related Report
      2009 Final Research Report
  • [Presentation] Diels-Alder Reactions of Naphthalenes in an Aqueous Molecular Host2009

    • Author(s)
      村瀬隆史, 堀内新之介, 藤田誠
    • Organizer
      The 4th International Conference on Cutting-Edge Organic Chemistry in Asia(ICCEOCA-4)
    • Place of Presentation
      Chulabhorn Research Institute(Thailand)
    • Year and Date
      2009-12-02
    • Related Report
      2009 Annual Research Report
  • [Presentation] 自己集合性中空錯体内で進行するナフタレンの Diels-Alder 反応2009

    • Author(s)
      村瀬隆史, 堀内新之介, 藤田誠
    • Organizer
      第20回基礎有機化学討論会
    • Place of Presentation
      群馬大学
    • Year and Date
      2009-09-28
    • Related Report
      2009 Final Research Report
  • [Presentation] 自己集合性中空錯体内で進行するナフタレンのDiels-Alder反応2009

    • Author(s)
      村瀬隆史、堀内新之介、藤田誠
    • Organizer
      第20回基礎有機化学討論会
    • Place of Presentation
      群馬大学(桐生キャンパス)
    • Year and Date
      2009-09-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] 芳香環ヘテロ有限集積体のゲスト交換挙動2009

    • Author(s)
      大塚浩介, 村瀬隆史, 藤田誠
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎大学
    • Year and Date
      2009-09-26
    • Related Report
      2009 Final Research Report
  • [Presentation] 芳番環ヘテロ有限集積体のゲスト交換挙動2009

    • Author(s)
      大塚浩介、村瀬隆史、藤田誠
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎大学(文教キャンパス)
    • Year and Date
      2009-09-26
    • Related Report
      2009 Annual Research Report
  • [Presentation] 芳香族分子による有機ピラー型かご状錯体の連結2009

    • Author(s)
      堤隼人, 村瀬隆史, 藤田誠
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学
    • Year and Date
      2009-03-29
    • Related Report
      2009 Final Research Report
  • [Presentation] 芳香族分子による有機ピラー型かご状錯体の連結2009

    • Author(s)
      堤隼人, 村瀬隆史, 藤田誠
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学理工学部船橋キャンパス
    • Year and Date
      2009-03-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] 自己組織化空間における芳香環の電荷移動集積2009

    • Author(s)
      大塚浩介, 村瀬隆史, 藤田誠
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学
    • Year and Date
      2009-03-28
    • Related Report
      2009 Final Research Report
  • [Presentation] 自己組織化空間における芳香環の電荷移動集積2009

    • Author(s)
      大塚浩介, 村瀬隆史, 藤田誠
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学理工学部船橋キャンパス
    • Year and Date
      2009-03-28
    • Related Report
      2008 Annual Research Report
  • [Book] 超分子自己集合 「錯体化学会選書5 超分子金属錯体」2009

    • Author(s)
      村瀬隆史, 藤田誠
    • Publisher
      三共出版
    • Related Report
      2009 Final Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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