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The observation of local structures of water-oil interfaces by fourth-order coherent Raman spectroscopy

Research Project

Project/Area Number 20850026
Research Category

Grant-in-Aid for Young Scientists (Start-up)

Allocation TypeSingle-year Grants
Research Field Physical chemistry
Research InstitutionKobe University

Principal Investigator

NOMOTO Tomonori  Kobe University, 自然科学系先端融合研究環分子フォトサイエンス研究センター, 学術研究員 (00510520)

Project Period (FY) 2008 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥3,276,000 (Direct Cost: ¥2,520,000、Indirect Cost: ¥756,000)
Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2008: ¥1,716,000 (Direct Cost: ¥1,320,000、Indirect Cost: ¥396,000)
Keywords表面・界面物性 / 振動分光法 / 非線形分光法 / 分子科学 / 物理化学
Research Abstract

In this research, we have developped the fourth-order coherent Raman spectroscopy, and time-domain infrared-visible-visible sum-frequency generation for detection of molecular structures of interfaces such as water-oil interfaces. During the study, spectra of lattice vibrations, molecular vibrations of various buried interfaces, and intensity change of second-harmonic generation of liquid-liquid interfaces derived from the change of interfacial structures. These results are the milestones toward the observation of interfaces and intermediate structures during chemical reactions that have been difficult to detect.

Report

(3 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • Research Products

    (31 results)

All 2010 2009 2008

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (23 results)

  • [Journal Article] Time-Domain Infrared-Visible-Visible Sum-Frequency Generation for Surface Vibrational Spectroscopy2009

    • Author(s)
      Tomonori Nomoto, Hiroshi Onishi
    • Journal Title

      J. Phys. Chem. C 113(52)

      Pages: 21467-21470

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Optically excited near-surface phonons of TiO2 (110) observed by fourth-order coherent Raman spectroscopy2009

    • Author(s)
      Tomonori Nomoto, Akira Sasahara, Hiroshi Onishi
    • Journal Title

      J. Chem. Phys. 131(8)

      Pages: 84703-84703

    • NAID

      120001506674

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Fourth-order coherent Raman spectroscopy of liquid-solid interfaces: near-surface phonons of TiO2 (110) in liquids2009

    • Author(s)
      Tomonori Nomoto, Hiroshi Onishi
    • Journal Title

      Applied Spectroscopy 63(8)

      Pages: 941-946

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Fourth-order coherent Raman spectroscopy of liquid-solid interfaces : near-surface phonons of TiO_2(110)in liquids2009

    • Author(s)
      Tomonori Nomoto, Hiroshi Onishi
    • Journal Title

      Applied Spectroscopy 63

      Pages: 941-946

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Optically excited near-surface phonons of TiO_2(110)observed by fourth-order coherent Raman spectroscopy2009

    • Author(s)
      Tomonori Nomoto, Akira Sasahara, Hiroshi Onishi
    • Journal Title

      The Journal of Chemical Physics 131

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Time-Domain Infrared-Visible-Visible Sum-Frequency Generation for Surface Vibrational Spectroscopy2009

    • Author(s)
      Tomonori Nomoto, Hiroshi Onishi
    • Journal Title

      The Journal of Physical Chemistry C 124

      Pages: 21467-21470

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fourth-order Raman spectroscopy of adsorbed organic species on TiO2 surface2008

    • Author(s)
      Tomonori Nomoto, Hiroshi Onishi
    • Journal Title

      Chem. Phys. Lett. 455(4-6)

      Pages: 343-347

    • NAID

      120001506650

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Fourth-order Raman spectroscopy of adsorbed organic species on TiO_2 surface2008

    • Author(s)
      Tomonori Nomoto, Hiroshi Onishi
    • Journal Title

      Chemical Physics Letters 455

      Pages: 343-347

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] Low-Frequency Vibrations of TiO_2 Observed by Surface Sensitive Time-Domain Vibrational Spectroscopy2010

    • Author(s)
      野本知理, 大西洋
    • Organizer
      The 1st Ultrafast Dynamics Symposium
    • Place of Presentation
      Hsinchu, Taiwan
    • Year and Date
      2010-01-14
    • Related Report
      2009 Annual Research Report
  • [Presentation] Low-Frequency Vibrations of TiO_2 Surface Observed by Fourth-order Coherent Raman Spectroscopy2010

    • Author(s)
      野本知理, 大西洋
    • Organizer
      The 6th Asian Conference on Ultrafast Phenomena
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      2010-01-12
    • Related Report
      2009 Annual Research Report
  • [Presentation] Low-Frequency Vibrations of TiO2 Observed by Surface Sensitive Time-Domain Vibrational Spectroscopy2010

    • Author(s)
      Tomonori Nomoto, Hiroshi Onishi
    • Organizer
      The 1st Ultrafast Dynamics Symposium
    • Place of Presentation
      Hsinchu, Taiwan
    • Related Report
      2009 Final Research Report
  • [Presentation] Low-Frequency Vibrations of TiO2 Surface Observed by Fourth-order Coherent Raman Spectroscopy2010

    • Author(s)
      Tomonori Nomoto, Hiroshi Onishi
    • Organizer
      The 6th Asian Conference on Ultrafast Phenomena (ACUP2010)
    • Place of Presentation
      Taipei, Taiwan
    • Related Report
      2009 Final Research Report
  • [Presentation] 二酸化チタン表面の界面敏感な振動スペクトル測定2009

    • Author(s)
      野本知理, 大西洋
    • Organizer
      表面・界面スペクトロスコピー2009
    • Place of Presentation
      札幌定山渓ホテルミリホーネ(北海道)
    • Year and Date
      2009-12-04
    • Related Report
      2009 Annual Research Report
  • [Presentation] Observation of near-surface phonons of TiO_2(110)coherently excited by terahertz electric field : Time-domain infrared-visible-visible vibrational sum frequency generation for surface spectroscopy2009

    • Author(s)
      野本知理, 大西洋
    • Organizer
      The International Workshop on Terahertz Technology 2009
    • Place of Presentation
      大阪大学(大阪府)
    • Year and Date
      2009-11-30
    • Related Report
      2009 Annual Research Report
  • [Presentation] N3色素吸着TiO_2(110)表面の4次ラマン応答と電子励起ダイナミクス2009

    • Author(s)
      野本知理, 小出直城, 片山博之, 大西洋
    • Organizer
      第3回分子科学討論会
    • Place of Presentation
      名古屋大学,(愛知県)
    • Year and Date
      2009-09-22
    • Related Report
      2009 Annual Research Report
  • [Presentation] THz光パルス励起によるTiO_2表面近傍のコヒーレントフォノン検出2009

    • Author(s)
      野本知理, 大西洋
    • Organizer
      第70回応用物理学会学術講演会
    • Place of Presentation
      富山大学,(富山県)
    • Year and Date
      2009-09-10
    • Related Report
      2009 Annual Research Report
  • [Presentation] Near-surface low-frequency vibrations of TiO_2 observed by fourth-order coherent Raman spectroscopy2009

    • Author(s)
      野本知理, 大西洋
    • Organizer
      The Fourteenth International Conference on Time-Resolved Vibrational Spectroscopy
    • Place of Presentation
      Meredith, NH, USA
    • Year and Date
      2009-05-13
    • Related Report
      2009 Annual Research Report
  • [Presentation] 界面近傍でのTHz光パルス検出 : 界面の低波数振動スペクトル測定に向けて2009

    • Author(s)
      野本知理, 大西洋
    • Organizer
      シンポジウム「表面・界面を観る非線形分光の新しい展開」
    • Place of Presentation
      理化学研究所, 和光
    • Year and Date
      2009-03-24
    • Related Report
      2008 Annual Research Report
  • [Presentation] Near-surface low-frequency vibrations of TiO2 (110)observed by fourth-order coherent Raman spectroscopy2009

    • Author(s)
      Tomonori Nomoto, Hiroshi Onishi
    • Organizer
      The Indo-Japan workshop on “Frontiers of Molecular Spectroscopy and Theory"
    • Place of Presentation
      IACS, Kolkata, India
    • Year and Date
      2009-03-08
    • Related Report
      2008 Annual Research Report
  • [Presentation] Observation of near-surface phonons of TiO2 (110) coherently excited by terahertz electric field: Time-domain infrared-visible-visible vibrational sum frequency generation for surface spectroscopy:2009

    • Author(s)
      Tomonori Nomoto, Hiroshi Onishi
    • Organizer
      The International Workshop on Terahertz Technology 2009
    • Place of Presentation
      Osaka, Japan
    • Related Report
      2009 Final Research Report
  • [Presentation] Near-surface low-frequency vibrations of TiO2 observed by fourth-order coherent Raman spectroscopy2009

    • Author(s)
      Tomonori Nomoto, Hiroshi Onishi
    • Organizer
      The Fourteenth International Conference on Time-Resolved Vibrational Spectroscopy
    • Place of Presentation
      Meredith, NH, USA
    • Related Report
      2009 Final Research Report
  • [Presentation] Near-surface low-frequency vibrations of TiO2 (110) observed by fourth-order coherent Raman spectroscopy2009

    • Author(s)
      Tomonori Nomoto, Hiroshi Onishi
    • Organizer
      Recent Progress in Spectroscopy and Theory in Chemistry
    • Place of Presentation
      Kolkata, India
    • Related Report
      2009 Final Research Report
  • [Presentation] 二酸化チタン表面の界面敏感な振動スペクトル測定:2009

    • Author(s)
      野本知理
    • Organizer
      大西洋, 表面・界面スペクトロスコピー2009
    • Place of Presentation
      札幌
    • Related Report
      2009 Final Research Report
  • [Presentation] N3色素吸着TiO2(110)表面の4次ラマン応答と電子励起ダイナミクス2009

    • Author(s)
      野本知理, 小出直城, 片山博之, 大西洋
    • Organizer
      第3回分子科学討論会
    • Place of Presentation
      名古屋
    • Related Report
      2009 Final Research Report
  • [Presentation] THz光パルス励起によるTiO2表面近傍のコヒーレントフォノン検出2009

    • Author(s)
      野本知理, 大西洋
    • Organizer
      第70回応用物理学会学術講演会
    • Place of Presentation
      富山
    • Related Report
      2009 Final Research Report
  • [Presentation] 界面近傍でのTHz光パルス検出:界面の低波数振動スペクトル測定に向けて2009

    • Author(s)
      野本知理, 大西洋
    • Organizer
      表面・界面を観る非線形分光の新しい展開
    • Place of Presentation
      和光
    • Related Report
      2009 Final Research Report
  • [Presentation] TiO2界面の四次コヒーレントラマン分光2009

    • Author(s)
      野本知理, 大西洋
    • Organizer
      表面・界面を観る非線形分光の新しい展開
    • Place of Presentation
      和光
    • Related Report
      2009 Final Research Report
  • [Presentation] Near-surface low-frequency vibrations of TiO2 (110)observed by fourth-order coherent Raman spectroscopy2008

    • Author(s)
      Tomonori Nomoto, Hiroshi Onishi
    • Organizer
      2008 Annual Meeting of the Spectroscopical Society of Japan
    • Place of Presentation
      東北大学, 仙台
    • Year and Date
      2008-11-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] 4次のコヒーレントラマン分光法による二酸化チタン(110)表面フォノンのスペクトル2008

    • Author(s)
      野本知理, 大西洋
    • Organizer
      第2回分子科学討論会
    • Place of Presentation
      福岡国際会議場, 福岡
    • Year and Date
      2008-09-25
    • Related Report
      2008 Annual Research Report
  • [Presentation] Near-surfacelow-frequency vibrations of TiO2 (110) observed by fourth-order coherent Raman spectroscopy2008

    • Author(s)
      Tomonori Nomoto, Hiroshi Onishi
    • Organizer
      International Symposium on "Recent Advances in Terahertz Spectroscopy, Microspectroscopy, and Living Cell Spectroscopy in Molecular Science and Molecular Imaging", 2008 Annual Meeting of the Spectroscopical Society of Japan
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2009 Final Research Report
  • [Presentation] 4次のコヒーレントラマン分光法による二酸化チタン(110)表面フォノンのスペクトル2008

    • Author(s)
      野本知理, 大西洋
    • Organizer
      第2回分子科学討論会
    • Place of Presentation
      福岡
    • Related Report
      2009 Final Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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