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Selective dehydration of monosaccharide using heterogeneous catalyst

Research Project

Project/Area Number 20860038
Research Category

Grant-in-Aid for Young Scientists (Start-up)

Allocation TypeSingle-year Grants
Research Field Catalyst/Resource chemical process
Research InstitutionJapan Advanced Institute of Science and Technology

Principal Investigator

TAKAGAKI Atsushi  Japan Advanced Institute of Science and Technology, マテリアルサイエンス研究科, 助教 (30456157)

Project Period (FY) 2008 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥3,289,000 (Direct Cost: ¥2,530,000、Indirect Cost: ¥759,000)
Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2008: ¥1,729,000 (Direct Cost: ¥1,330,000、Indirect Cost: ¥399,000)
Keywords固体酸触媒 / バイオマス変換 / 脱水反応 / 無水糖 / イオン交換樹脂 / ハイドロタルサイト / ヒドロキシメチルフルフラール / スルホ基
Research Abstract

バイオマスの中でも糖類基本単位であるグルコースを原料とし,脱水反応により有用化合物を高選択的に合成できる固体触媒を開発することを目的とした.まず,イオン交換樹脂アンバーリスト-15がグルコースから無水糖(レボグルコサン)を選択的に合成できることを見出した.また,固体塩基(ハイドロタルサイト)と固体酸(アンバーリスト-15)を同時に加えると,ワンポットにて5-ヒドロキシメチルフルフラールが高選択的に得られることがわかった.

Report

(3 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • Research Products

    (29 results)

All 2010 2009 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (16 results) Patent(Industrial Property Rights) (5 results) (of which Overseas: 1 results)

  • [Journal Article] Monodisperse iron oxide nanoparticles embedded in Mg-Al hydrotalciteas a highly active, magnetically separable and recyclable solid base catalyst2010

    • Author(s)
      S.Nishimura, A.Takagaki, K.Ebitani
    • Journal Title

      Bulletin of the Chemical Society of Japan (in press)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A one-pot reaction for biorefinery: combination of solid acid and base catalysts for direct production of 5-hydroxymethylfurfural from saccharides2009

    • Author(s)
      Atsushi Takagaki, Mika Ohara, Shun Nishimura, Kohki Ebitani
    • Journal Title

      Chemical Communications

      Pages: 6276-6278

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Glucose to Value-added Chemicals:Anhydroglucose Formation by Selective Dehydration over Solid Acid Catalysts2009

    • Author(s)
      Atsushi Takagaki, Kohki Ebitani
    • Journal Title

      Chemistry Letters 38

      Pages: 650-651

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Glucose to Valued-added Chemicals : Anhydroglucose Formation by Selective Dehydration over Solid Acid Catalysts2009

    • Author(s)
      A.Takagaki, K.Ebitani
    • Journal Title

      Chemistry Letters 38

      Pages: 650-651

    • NAID

      10025123689

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A one-pot reaction for biorefinery : combination of solid acid and base catalysts for direct production of 5-hydroxymethylfurfural from saccharides2009

    • Author(s)
      A.Takagaki, M.Ohara, S.Nishimura, K.Ebitani
    • Journal Title

      Chemical Communications

      Pages: 6276-6278

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Glucose to Valued-added Chemicals : Anhydroglucose Formation by Selective Dehydration over Solid Acid Catalysts2009

    • Author(s)
      A. Takagaki, K. Ebitani
    • Journal Title

      Chemistry Letters (in press)

    • NAID

      10025123689

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of 5-hydroxymethylfurfural and levoglucosan by selective dehydration of glucose using solid acid and base catalysts

    • Author(s)
      Mika Ohara, Atsushi Takagaki, Shun Nishimura, Kohki Ebitani
    • Journal Title

      Applied Catalysis A: General (in press)

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Monodisperse iron oxide nanoparticles embedded in Mg-Al hydrotalcite as a highly active, magnetically separable and recyclable solid base catalyst

    • Author(s)
      Shun Nishimura, Atsushi Takagaki, Kohki Ebitani
    • Journal Title

      Bulletin of the Chemical Society of Japan (in press)

    • NAID

      10027175344

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Presentation] 金属酸化物ナノシートを用いた水中での5-ヒドロキシメチルフルフラールの合成2010

    • Author(s)
      大原三佳、西村俊、高垣敦、堂免一成、海老谷幸喜
    • Organizer
      日本化学会第90回春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-28
    • Related Report
      2009 Final Research Report
  • [Presentation] 金属酸化物ナノシートを用いた水中での5-ヒドロキシメチルフルフラールの合成2010

    • Author(s)
      大原三佳、西村俊、高垣敦、堂免一成、海老谷幸喜
    • Organizer
      日本化学会第90回春季年会
    • Place of Presentation
      近畿大学(大阪)
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] 固体酸塩基触媒を用いた糖類からのフルフラール類のワンポット合成2010

    • Author(s)
      大原三佳、西村俊、高垣敦、海老谷幸喜
    • Organizer
      第105回触媒討論会
    • Place of Presentation
      京都
    • Year and Date
      2010-03-24
    • Related Report
      2009 Final Research Report
  • [Presentation] 固体酸塩基触媒を用いた糖類からのフルフラール類のワンポット合成2010

    • Author(s)
      大原三佳、西村俊、高垣敦、海老谷幸喜
    • Organizer
      第105回触媒討論会
    • Place of Presentation
      京都テルサ(京都)
    • Year and Date
      2010-03-24
    • Related Report
      2009 Annual Research Report
  • [Presentation] 固体酸塩基触媒を用いた糖類からの5-ヒドロキシメチルフルフラールの直接合成2009

    • Author(s)
      大原三佳、西村俊、高垣敦、海老谷幸喜
    • Organizer
      平成21年度日本化学会北陸地区研究会
    • Place of Presentation
      石川
    • Year and Date
      2009-11-28
    • Related Report
      2009 Final Research Report
  • [Presentation] Anhydroglucose Formation from Glucose over Solid Acid Catalysts2009

    • Author(s)
      高垣敦, 海老谷幸喜
    • Organizer
      The 12^<th> Japan-Korea Symposium on Catalysis
    • Place of Presentation
      秋田キャッスルホテル(秋田)
    • Year and Date
      2009-10-15
    • Related Report
      2009 Annual Research Report
  • [Presentation] 5-Hydroxymethylfurfural Formation from Glucose over Solid Acid/Base Catalysts2009

    • Author(s)
      大原三佳, 西村俊, 高垣敦, 海老谷幸喜
    • Organizer
      The 12^<th> Japan-Korea Symposium on Catalysis
    • Place of Presentation
      秋田キャッスルホテル(秋田)
    • Year and Date
      2009-10-15
    • Related Report
      2009 Annual Research Report
  • [Presentation] Anhydroglucose Formation from Glucose over Solid Acid Catalysts2009

    • Author(s)
      Atsushi Takagaki, Kohki Ebitani
    • Organizer
      The 12th Japan-Korea Symposium on Catalysis
    • Place of Presentation
      Akita (Japan)
    • Year and Date
      2009-10-14
    • Related Report
      2009 Final Research Report
  • [Presentation] 5-Hydroxymethylfurfural Formation from Glucose over Solid Acid/Base Catalysts2009

    • Author(s)
      Mika Ohara, Shun Nishimura, Atsushi Takagaki, Kohki Ebitani
    • Organizer
      The 12th Japan-Korea Symposium on Catalysis
    • Place of Presentation
      Akita (Japan)
    • Year and Date
      2009-10-14
    • Related Report
      2009 Final Research Report
  • [Presentation] 固体酸触媒による無水糖の合成2009

    • Author(s)
      高垣敦、海老谷幸喜
    • Organizer
      第104回触媒討論会
    • Place of Presentation
      宮崎
    • Year and Date
      2009-09-29
    • Related Report
      2009 Final Research Report
  • [Presentation] 固体酸触媒による無水糖の合成2009

    • Author(s)
      高垣敦、海老谷幸喜
    • Organizer
      第104回触媒討論会
    • Place of Presentation
      宮崎大学(宮崎)
    • Year and Date
      2009-09-29
    • Related Report
      2009 Annual Research Report
  • [Presentation] 固体酸塩基触媒による糖類からの5-ヒドロキシメチルフルフラールへ直接合成2009

    • Author(s)
      大原三佳、西村俊、高垣敦、海老谷幸喜
    • Organizer
      第104回触媒討論会
    • Place of Presentation
      宮崎大学(宮崎)
    • Year and Date
      2009-09-29
    • Related Report
      2009 Annual Research Report
  • [Presentation] Selective synthesis of 5-hydroxymethylfurfural and levoglucosan from glucose over solid acid/base catalysts2009

    • Author(s)
      Atsushi Takagaki, Mika Ohara, Kohki Ebitani
    • Organizer
      6th World Congress on Catalysis by Acids and Bases (ABC-6)
    • Place of Presentation
      Genova (Italy)
    • Year and Date
      2009-05-14
    • Related Report
      2009 Final Research Report
  • [Presentation] Selective synthesis of 5-hydroxymethylfurfural and levoglucosan from glucose over solid acid/base catalysts2009

    • Author(s)
      高垣敦, 大原三佳, 海老谷幸喜
    • Organizer
      6^<th> World Congress on Catalysis by Acids and Bases(ABC-6)
    • Place of Presentation
      Ancient Harbor, Genova(Italy)
    • Year and Date
      2009-05-14
    • Related Report
      2009 Annual Research Report
  • [Presentation] 固体酸触媒を用いたグルコースの脱水反応によるレボグルコサンの合成2009

    • Author(s)
      高垣敦、海老谷幸喜
    • Organizer
      日本化学会第89回春季年会
    • Place of Presentation
      千葉
    • Year and Date
      2009-03-27
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] 固体酸塩基触媒を用いたグルコースから5-ヒドロキシメチルフルフラールへのOne-pot合成2009

    • Author(s)
      大原三佳、西村俊、高垣敦、海老谷幸喜
    • Organizer
      日本化学会第89回春季年会
    • Place of Presentation
      千葉
    • Year and Date
      2009-03-27
    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] 海老谷幸喜、高垣敦2010

    • Inventor(s)
      国立大学法人北陸先端科学技術大学院大学
    • Filing Date
      2010-02-18
    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] 5-ヒドロキシメチルフルフラールの製造方法2010

    • Inventor(s)
      海老谷幸喜、高垣敦
    • Industrial Property Rights Holder
      北陸先端科学技術大学院大学
    • Filing Date
      2010-02-18
    • Related Report
      2009 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 無水糖の製造方法2009

    • Inventor(s)
      海老谷幸喜、高垣敦
    • Industrial Property Rights Holder
      国立大学法人北陸先端科学技術大学院大学
    • Industrial Property Number
      2009-053068
    • Filing Date
      2009-03-06
    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] 5-ヒドロキシメチルフルフラールの製造方法2009

    • Inventor(s)
      海老谷幸喜、高垣敦
    • Industrial Property Rights Holder
      国立大学法人北陸先端科学技術大学院大学
    • Industrial Property Number
      2009-053041
    • Filing Date
      2009-03-06
    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] 無水糖の製造方法2009

    • Inventor(s)
      海老谷幸喜, 高垣敦
    • Industrial Property Rights Holder
      北陸先端科学技術大学院大学
    • Industrial Property Number
      2009-053068
    • Filing Date
      2009-03-06
    • Related Report
      2008 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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